Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (2): 174-182.

Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications

Volodymyr V. Strelko

Institute for Sorption and Problems of Endoecology of National Academy of Sciences of Ukraine, 13 General Naumov str., Kiev 03164, Ukraine

收稿日期:2012-11-20 修回日期:2013-02-19 出版日期:2013-03-20 发布日期:2013-04-04
通讯作者: Volodymyr V. Strelko
作者简介:Professor of chemistry: founder (1991) and director (1991-till now) of the institute for sorption and problems of endoecology (ISPE), national academy of sciences of Ukraine (NASU); head of the department for sorption and f ine inorganic synthesis of ISPE; academician (full member) of NASU (1995). Main fields of the scientific interests are synthesis and investigations of carbons and inorganic sorbents (ion exchangers) for environmental protection, fine chemical technologies, radiochemistry, catalysis and medicine. Member of a few scientific councils by materials science, adsorbent and medicine.

Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications

Volodymyr V. Strelko

Institute for Sorption and Problems of Endoecology of National Academy of Sciences of Ukraine, 13 General Naumov str., Kiev 03164, Ukraine

Received:2012-11-20 Revised:2013-02-19 Online:2013-03-20 Published:2013-04-04

摘要/Abstract

摘要： The conceptual ideas about the positive effects of N- and O-heteroatoms on the reactivity of carbons in gasification processes, their catalytic activity in electron transfer reactions, as well as the performance of the electrode double-layer supercapacitors due to their electron-donating influence on the π-conjugated system of graphene layers have been developed. This influence decreases both work function and band gap of carbons, and also significantly affects their electron-donating properties. As a result of our investigations based on quantum chemical calculations of model graphene clusters with N- and O-heteroatoms in different positions, prognostic data have been obtained. These data have been confirmed by our experimental results of catalytic activity of corresponding carbons in H₂O₂ decomposition reaction, their reactivity in gasification processes, and also their performance as electrodes in supercapacitors.

关键词: N- and O-heteroatoms, carbon catalysts, gasification of carbons, supercapacitors, alkali and alkaline earth metals

Abstract: The conceptual ideas about the positive effects of N- and O-heteroatoms on the reactivity of carbons in gasification processes, their catalytic activity in electron transfer reactions, as well as the performance of the electrode double-layer supercapacitors due to their electron-donating influence on the π-conjugated system of graphene layers have been developed. This influence decreases both work function and band gap of carbons, and also significantly affects their electron-donating properties. As a result of our investigations based on quantum chemical calculations of model graphene clusters with N- and O-heteroatoms in different positions, prognostic data have been obtained. These data have been confirmed by our experimental results of catalytic activity of corresponding carbons in H₂O₂ decomposition reaction, their reactivity in gasification processes, and also their performance as electrodes in supercapacitors.

Key words: N- and O-heteroatoms, carbon catalysts, gasification of carbons, supercapacitors, alkali and alkaline earth metals

Volodymyr V. Strelko. Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications[J]. 能源化学(英文), 2013, 22(2): 174-182.

Volodymyr V. Strelko. Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications[J]. Journal of Energy Chemistry, 2013, 22(2): 174-182.

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Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications

Role of carbon matrix heteroatoms at synthesis of carbons for catalysis and energy applications

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