1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (1): 145-150.

1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period

Xiujie Li^a*, Xiangxue Zhu^a, Dazhou Zhang^a, Fucun Chen^a, Peng Zeng^b, Shenglin Liu^a, Sujuan Xie^a, Longya Xu^a*

a. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b. Liaoning Branches, China Huanqiu Contracting & Engineering Corporation, Fushun 113006, Liaoning, China

收稿日期:2012-11-12 修回日期:2013-01-10 出版日期:2013-01-20 发布日期:2013-02-06
通讯作者: Xiujie Li
基金资助:
复合载体多相Mo基催化剂上烯烃歧化反应诱导期的调控

1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period

Xiujie Li^a*, Xiangxue Zhu^a, Dazhou Zhang^a, Fucun Chen^a, Peng Zeng^b, Shenglin Liu^a, Sujuan Xie^a, Longya Xu^a*

a. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b. Liaoning Branches, China Huanqiu Contracting & Engineering Corporation, Fushun 113006, Liaoning, China

Received:2012-11-12 Revised:2013-01-10 Online:2013-01-20 Published:2013-02-06
Contact: Xiujie Li

摘要/Abstract

摘要： Effects of space velocity, reaction temperature and support acidity on product distribution and induction period in 1-butene isomerization and metathesis over Mo/mordenite-alumina were investigated. As revealed by the catalytic performance results, induction period and objective product were closely related to the reaction conditions. Lower space velocity led to longer induction period and higher propene yield. The optimal reaction temperature for propene production is around 150 ℃ and it shifted to 100 ℃ for ethene production. 1-Butene auto-metathesis predominated in the reaction network if the support with lower degree of sodium exchanged. And propene gradually became the dominant product upon increasing the support sodium exchange degree. 6Mo/H₁₀₀Na₀M-30Al catalyst with a support of full sodium exchange degree exhibited the highest propene yield.

关键词: 1-butene, metathesis, propene, molybdenum, production distribution, induction period

Abstract: Effects of space velocity, reaction temperature and support acidity on product distribution and induction period in 1-butene isomerization and metathesis over Mo/mordenite-alumina were investigated. As revealed by the catalytic performance results, induction period and objective product were closely related to the reaction conditions. Lower space velocity led to longer induction period and higher propene yield. The optimal reaction temperature for propene production is around 150 ℃ and it shifted to 100 ℃ for ethene production. 1-Butene auto-metathesis predominated in the reaction network if the support with lower degree of sodium exchanged. And propene gradually became the dominant product upon increasing the support sodium exchange degree. 6Mo/H₁₀₀Na₀M-30Al catalyst with a support of full sodium exchange degree exhibited the highest propene yield.

Key words: 1-butene, metathesis, propene, molybdenum, production distribution, induction period

Xiujie Li*, Xiangxue Zhu, Dazhou Zhang, Fucun Chen, Peng Zeng, Shenglin Liu. 1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period[J]. 能源化学(英文), 2013, 22(1): 145-150.

Xiujie Li*, Xiangxue Zhu, Dazhou Zhang, Fucun Chen, Peng Zeng, Shenglin Liu, Sujuan Xie, Longya Xu* . 1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period[J]. Journal of Energy Chemistry, 2013, 22(1): 145-150.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.jenergychem.com/CN/

https://www.jenergychem.com/CN/Y2013/V22/I1/145

参考文献

[1] Zhu X X, Li X J, Xie S J, Liu S L, Xu G L, Xin W J, Huang S J, Xu L Y. Catal Survey Asia, 2009, 13(1): 1
[2] Zhu X X, Liu S L, Song Y Q, Xu L Y. Appl Catal A, 2005, 288(1-2): 134
[3] Liu Z M, Sun C L, Wang G W, Wang Q X, Cai G Y. Fuel Process Technol, 2000, 62(2-3): 161
[4] Mol J C. Catal Today, 1999, 51(2): 289
[5] Mol J C. J Mol Catal A, 2004, 213(1): 39
[6] Liu S L, Li X J, Xin W J, Xie S J, Zeng P, Zhang L X, Xu L Y. J Nat Gas Chem, 2010, 19(5): 482
[7] Phongsawat W, Netiworaruksa B, Suriye K, Dokjampa S, Praserthdam P, Panpranot J. J Nat Gas Chem, 2012, 21(2): 158
[8] Zhang D Z, Li X J, Liu S L, Zhu X X, Xin W J, Xie S J, Zeng P, Xu L Y. Chin J Catal (Cuihua Xuebao), 2011, 32(11): 1747
[9] Debecker D P, Schimmoeller B, Stoyanova M, Poleunis C, Bertrand P, Rodemerck U, Gaigneaux E M. J Catal, 2011, 277(2): 154
[10] Gerhard Ertl, Helmut Kn\"{o}zinger, Ferdi Sch\"{u}th, Weitkamp J. Handbook of Heterogeneous Catalysis. 2nd Ed. Wiley-VCH, 2008. 3240
[11] Harmse L, van Schalkwyk C, van Steen E. Catal Lett, 2010, 137(3-4): 123
[12] Hua D R, Chen S L, Yuan G M, Wang Y L, Zhao Q F, Wang X L, Fu B. Microporous Mesoporous Mater, 2011, 143(2-3): 320
[13] Wang Y D, Chen Q L, Yang W M, Xie Z K, Xu W, Huang D. Appl Catal A, 2003, 250(1): 25
[14] Sang L, Chen S L, Yuan G M, Zheng M, You J, Chen A C, Li R, Chen L J. J Nat Gas Chem, 2012, 21(2): 105
[15] Sang L, Chen S L, Yuan G M, Zhou Z, Li R, Chen A C, Zheng M, You J. J Nat Gas Chem, 2012, 21(3): 352
[16] Liu H J, Zhang L, Li X J, Huang S J, Liu S L, Xin W J, Xie S J, Xu L Y. J Nat Gas Chem, 2009, 18(3): 331
[17] Huang S J, Liu H J, Zhang L, Liu S L, Xin W J, Li X J, Xie S J, Xu L Y. Appl Catal A, 2011, 404 (1-2): 113
[18] Liu H J, Huang S J, Zhang L, Liu S L, Wang W, Xin W J, Xie S J, Xu L Y. Chin J Catal (Cuihua Xuebao), 2008, 29(6): 513
[19] Andreini A, Mol J C. J Chem Soc Faraday Trans1, 1985, 81: 1705
[20] Gangwal S K, Fathikalajahi J, Wills G B. Ind Eng Chem Res, 1977, 16(3): 237
[21] Zhang D Z, Li X J, Liu S L, Huang S J, Zhu X X, Chen F C, Xie S J, Xu L Y. Appl Catal A, 2012, 439: 171

