Ammonia-treatment assisted fully encapsulation of Fe2O3 nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (2): 329-335.

Ammonia-treatment assisted fully encapsulation of Fe₂O₃ nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries

Fei Han, Wen-Cui Li, Duo Li, An-Hui Lu

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning, China

收稿日期:2012-10-27 修回日期:2012-12-29 出版日期:2013-03-20 发布日期:2013-04-04
通讯作者: An-Hui Lu
基金资助:
This work was supported by the Fundamental Research Funds for the Central Universities (Grant No. DUT12ZD218), the National Natural Science Foundation of China (Grant No. 21103184), and the Ph. D. Programs Foundation (Grant No. 20100041110017) of Ministry of Education of China.

Ammonia-treatment assisted fully encapsulation of Fe₂O₃ nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries

Fei Han, Wen-Cui Li, Duo Li, An-Hui Lu

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2012-10-27 Revised:2012-12-29 Online:2013-03-20 Published:2013-04-04
Supported by:
This work was supported by the Fundamental Research Funds for the Central Universities (Grant No. DUT12ZD218), the National Natural Science Foundation of China (Grant No. 21103184), and the Ph. D. Programs Foundation (Grant No. 20100041110017) of Ministry of Education of China.

摘要/Abstract

摘要： To improve the initial coulombic efficiency and bulk density of ordered mesoporous carbons, active Fe₂O₃ nanoparticles were introduced into tubular mesopore channels of CMK-5 carbon, which possesses high specific surface area (>1700 m²穏^-1) and large pore volume (>1.8 cm³穏^-1). Fine Fe₂O₃ nanoparticles with sizes in the range of 5-7 nm were highly and homogenously encapsulated into CMK-5 matrix through ammonia-treatment and subsequent pyrolysis method. The Fe₂O₃ loading was carefully tailored and designed to warrant a high Fe₂O₃ content and adequate buffer space for improving the electrochemical performance. In particular, such Fe₂O₃ and mesoporous carbon composite with 47 wt% loading exhibits a considerably stable cycle performance (683 mAh穏^-1 after 100 cycles, 99% capacity retention against that of the second cycle) as well as good rate capability. The fabrication strategy can effectively solve the drawback of single material, and achieve a high-performance lithium electrode material.

关键词: ordered mesoporous carbon, Fe₂O₃ nanoparticle, cycle stability, lithium-ion anode

Abstract: To improve the initial coulombic efficiency and bulk density of ordered mesoporous carbons, active Fe₂O₃ nanoparticles were introduced into tubular mesopore channels of CMK-5 carbon, which possesses high specific surface area (>1700 m²穏^-1) and large pore volume (>1.8 cm³穏^-1). Fine Fe₂O₃ nanoparticles with sizes in the range of 5-7 nm were highly and homogenously encapsulated into CMK-5 matrix through ammonia-treatment and subsequent pyrolysis method. The Fe₂O₃ loading was carefully tailored and designed to warrant a high Fe₂O₃ content and adequate buffer space for improving the electrochemical performance. In particular, such Fe₂O₃ and mesoporous carbon composite with 47 wt% loading exhibits a considerably stable cycle performance (683 mAh穏^-1 after 100 cycles, 99% capacity retention against that of the second cycle) as well as good rate capability. The fabrication strategy can effectively solve the drawback of single material, and achieve a high-performance lithium electrode material.

Key words: ordered mesoporous carbon, Fe₂O₃ nanoparticle, cycle stability, lithium-ion anode

Fei Han, Wen-Cui Li, Duo Li, An-Hui Lu. Ammonia-treatment assisted fully encapsulation of Fe₂O₃ nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries[J]. 能源化学(英文), 2013, 22(2): 329-335.

