Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (1): 114-118.

Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor

Yousef Salamat^a, Abdolreza Moghadassi^a, Mohammad Illbeigi^b, Ali Eslamimanesh^c, Amir H. Mohammadi^d,e*

a. Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran; b. Chemical Engineering Department, Faculty of Engineering,
Isfahan University , Isfahan, Iran; c. Department of Chemical & Biomolecular Engineering, Clarkson University, Potsdam, NY 13699-5705, USA; d. Institut de Recherche
en Génie Chimique et Pétrolier (IRGCP), Paris Cedex, France; e. Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal,
Howard College Campus, King George V Avenue, Durban 4041, South Africa

收稿日期:2012-06-04 修回日期:2012-09-11 出版日期:2013-01-20 发布日期:2013-02-06
通讯作者: Ali Nakhaei Pour

Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor

Yousef Salamat^a, Abdolreza Moghadassi^a, Mohammad Illbeigi^b, Ali Eslamimanesh^c, Amir H. Mohammadi^d,e*

a. Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran; b. Chemical Engineering Department, Faculty of Engineering,
Isfahan University , Isfahan, Iran; c. Department of Chemical & Biomolecular Engineering, Clarkson University, Potsdam, NY 13699-5705, USA; d. Institut de Recherche
en Génie Chimique et Pétrolier (IRGCP), Paris Cedex, France; e. Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal,
Howard College Campus, King George V Avenue, Durban 4041, South Africa

Received:2012-06-04 Revised:2012-09-11 Online:2013-01-20 Published:2013-02-06
Contact: Ali Nakhaei Pour

摘要/Abstract

摘要： In this paper, the effect of adding different concentrations of kinetic inhibitors on the induction time of hydrogen sulfide hydrate formation in a reactor equipped with automatic adjustable temperature controller is studied. A novel method namely ``sudden cooling" is used for performing the relevant measurements, in which the induction time of H₂S hydrate in the presence/absence of PVP and L-tyrosine with different concentrations (100, 500, and 1000 ppm) is determined. As a result, PVP with the concentration of 1000 ppm in aqueous solution is detected as a more suitable material for increasing the induction time of H₂S hydrate formation among the investigated kinetic hydrate inhibitors.

关键词: hydrogen sulfide, gas hydrates, clathrate hydrates kinetic inhibitor, induction time, sudden cooling

Abstract: In this paper, the effect of adding different concentrations of kinetic inhibitors on the induction time of hydrogen sulfide hydrate formation in a reactor equipped with automatic adjustable temperature controller is studied. A novel method namely ``sudden cooling" is used for performing the relevant measurements, in which the induction time of H₂S hydrate in the presence/absence of PVP and L-tyrosine with different concentrations (100, 500, and 1000 ppm) is determined. As a result, PVP with the concentration of 1000 ppm in aqueous solution is detected as a more suitable material for increasing the induction time of H₂S hydrate formation among the investigated kinetic hydrate inhibitors.

Key words: hydrogen sulfide, gas hydrates, clathrate hydrates kinetic inhibitor, induction time, sudden cooling

Yousef Salamata, Abdolreza Moghadassi, Mohammad Illbeigi, Ali Eslamimanesh. Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor[J]. 能源化学(英文), 2013, 22(1): 114-118.

Yousef Salamata, Abdolreza Moghadassi, Mohammad Illbeigi, Ali Eslamimanesh, Amir H. Mohammadi* . Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor[J]. Journal of Energy Chemistry, 2013, 22(1): 114-118.

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Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor

Experimental study of hydrogen sulfide hydrate formation: Induction time in the presence and absence of kinetic inhibitor

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