Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts

能源化学(英文) ›› 2010, Vol. 19 ›› Issue (6): 0-0.

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Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts

Ahmad Tavasoli¹,Ali Nakhaei Pour²

1. Applied Chemistry School of Chemistry, College of Science, University of Tehran
2. Gas research departement,research institute of petrolium industry

收稿日期:2010-04-06 修回日期:2010-05-12 出版日期:2010-11-30 发布日期:2010-11-25
通讯作者: Ahmad Tavasoli

Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts

Ahmad Tavasoli,Ali Nakhaei Pour

Received:2010-04-06 Revised:2010-05-12 Online:2010-11-30 Published:2010-11-25
Contact: Ahmad Tavasoli

摘要/Abstract

关键词: Fischer–Tropsch synthesis , cobalt , Ruthenium , Reaction rate , products distribution , Fischer–Tropsch synthesis, cobalt, Ruthenium, Reaction rate, products distribution

Abstract: Hydrocarbon production rates and distributions on ruthenium promoted alumina supported cobalt Fischer-Tropsch Synthesis (FTS) catalysts were studied by the concept of two superimposed Anderson  Schulz  Flory (ASF) distributions. The results indicated that the characterizing growth probabilities 僴冄1 and 冄2 are strongly dependent to reaction conditions. By increasing the H2/CO partial pressures ratios and reaction temperatures, deviation from normal ASF distribution decreases and the double儃冄儃僴ASF distribution changes into a straight line. Based on the concept of double儃冄儃僴ASF distribution, a useful power-law hydrocarbons production rates for industrial reaction conditions is obtained.

Ahmad Tavasoli Ali Nakhaei Pour. Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts [J]. 能源化学(英文), 2010, 19(6): 0-0.

Ahmad Tavasoli Ali Nakhaei Pour. Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts[J]. Journal of Energy Chemistry, 2010, 19(6): 0-0.

参考文献

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Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts

Kinetics and products distribution studies on Ruthenium promoted Cobalt/Alumina Fischer-Tropsch Synthesis catalysts

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