Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

能源化学(英文) ›› 2002, Vol. 11 ›› Issue (1): 57-62.

Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

Fandong Meng, Genhui Xu, Baowei Wang, Xinbin Ma

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

出版日期:2002-03-30 发布日期:2002-03-30

Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

Fandong Meng, Genhui Xu, Baowei Wang, Xinbin Ma

Online:2002-03-30 Published:2002-03-30

摘要/Abstract

摘要： This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.

关键词: CO coupling, diethyl oxalate, kinetics and mechanism, simulation, scale-up test

Abstract: This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.

Key words: CO coupling, diethyl oxalate, kinetics and mechanism, simulation, scale-up test

Fandong Meng;Genhui Xu;Baowei Wang;Xinbin Ma. Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide[J]. 能源化学(英文), 2002, 11 (1): 57-62.

Fandong Meng;Genhui Xu;Baowei Wang;Xinbin Ma. Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide[J]. Journal of Energy Chemistry, 2002, 11 (1): 57-62.

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Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

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