Characterization and performance of Cu/ZnO/Al2O3 catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H2 and CO2

能源化学(英文) ›› 2011, Vol. 20 ›› Issue (6): 629-634.

Characterization and performance of Cu/ZnO/Al₂O₃ catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H₂ and CO₂

Danjun Wang^1,2, Jun Zhao¹, Huanling Song¹, Lingjun Chou¹*

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000,
Gansu, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2011-04-07 修回日期:2011-08-29 出版日期:2011-11-20 发布日期:2011-11-18
通讯作者: 丑凌军
基金资助:
Specialized Research Fund for the Doctoral Program of Higher Education of China

Characterization and performance of Cu/ZnO/Al₂O₃ catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H₂ and CO₂

Danjun Wang^1,2, Jun Zhao¹, Huanling Song¹, Lingjun Chou¹*

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000,
Gansu, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received:2011-04-07 Revised:2011-08-29 Online:2011-11-20 Published:2011-11-18
Contact: Ling-Jun CHOU

摘要/Abstract

摘要： Methanol synthesis from hydrogenation of CO₂ is investigated over Cu/ZnO/Al₂O₃ catalysts prepared by decomposition of M(Cu, Zn)-ammonia complexes (DMAC) at various temperatures. The catalysts were characterized in detail, including X-ray diffraction, N₂ adsorption-desorption, N₂O chemisorption, temperature-programmed reduction and evolved gas analyses. The influences of DMAC temperature, reaction temperature and specific Cu surface area on catalytic performance are investigated. It is considered that the aurichalcite phase in the precursor plays a key role in improving the physiochemical properties and activities of the final catalysts. The catalyst from rich-aurichalcite precursor exhibits large specific Cu surface area and high space time yield of methanol (212 g/(L_cat•h);T = 513 K, p = 3 MPa, SV = 12000 h^-¹).

关键词: decomposition of M(Cu, Zn)-ammonia complexes, Cu/ZnO/Al2O3 catalyst, CO2 hydrogenation, methanol synthesis

Abstract: Methanol synthesis from hydrogenation of CO₂ is investigated over Cu/ZnO/Al₂O₃ catalysts prepared by decomposition of M(Cu, Zn)-ammonia complexes (DMAC) at various temperatures. The catalysts were characterized in detail, including X-ray diffraction, N₂ adsorption-desorption, N₂O chemisorption, temperature-programmed reduction and evolved gas analyses. The influences of DMAC temperature, reaction temperature and specific Cu surface area on catalytic performance are investigated. It is considered that the aurichalcite phase in the precursor plays a key role in improving the physiochemical properties and activities of the final catalysts. The catalyst from rich-aurichalcite precursor exhibits large specific Cu surface area and high space time yield of methanol (212 g/(L_cat•h);T = 513 K, p = 3 MPa, SV = 12000 h^-¹).

Key words: decomposition of M(Cu, Zn)-ammonia complexes, Cu/ZnO/Al2O3 catalyst, CO2 hydrogenation, methanol synthesis

Danjun Wang, Jun Zhao, Huanling Song, Lingjun Chou*. Characterization and performance of Cu/ZnO/Al₂O₃ catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H₂ and CO₂[J]. 能源化学(英文), 2011, 20(6): 629-634.

参考文献

[1] Xu A M, Indala S, Hertwig T A, Pike R W, Knopf F C, Yaws C L, Hopper J R. Clean Technol Environ Policy, 2005, 7(2): 97
[2] Ma J, Sun N N, Zhang X L, Zhao N, Xiao F K, Wei W, Sun Y H. Catal Today, 2009, 148(3-4): 221
[3] Sakakura T, Choi J C, Yasuda H. Chem Rev, 2007, 107(6): 2365
[4] Joo O S, Jung K D, Moon I, Rozovskii A Y, Lin G I, Han S H, Uhm S J. Ind Eng Chem Res, 1999, 38(5): 1808
[5] Turco M, Bagnasco G, Cammarano C, Senese P, Costantino U, Sisani M. Appl Catal B, 2007, 77(1-2): 46
[6] Arena F, Italiano G, Barbera K, Bordiga S, Bonura G, Spadaro L, Frusteri F. Appl Catal A, 2008, 350(1): 16
[7] Behrens M, Furche A, Kasatkin I, Trunschke A, Busser W, Muhler M, Kniep B, Fischer R, Schl\"{o}gl R. ChemCatChem, 2010, 2(7): 816
[8] Liu Y, Zhang Y, Wang T J, Tsubaki N. Chem Lett, 2007, 36(9): 1182
[9] Baltes C, Vukojevi? S, Schüth F. J Catal, 2008, 258(2): 334
[10] Liu X M, Lu G Q, Yan Z F, Beltramini J. Ind Eng Chem Res, 2003, 42(25): 6518
[11] Li J L, Inui T. Appl Catal A, 1996, 137(1): 105
[12] Jun K W, Shen W J, Rao K S R, Lee K W. Appl Catal A, 1998, 174(1-2): 231
[13] Wu J G, Luo S C, Toyir J, Saito M, Takeuchi M, Watanabe T. Catal Today, 1998, 45(1-4): 215
[14] Ma Y, Sun Q, Wu D, Fan W H, Zhang Y L, Deng J F. Appl Catal A, 1998, 171(1): 45
[15] Ruckenstein E, Hong L. Chem Mater, 1996, 8(2): 546
[16] Hong Z S, Cao Y, Deng J F, Fan K N. Catal Lett, 2002, 82(1-2): 37
[17] Huang Z W, Cui F, Kang H X, Chen J, Zhang X Z, Xia C G. Chem Mater, 2008, 20(15): 5090
[18] Arena F, Barbera K, Italiano G, Bonura G, Spadaro L, Frusteri F. J Catal, 2007, 249(2): 185
[19] Atake I, Nishida K, Li D, Shishido T, Oumi Y, Sano T, Takehira K. J Mol Catal A, 2007, 275(1-2): 130
[20] Turco M, Bagnasco G, Costantino U, Marmottini F, Montanari T, Ramis G, Busca G. J Catal, 2004, 228(1): 43
[21] Kim J Y, Rodriguez J A, Hanson J C, Frenkel A I, Lee P L. J Am Chem Soc, 2003, 125(35): 10684
[22] Gervasini A, Bennici S. Appl Catal A, 2005, 281(1-2): 199
[23] Yahiro H, Nakaya K, Yamamoto T, Saiki K, Yamaura H. Catal Commun, 2006, 7(4): 228
[24] Velu S, Suzuki K, Okazaki M, Kapoor M P, Osaki T, Ohashi F. J Catal, 2000, 194(2): 373
[25] Xia W Q, Tang H D, Lin S D, Cen Y Q, Liu H Z. Chin J Catal (Cuihua Xuebao), 2009, 30(9): 879
[26] Lin S D, Tang H D, L\"{u} Z B, Liu C L, Cen Y Q, Liu H Z. Chin J Catal (Cuihua Xuebao), 2010, 31(10): 1257
[27] Bems B, Schur M, Dassenoy A, Junkes H, Herein D, Schlögl R. Chem Eur J, 2003, 9(9): 2039
[28] An X, Li J L, Zuo Y Z, Zhang Q, Wang D Z, Wang J F. Catal Lett, 2007, 118(3-4): 264

Characterization and performance of Cu/ZnO/Al₂O₃ catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H₂ and CO₂

Characterization and performance of Cu/ZnO/Al₂O₃ catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H₂ and CO₂

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