Review of Directly Producing Light Olens via CO Hydrogenation

摘要/Abstract

摘要： Directly making light olens via CO hydrogenation is a promising process to obtain a nonpetroleum based supply of alkenes. Limited by the ASF distribution function of Fischer-Tropsch synthesis, the yield of light olefins (C2-C4) can not reach the desired levels, which is a great challenge to overcome. Beginning with a brief introduction of F-T synthesis, this paper provides a review of current research, including thermodynamic analysis, the ASF distribution function, the reaction performance of CO hydrogenation and slurry reactor studies. The problems currently faced by this research area are presented at the end of the article.

关键词: light olen, Fischer-Tropsch synthesis, iron based catalyst, promoter, CO hydrogenation

Abstract: Directly making light olens via CO hydrogenation is a promising process to obtain a nonpetroleum based supply of alkenes. Limited by the ASF distribution function of Fischer-Tropsch synthesis, the yield of light olefins (C2-C4) can not reach the desired levels, which is a great challenge to overcome. Beginning with a brief introduction of F-T synthesis, this paper provides a review of current research, including thermodynamic analysis, the ASF distribution function, the reaction performance of CO hydrogenation and slurry reactor studies. The problems currently faced by this research area are presented at the end of the article.

Key words: light olen, Fischer-Tropsch synthesis, iron based catalyst, promoter, CO hydrogenation

Chong Wang;Longya Xu;Qingxia Wang. Review of Directly Producing Light Olens via CO Hydrogenation[J]. 能源化学(英文), 2003, 12 (1): 10-16.

Chong Wang;Longya Xu;Qingxia Wang. Review of Directly Producing Light Olens via CO Hydrogenation[J]. Journal of Energy Chemistry, 2003, 12 (1): 10-16.

[1]	Teng Lv, Wei Weng, Jing Zhou,dong Gu, Wei Xiao. Effects of K and Mn promoters over Fe₂O₃ on Fischer-Tropsch synthesis[J]. 能源化学(英文版), 2020, 47(8): 118-127.
[2]	Fanfei Sun, Ruoou Yang, Zhaoming Xia, Yuqi Yang, Ziang Zhao, Songqi Gu, Dongshuang Wu, Yunjie Ding, Zheng Jiang. Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts[J]. 能源化学(英文版), 2020, 42(3): 227-232.
[3]	Ting Kuang, Shuai Lyu, Sixu Liu, Yuhua Zhang, Jinlin Li, Guanghui Wang, Li Wang. Controlled synthesis of cobalt nanocrystals on the carbon spheres for enhancing Fischer-Tropsch synthesis performance[J]. 能源化学(英文), 2019, 28(6): 67-73.
[4]	Israf Ud Din, Maizatul S. Shaharun, A. Naeem, S Tasleem, Pervaiz Ahmad. Revalorization of CO₂ for methanol production via ZnO promoted carbon nanofibers based Cu-ZrO₂ catalytic hydrogenation[J]. 能源化学(英文版), 2019, 39(12): 68-76.
[5]	Jafar Shariati, Ali Haghtalab, Amir Mosayebi. Fischer-Tropsch synthesis using Co and Co-Ru bifunctional nanocatalyst supported on carbon nanotube prepared via chemical reduction method[J]. 能源化学(英文), 2019, 33(1): 9-22.
[6]	Suthasinee Pengnarapat, Peipei Ai, Prasert Reubroycharoen, Tharapong Vitidsant, Yoshiharu Yoneyama, Noritatsu Tsubaki. Active Fischer-Tropsch synthesis Fe-Cu-K/SiO₂ catalysts prepared by autocombustion method without a reduction step[J]. 能源化学(英文), 2018, 27(2): 432-438.
[7]	Xuan Deng, Yong-Jun Liu, Wei Huang. Higher alcohols synthesis from syngas over lanthanum-promoted CuZnAl catalyst[J]. 能源化学(英文), 2018, 27(1): 319-325.
[8]	Lisheng Guo, Jian Sun, Jian Wei, Zhiyong Wen, Hengyong Xu, Qingjie Ge. Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters[J]. 能源化学(英文), 2017, 26(4): 632-638.
[9]	Ali Nakhaei Pour, Mohammad Reza Housaindokht. A new kinetic model for direct CO₂ hydrogenation to higher hydrocarbons on a precipitated iron catalyst: Effect of catalyst particle size[J]. 能源化学(英文), 2017, 26(3): 359-367.
[10]	Yizhi Xiang, Norbert Kruse. Cobalt-copper based catalysts for higher terminal alcohols synthesis via Fischer-Tropsch reaction[J]. 能源化学(英文), 2016, 25(6): 895-906.
[11]	Di Wang, Bingxu Chen, Xuezhi Duan, De Chen, Xinggui Zhou. Iron-based Fischer-Tropsch synthesis of lower olefins: The nature of χ-Fe₅C₂ catalyst and why and how to introduce promoters[J]. 能源化学(英文), 2016, 25(6): 911-916.
[12]	Martin Oschatz, Nynke Krans, Jingxiu Xie, Krijn P. de Jong. Systematic variation of the sodium/sulfur promoter content on carbon-supported iron catalysts for the Fischer-Tropsch to olefins reaction[J]. 能源化学(英文), 2016, 25(6): 985-993.
[13]	Chuang Xing, Peipei Ai, Peipei Zhang, Xinhua Gao, Ruiqin Yang, Noriyuki Yamane, Jian Sun, Prasert Reubroycharoen, Noritatsu Tsubaki. Fischer-Tropsch synthesis on impregnated cobalt-based catalysts:New insights into the effect of impregnation solutions and pH value[J]. 能源化学(英文), 2016, 25(6): 994-1000.
[14]	Zhen Dong, Tao Wang, Jie Zhao, Teng Fu, Li Wang, Jinlin Li, Weiping Ding. Catalytic performance of iron oxide loaded on electron-rich surfaces of carbon nitride[J]. 能源化学(英文), 2016, 25(6): 1021-1026.
[15]	Xuezhi Duan, Di Wang, Gang Qian, John C. Walmsley, Anders Holmen, De Chen, Xinggui Zhou. Fabrication of K-promoted iron/carbon nanotubes composite catalysts for the Fischer-Tropsch synthesis of lower olefins[J]. 能源化学(英文), 2016, 25(2): 311-317.

Review of Directly Producing Light Olens via CO Hydrogenation

Review of Directly Producing Light Olens via CO Hydrogenation

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

Review of Directly Producing Light Ole ns via CO Hydrogenation

Review of Directly Producing Light Ole ns via CO Hydrogenation

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

Review of Directly Producing Light Olens via CO Hydrogenation

Review of Directly Producing Light Olens via CO Hydrogenation