Hydrate capture CO2 from shifted synthesis gas, flue gas and sour natural gas or biogas

摘要/Abstract

摘要： CO₂ capture by hydrate formation is a novel gas separation technology, by which CO₂ is selectively engaged in the cages of hydrate and is separated with other gases, based on the differences of phase equilibrium for CO₂ and other gases. However, rigorous temperature and pressure, high energy cost and industrialized hydration separator dragged the development of the hydrate based CO₂ capture. In this paper, the key problems in CO₂ capture from the different sources such as shifted synthesis gas, flue gas and sour natural gas or biogas were analyzed. For shifted synthesis gas and flue gas, its high energy consumption is the barrier, and for the sour natural gas or biogas (CO₂/CH₄ system), the bottleneck is how to enhance the selectivity of CO₂ hydration. For these gases, scale-up is the main difficulty. Also, this paper explored the possibility of separating different gases by selective hydrate formation and reviewed the progress of CO₂ separation from shifted synthesis gas, flue gas and sour natural gas or biogas.

关键词: clathrate hydrate, CO2 capture, hydrogen, shifted synthesis gas, flue gas, sour natural gas or biogas

Abstract: CO₂ capture by hydrate formation is a novel gas separation technology, by which CO₂ is selectively engaged in the cages of hydrate and is separated with other gases, based on the differences of phase equilibrium for CO₂ and other gases. However, rigorous temperature and pressure, high energy cost and industrialized hydration separator dragged the development of the hydrate based CO₂ capture. In this paper, the key problems in CO₂ capture from the different sources such as shifted synthesis gas, flue gas and sour natural gas or biogas were analyzed. For shifted synthesis gas and flue gas, its high energy consumption is the barrier, and for the sour natural gas or biogas (CO₂/CH₄ system), the bottleneck is how to enhance the selectivity of CO₂ hydration. For these gases, scale-up is the main difficulty. Also, this paper explored the possibility of separating different gases by selective hydrate formation and reviewed the progress of CO₂ separation from shifted synthesis gas, flue gas and sour natural gas or biogas.

Key words: clathrate hydrate, CO2 capture, hydrogen, shifted synthesis gas, flue gas, sour natural gas or biogas

Yanhong Wang, Xuemei Lang, Shuanshi Fan* . Hydrate capture CO₂ from shifted synthesis gas, flue gas and sour natural gas or biogas[J]. 能源化学(英文), 2013, 22(1): 39-47.

Yanhong Wang, Xuemei Lang, Shuanshi Fan* . Hydrate capture CO₂ from shifted synthesis gas, flue gas and sour natural gas or biogas[J]. Journal of Energy Chemistry, 2013, 22(1): 39-47.

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Hydrate capture CO₂ from shifted synthesis gas, flue gas and sour natural gas or biogas

Hydrate capture CO₂ from shifted synthesis gas, flue gas and sour natural gas or biogas

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