Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas

doi:10.1016/S1003-9953(10)60236-8

能源化学(英文) ›› 2011, Vol. 20 ›› Issue (6): 585-594.DOI: 10.1016/S1003-9953(10)60236-8

Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas

Wan Azelee Wan Abu Bakar*, Rusmidah Ali, Susilawati Toemen

Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia

收稿日期:2011-02-14 修回日期:2011-07-26 出版日期:2011-11-20 发布日期:2011-11-18
通讯作者: wan azelee wan abu bakar

Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas

Wan Azelee Wan Abu Bakar*, Rusmidah Ali, Susilawati Toemen

Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia

Received:2011-02-14 Revised:2011-07-26 Online:2011-11-20 Published:2011-11-18
Contact: wan azelee wan abu bakar

摘要/Abstract

摘要： In this research, new catalyst with high industrial impact is developed, which can catalyze the conversion of CO₂ to methane through methanation reaction. A series of catalysts based on nickel oxide were prepared using wetness impregnation technique and ageing, followed by calcination at 400 ℃. Rh/Ni (30 : 70)/Al₂O₃ catalyst was revealed as the most potential catalyst based on the results of catalytic activity measurement monitored by Fourier Transform Infrared Spectroscopy (FTIR) and Gas Chromatography (GC). The results showed 90.1% CO₂ conversion and 70.8% yield at 400 ℃.

关键词: noble metal, nickel oxide, catalyst, carbon dioxide, methanation

Abstract: In this research, new catalyst with high industrial impact is developed, which can catalyze the conversion of CO₂ to methane through methanation reaction. A series of catalysts based on nickel oxide were prepared using wetness impregnation technique and ageing, followed by calcination at 400 ℃. Rh/Ni (30 : 70)/Al₂O₃ catalyst was revealed as the most potential catalyst based on the results of catalytic activity measurement monitored by Fourier Transform Infrared Spectroscopy (FTIR) and Gas Chromatography (GC). The results showed 90.1% CO₂ conversion and 70.8% yield at 400 ℃.

Key words: noble metal, nickel oxide, catalyst, carbon dioxide, methanation

Wan Azelee Wan Abu Bakar*, Rusmidah Ali, Susilawati Toemen . Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas[J]. 能源化学(英文), 2011, 20(6): 585-594.

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Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas

Catalytic methanation reaction over supported nickel-rhodium oxide for purification of simulated natural gas

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