Important roles of graphene edges in carbon-based energy storage devices

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (2): 183-194.

Important roles of graphene edges in carbon-based energy storage devices

Yoong Ahm Kim^a, Takuya Hayashi^a, Jin Hee Kim^a, Morinobu Endo^b

a. Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan;
b. Research Center for Exotic Nanocarbons (JST), Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan

收稿日期:2012-11-20 修回日期:2013-01-29 出版日期:2013-03-20 发布日期:2013-04-04
通讯作者: Yoong Ahm Kim
作者简介:Yoong Ahm Kim received his PhD in Material Engineering from Shinshu University, Japan in 2001. He is an associate professor of Shinshu University and has published about 175 papers in international journals. His current research areas are carbon nanotube-based transparent conductive film, optical properties of double walled carbon nanotubes, fabrication of novel nanofibers by electrospinning, biological compatibility of carbon nanotubes, fabrication of high quality graphene, application of nanocarbons in energy storage devices, and nanocarbonbased 3D scaffold for growing cells.
基金资助:
This work was supported by the grant No. 24310088 from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

Important roles of graphene edges in carbon-based energy storage devices

Yoong Ahm Kim^a, Takuya Hayashi^a, Jin Hee Kim^a, Morinobu Endo^b

a. Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan;
b. Research Center for Exotic Nanocarbons (JST), Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan

Received:2012-11-20 Revised:2013-01-29 Online:2013-03-20 Published:2013-04-04
Supported by:
This work was supported by the grant No. 24310088 from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

摘要/Abstract

摘要： Nanostructured carbon materials, including carbon nanotubes, graphene and nanoporous carbon, show promise for expanding renewable energy. In particular, the configuration and electronic properties of graphene edges in relation with their electrochemical activity have become a major issue in carbon-based energy storage devices. Here, we review recent results concerning the important roles of graphene edges as the gateway for lithium ion intercalation in the anode of lithium-ion batteries, as promoters of high capacitance in carbon-based supercapacitors, and as anchoring sites for Pt nanoparticles in fuel cells. We envisage that the controlled synthesis of a specific, clean, and stable edge configuration could be achieved to maximize the electrochemical performance of nanostructured carbon-based energy storage devices.

关键词: carbon nanotube, graphene, edge, lithium ion battery, supercapacitor, fuel cell

Abstract: Nanostructured carbon materials, including carbon nanotubes, graphene and nanoporous carbon, show promise for expanding renewable energy. In particular, the configuration and electronic properties of graphene edges in relation with their electrochemical activity have become a major issue in carbon-based energy storage devices. Here, we review recent results concerning the important roles of graphene edges as the gateway for lithium ion intercalation in the anode of lithium-ion batteries, as promoters of high capacitance in carbon-based supercapacitors, and as anchoring sites for Pt nanoparticles in fuel cells. We envisage that the controlled synthesis of a specific, clean, and stable edge configuration could be achieved to maximize the electrochemical performance of nanostructured carbon-based energy storage devices.

Key words: carbon nanotube, graphene, edge, lithium ion battery, supercapacitor, fuel cell

Yoong Ahm Kim, Takuya Hayashi, Jin Hee Kim, Morinobu Endo. Important roles of graphene edges in carbon-based energy storage devices[J]. 能源化学(英文), 2013, 22(2): 183-194.

Yoong Ahm Kim, Takuya Hayashi, Jin Hee Kim, Morinobu Endo. Important roles of graphene edges in carbon-based energy storage devices[J]. Journal of Energy Chemistry, 2013, 22(2): 183-194.

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Important roles of graphene edges in carbon-based energy storage devices

Important roles of graphene edges in carbon-based energy storage devices

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