Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3·6H2O/BF3·(Et)2O in ethanol

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (1): 93-97.

Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl₃·6H₂O/BF₃·(Et)₂O in ethanol

Xiuquan Jia^a,b, Jiping Ma^a, Penghua Che^a,b, Fang Lu^a, Hong Miao^a, Jin Gao^a, Jie Xu^a*

a. Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,
Dalian 116023, Liaoning, China; b. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2012-11-12 修回日期:2013-01-10 出版日期:2013-01-20 发布日期:2013-02-06
通讯作者: 徐杰

Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl₃·6H₂O/BF₃·(Et)₂O in ethanol

Xiuquan Jia^a,b, Jiping Ma^a, Penghua Che^a,b, Fang Lu^a, Hong Miao^a, Jin Gao^a, Jie Xu^a*

a. Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,
Dalian 116023, Liaoning, China; b. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2012-11-12 Revised:2013-01-10 Online:2013-01-20 Published:2013-02-06

摘要/Abstract

摘要： Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (EMF) catalyzed by Lewis acid in ethanol was investigated. It was found that BF₃·(Et)₂O was favorable for 5-hydroxymethylfurfural (HMF) etherification to EMF. BF₃·(Et)₂O combination with AlCl₃·6H₂O with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively.

关键词: carbohydrates, 5-ethoxymethylfurfural, catalysis, Lewis acid

Abstract: Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (EMF) catalyzed by Lewis acid in ethanol was investigated. It was found that BF₃·(Et)₂O was favorable for 5-hydroxymethylfurfural (HMF) etherification to EMF. BF₃·(Et)₂O combination with AlCl₃·6H₂O with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively.

Key words: carbohydrates, 5-ethoxymethylfurfural, catalysis, Lewis acid

Xiuquan Jia, Jiping Ma, Penghua Che, Fang Lu, Hong Miao, Jin Gao, Jie Xu* . Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl₃·6H₂O/BF₃·(Et)₂O in ethanol[J]. 能源化学(英文), 2013, 22(1): 93-97.

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Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl₃·6H₂O/BF₃·(Et)₂O in ethanol

Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl₃·6H₂O/BF₃·(Et)₂O in ethanol

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