参考文献

[1] Li H, Wang Z X, Chen L Q, Huang X J. Adv Mater, 2009, 21(45): 4593
[2] Cheng F Y, Liang J, Tao Z L, Chen J. Adv Mater, 2011, 23(15): 1695
[3] Li H Q, Zhou H S. Chem Commun, 2012, 48(9): 1201
[4] Han F, Li W C, Li M R, Lu A H. J Mater Chem, 2012, 22(19): 9645
[5] Hao G P, Han F, Guo D C, Fan R J, Xiong G, Li W C, Lu A H. J Phys Chem C, 2012, 116(18): 10303
[6] Sun Q, Zhang X Q, Han F, Li W C, Lu A H. J Mater Chem, 2012, 22(33): 17049
[7] Wang H Y, Abe T, Maruyama S, Iriyama Y, Ogumi Z, Yoshikawa K. Adv Mater, 2005, 17(23): 2857
[8] Zhang J, Hu Y S, Tessonnier J P, Weinberg G, Maier J, Schlögl R, Su D S. Adv Mater, 2008, 20(8): 1450
[9] Shin W H, Jeong H M, Kim B G, Kang J K, Choi J W. Nano Lett, 2012, 12(5): 2283
[10] Han F D, Bai Y J, Liu R, Yao B, Qi Y X, Lun N, Zhang J X. Adv Energy Mater, 2011, 1(5): 798
[11] Kim M S, Fang B Z, Kim J H, Yang D, Kim Y K, Bae T S, Yu J S. J Mater Chem, 2011, 21(48): 19362
[12] Wu Z S, Xue L L, Ren W C, Li F, Wen L, Cheng H M. Adv Funct Mater, 2012, 22(15): 3290
[13] Jang B Z, Liu C G, Neff D, Yu Z N, Wang M C, Xiong W, Zhamu A. Nano Lett, 2011, 11(9): 3785
[14] Zhou H S, Zhu S M, Hibino M, Honma I, Ichihara M. Adv Mater, 2003, 15(24): 2107
[15] Hu Y S, Adelhelm P, Smarsly B M, Hore S, Antonietti M, Maier J. Adv Funct Mater, 2007, 17(12): 1873
[16] Liang C D, Li Z J, Dai S. Angew Chem Int Ed, 2008, 47(20): 3696
[17] Zhai Y P, Dou Y Q, Zhao D Y, Fulvio P F, Mayes R T, Dai S. Adv Mater, 2011, 23(42): 4828
[18] Kaskhedikar N A, Maier J. Adv Mater, 2009, 21(25-26): 2664
[19] Mao Y, Duan H, Xu B, Zhang L, Hu Y S, Zhao C C, Wang Z X, Chen L Q, Yang Y S. Energy Environ Sci, 2012, 5(7): 7950
[20] Nishihara H, Kyotani T. Adv Mater, 2012, 24(33): 4473
[21] Han F, Li D, Li W C, Lei C, Sun Q, Lu A H. Adv Funct Mater, 2012, DOI: 10.1002/adfm.201202254
[22] Kim H, Cho J. Nano Lett, 2008, 8(11): 3688
[23] Zhu S M, Zhou H A, Hibino M, Honma I, Ichihara M. Adv Funct Mater, 2005, 15(3): 381
[24] Yu W J, Hou P X, Zhang L L, Li F, Liu C, Cheng H M. Chem Commun, 2010, 46(45): 8576
[25] Wang Z Y, Luan D Y, Madhavi S, Hu Y, Lou X W. Energy Environ Sci, 2012, 5(1): 5252
[26] Nagao M, Otani M, Tomita H, Kanzaki S, Yamada A, Kanno R. J Power Sources, 2011, 196(10): 4741
[27] Lu A H, Nitz J J, Comotti M, Weidenthaler C, Schlichte K, Lehmann C W, Terasaki O, Schüth F. J Am Chem Soc, 2010, 132(40): 14152
[28] Wu Z X, Li W, Webley P A, Zhao D Y. Adv Mater, 2012, 24(4): 485
[29] Lu A H, Schmidt W, Spliethoff B, Schüth F. Adv Mater, 2003, 15(19): 1602
[30] Lu A H, Li W C, Schmidt W, Kiefer W, Schüth F. Carbon, 2004, 42(14): 2939
[31] Sun B, Horvat J, Kim H S, Kim W S, Ahn J, Wang G X. J Phys Chem C, 2010, 114(44): 18753
[32] Zhou W, Lin L J, Wang W J, Zhang L L, Wu Q O, Li J H, Guo L. J Phys Chem C, 2011, 115(14): 7126
[33] Cherian C T, Sundaramurthy J, Kalaivani M, Ragupathy P, Kumar P S, Thavasi V, Reddy M V, Sow C H, Mhaisalkar S G, Ramakrishna S, Choudari B V R. J Mater Chem, 2012, 22(24): 12198
[34] Kang E, Jung Y S, Cavanagh A S, Kim G H, George S M, Dillon A C, Kim J K, Lee J. Adv Funct Mater, 2011, 21(13): 2430
[35] Wang Z Y, Luan D Y, Madhavi S, Li C M, Lou X W. Chem Commun, 2011, 47(28): 8061
[36] Ji L W, Toprakci O, Alcoutlabi M, Yao Y F, Li Y, Zhang S, Guo B K, Lin Z, Zhang X W. ACS Appl Mater Interfaces, 2012, 4(5): 2672
[37] Wang S Q, Zhang J Y, Chen C H. J Power Sources, 2010, 195(16): 5379

Ammonia-treatment assisted fully encapsulation of Fe₂O₃ nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries

Ammonia-treatment assisted fully encapsulation of Fe₂O₃ nanoparticles in mesoporous carbons as stable anodes for lithium ion batteries

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 6

编辑推荐

Metrics

[1]	Shubiao Xia, Wenjin Huang, Xiang Shen, Jiaming Liu, Feixiang Cheng, Jian-Jun Liu, Xiaofei Yang, Hong Guo. Rearrangement on surface structures by boride to enhanced cycle stability for LiNi_0.80Co_0.15Al_0.05O₂ cathode in lithium ion batteries[J]. 能源化学(英文版), 2020, 45(6): 110-118.
[2]	Fang Wang, Lv Li, Da Lei, Yongpeng Li, He Yang, Weili Zhu, Fengxiang Zhang. Quaternized polymer binder for lithium-sulfur batteries: The effect of cation structure on battery performance[J]. 能源化学(英文版), 2020, 43(4): 165-172.
[3]	Yanghua He, Jinming Xu, Fanan Wang, Xiaochen Zhao, Guangzhao Yin, Qing Mao, Yanqiang Huang, Tao Zhang. In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode[J]. 能源化学(英文), 2017, 26(6): 1140-1146.
[4]	Vincent Mirai Bau, Xiangjie Bo, Liping Guo. Nitrogen-doped cobalt nanoparticles/nitrogen-doped plate-like ordered mesoporous carbons composites as noble-metal free electrocatalysts for oxygen reduction reaction[J]. 能源化学(英文), 2017, 26(1): 63-71.
[5]	Anran Huang, Jingwang Yan, Hongzhang Zhang, Xianfeng Li, Huamin Zhang. Effect of the pore length and orientation upon the electrochemical capacitive performance of ordered mesoporous carbons[J]. 能源化学(英文), 2017, 26(1): 121-128.
[6]	Kun Xiong, Yuhua Zhang, Jinlin Li, Kongyong Liew. Catalytic properties of Ru nanoparticles embedded on ordered mesoporous carbon with different pore size in Fischer-Tropsch synthesis[J]. 能源化学(英文), 2013, 22(4): 560-566.