Adaptation of Cu/ZnO/Al2O3 to Temperature Change in Methanol Synthesis from CO2

摘要/Abstract

摘要： The induction behavior in CO2 hydrogenation was studied by varying the reaction temperature to investigate the adaptation of the Cu/ZnO/Al2O3 catalyst to the temperature change. The results indicated that a used catalyst had a tendency to keep the last running state in new reaction conditions for MeOH formation, and that this tendency was related to the dierence in Cu/Cun+ ratio caused by CO2 and CO produced at dierent reaction temperatures. However, the reverse water-gas shift reaction (RWGS) induced at four temperatures was completely dierent from that of methanol synthesis. It implied that the two so-called competitive reactions in CO2+H2, RWGS and methanol synthesis, have dierent active centers.

关键词: induction, Cu/ZnO/Al2O3 catalyst, methanol, adaptation

Abstract: The induction behavior in CO2 hydrogenation was studied by varying the reaction temperature to investigate the adaptation of the Cu/ZnO/Al2O3 catalyst to the temperature change. The results indicated that a used catalyst had a tendency to keep the last running state in new reaction conditions for MeOH formation, and that this tendency was related to the dierence in Cu/Cun+ ratio caused by CO2 and CO produced at dierent reaction temperatures. However, the reverse water-gas shift reaction (RWGS) induced at four temperatures was completely dierent from that of methanol synthesis. It implied that the two so-called competitive reactions in CO2+H2, RWGS and methanol synthesis, have dierent active centers.

Key words: induction, Cu/ZnO/Al2O3 catalyst, methanol, adaptation

Jialin Tao;Ki-Won Jun;Kyu-Wan Lee. Adaptation of Cu/ZnO/Al2O3 to Temperature Change in Methanol Synthesis from CO2[J]. 能源化学(英文), 2002, 11 (1): 63-69.

Jialin Tao;Ki-Won Jun;Kyu-Wan Lee. Adaptation of Cu/ZnO/Al2O3 to Temperature Change in Methanol Synthesis from CO2[J]. Journal of Energy Chemistry, 2002, 11 (1): 63-69.

[1]	Wenna Zhang, Shutao Xu, Yuchun Zhi, Yingxu Wei, Zhongmin Liu. Methylcyclopentenyl cation mediated reaction route in methanol-to-olefins reaction over H-RUB-50 with small cavity[J]. 能源化学(英文版), 2020, 45(6): 25-30.
[2]	Mao Wen, Xue-Ying Zhang, Min-Hua Zong, Ning Li. Significantly improved oxidation of bio-based furans into furan carboxylic acids using substrate-adapted whole cells[J]. 能源化学(英文版), 2020, 41(2): 20-26.
[3]	Xiaoyu Yue, Yuguang Pu, Wen Zhang, Ting Zhang, Wei Gao. Ultrafine Pt nanoparticles supported on double-shelled C/TiO₂ hollow spheres material as highly efficient methanol oxidation catalysts[J]. 能源化学(英文版), 2020, 49(10): 275-282.
[4]	Jialong Li, Lei Zhao, Xifei Li, Sue Hao, Zhenbo Wang. Fabrication of C@Mo_xTi_1-xO_2-δ nanocrystalline with functionalized interface as efficient and robust PtRu catalyst support for methanol electrooxidation[J]. 能源化学(英文版), 2020, 40(1): 7-14.
[5]	Weiwei Wang, Zhenping Qu, Lixin Song, Qiang Fu. CO₂ hydrogenation to methanol over Cu/CeO₂ and Cu/ZrO₂ catalysts: Tuning methanol selectivity via metal-support interaction[J]. 能源化学(英文版), 2020, 40(1): 22-30.
[6]	Camelia Berghian-Grosan, Teodora Radu, Alexandru R. Biris, Monica Dan, Cezara Voica, Fumiya Watanabe, Alexandru S. Biris, Adriana Vulcu. Platinum nanoparticles coated by graphene layers: A low-metal loading catalyst for methanol oxidation in alkaline media[J]. 能源化学(英文版), 2020, 40(1): 81-88.
[7]	Qingyun Hu, Wei Zhan, Yifei Guo, Laiming Luo, Ronghua Zhang, Di Chen, Xinwen Zhou. Heat treatment bimetallic PdAu nanocatalyst for oxygen reduction reaction[J]. 能源化学(英文版), 2020, 40(1): 217-223.
[8]	Adhitya G. Saputro, Refaldi I. D. Putra, Arifin L. Maulana, Muhammad U. Karami, Mochamad R. Pradana, Mohammad K. Agusta, Hermawan K. Dipojono, Hideaki Kasai. Theoretical study of CO₂ hydrogenation to methanol on isolated small Pd_x clusters[J]. 能源化学(英文), 2019, 28(8): 79-87.
[9]	N. Gutiérrez-Guerra, J. A. González, J. C. Serrano-Ruiz, E. López-Fernández, J. L. Valverde, A. de Lucas-Consuegra. Gas-phase electrocatalytic conversion of CO₂ to chemicals on sputtered Cu and Cu-C catalysts electrodes[J]. 能源化学(英文), 2019, 28(4): 46-53.
[10]	Enrico Catizzone, Massimo Migliori, Antonio Purita, Girolamo Giordano. Ferrierite vs. γ-Al₂O₃:The superiority of zeolites in terms of water-resistance in vapour-phase dehydration of methanol to dimethyl ether[J]. 能源化学(英文), 2019, 28(3): 162-169.
[11]	Fan Yang, Bing Zhang, Sen Dong, Chunxia Wang, Andong Feng, Xiaoxu Fan, Yongfeng Li. Reduced graphene oxide supported Pd-Cu-Co trimetallic catalyst: synthesis, characterization and methanol electrooxidation properties[J]. 能源化学(英文), 2019, 28(2): 72-78.
[12]	Gracita M. Tomboc, Medhen W. Abebe, Anteneh F. Baye, Hern Kim. Utilization of the superior properties of highly mesoporous PVP modified NiCo₂O₄ with accessible 3D nanostructure and flower-like morphology towards electrochemical methanol oxidation reaction[J]. 能源化学(英文), 2019, 28(2): 136-146.
[13]	Israf Ud Din, Maizatul S. Shaharun, A. Naeem, S Tasleem, Pervaiz Ahmad. Revalorization of CO₂ for methanol production via ZnO promoted carbon nanofibers based Cu-ZrO₂ catalytic hydrogenation[J]. 能源化学(英文版), 2019, 39(12): 68-76.
[14]	Liang Liang, Meiling Xiao, Jianbing Zhu, Junjie Ge, Changpeng Liu, Wei Xing. Low-temperature synthesis of nitrogen doped carbon nanotubes as promising catalyst support for methanol oxidation[J]. 能源化学(英文), 2019, 33(1): 118-122.
[15]	Liyuan Gong, Zhiyuan Yang, Kui Li, Wei Xing, Changpeng Liu, Junjie Ge. Recent development of methanol electrooxidation catalysts for direct methanol fuel cell[J]. 能源化学(英文), 2018, 27(6): 1618-1628.