1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period

1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Sasan Ghashghaie, Samson Ho-Sum Cheng, Jie Fang, Hafiz Khurram Shahzad, Robin Lok-Wang Ma, chi-Yuen Chung. Electrophoretically deposited binder-free 3-D carbon/sulfur nanocomposite cathode for high-performance Li-S batteries[J]. 能源化学(英文版), 2020, 48(9): 92-101.
[2]	Jing-Qi Chi, Min Yang, Yong-Ming Chai, Zhi Yang, Lei Wang, bin Dong. Design and modulation principles of molybdenum carbide-based materials for green hydrogen evolution[J]. 能源化学(英文版), 2020, 48(9): 398-423.
[3]	Jun Zhao, Zijia Yin,baowei Wang, Zhenhua Li, Yan Xu, Xinbin Ma. Phytic acid-derived fabrication of ultra-small MoP nanoparticles for efficient CO methanation: Effects of P/Mo ratios[J]. 能源化学(英文版), 2020, 47(8): 248-255.
[4]	Hao Zhang, Haiyan Jin, Yuqi Yang, Fanfei Sun, Yang Liu, Xianlong Du, Shuo Zhang, Fei Song, Jianqiang Wang, Yong Wang, Zheng Jiang. Understanding the synergetic interaction within α-MoC/β-Mo₂C heterostructured electrocatalyst[J]. 能源化学(英文), 2019, 28(8): 66-70.
[5]	Vaidheeshwar Ramasubramanian, Hema Ramsurn, Geoffrey L. Price. Methane dehydroaromatization-A study on hydrogen use for catalyst reduction, role of molybdenum, the nature of catalyst support and significance of Bronsted acid sites[J]. 能源化学(英文), 2019, 28(7): 20-32.
[6]	Jin-Tao Ren, Yue-Jun Song, Zhong-Yong Yuan. Facile synthesis of molybdenum carbide nanoparticles in situ decorated on nitrogen-doped porous carbons for hydrogen evolution reaction[J]. 能源化学(英文), 2019, 28(5): 78-84.
[7]	Angela Daisley, Justin S. J. Hargreaves. The role of interstitial species upon the ammonia synthesis activity of ternary Fe-Mo-C(N) and Ni-Mo-C(N) phases[J]. 能源化学(英文版), 2019, 39(12): 170-175.
[8]	Yue-Jun Song, Jin-Tao Ren, Gege Yuan, Yali Yao, Xinying Liu, Zhong-Yong Yuan. Facile synthesis of Mo₂C nanoparticles on N-doped carbon nanotubes with enhanced electrocatalytic activity for hydrogen evolution and oxygen reduction reactions[J]. 能源化学(英文版), 2019, 38(11): 68-77.
[9]	Tingting Cui, Jinhu Dong, Xiulian Pan, Tie Yu, Qiang Fu, Xinhe Bao. Enhanced hydrogen evolution reaction over molybdenum carbide nanoparticles confined inside single-walled carbon nanotubes[J]. 能源化学(英文), 2019, 33(1): 123-127.
[10]	Yan Han, Yu Ge, Yunfeng Chao, Caiyun Wang, Gordon G. Wallace. Recent progress in 2D materials for flexible supercapacitors[J]. 能源化学(英文), 2018, 27(1): 57-72.
[11]	Anatoliy N. Nesterov, Aleksey M. Reshetnikov, Andrey Yu. Manakov, Tatyana P. Adamova. Synergistic effect of combination of surfactant and oxide powder on enhancement of gas hydrates nucleation[J]. 能源化学(英文), 2017, 26(4): 808-814.
[12]	R. Senthilkumar, G. Anandhababu, T. Mahalingam, G. Ravi. Photoelectrochemical study of MoO₃assorted morphology films formed by thermal evaporation[J]. 能源化学(英文), 2016, 25(5): 798-804.
[13]	Jiayuan Li, Dunfeng Gao, Jing Wang, Shu Miao, Guoxiong Wang, Xinhe Bao. Ball-milling MoS₂/carbon black hybrid material for catalyzing hydrogen evolution reaction in acidic medium[J]. 能源化学(英文), 2015, 21(5): 608-613.
[14]	Dunfeng Gao, Fan Cai, Qinqin Xu, Guoxiong Wang, Xiulian Pan, Xinhe Bao. Gas-phase electrocatalytic reduction of carbon dioxide using electrolytic cell based on phosphoric acid-doped polybenzimidazole membrane[J]. 能源化学(英文), 2014, 23(6): 694-700.
[15]	Xiao Liu, Hongmin Wang, Siguo Chen, Xueqiang Qi, Huiliang Gao, Yi Hui, Yang Bai, Lin Guo, Wei Ding, Zidong Wei. SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction[J]. 能源化学(英文), 2014, 23(3): 358-362.