A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (2): 270-278.

A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers

O. Yu. Podyacheva^a, A. N. Shmakov^a,b, A. I. Boronin^a, L. S. Kibis^a, S. V. Koscheev^a, E. Yu. Gerasimov^a, Z. R. Ismagilov^a,c

a. Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia;
b. Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090, Russia;
c. Institute of Coal Chemistry and Material Science, Pr. Sovetskiy18, Kemerovo 65000, Russia

收稿日期:2012-10-25 修回日期:2012-12-13 出版日期:2013-03-20 发布日期:2013-04-04
通讯作者: O. Yu. Podyacheva
基金资助:
The work was supported by the Federal Target Program “Scientific and Educational Personnel of Innovative Russia” 2009-2013 (Agreement 8429), RFBR Grant No. 12-03-01091-a, Presidium RAS (Project 24.51), Presidium SB RAS (Project 36), and Integration Research Projects SB RAS No. 75.

A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers

O. Yu. Podyacheva^a, A. N. Shmakov^a,b, A. I. Boronin^a, L. S. Kibis^a, S. V. Koscheev^a, E. Yu. Gerasimov^a, Z. R. Ismagilov^a,c

a. Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia;
b. Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090, Russia;
c. Institute of Coal Chemistry and Material Science, Pr. Sovetskiy18, Kemerovo 65000, Russia

Received:2012-10-25 Revised:2012-12-13 Online:2013-03-20 Published:2013-04-04
Supported by:
The work was supported by the Federal Target Program “Scientific and Educational Personnel of Innovative Russia” 2009-2013 (Agreement 8429), RFBR Grant No. 12-03-01091-a, Presidium RAS (Project 24.51), Presidium SB RAS (Project 36), and Integration Research Projects SB RAS No. 75.

摘要/Abstract

摘要： Changes of a 65Ni25Cu10Al₂O₃ catalyst consisting of Ni-enriched and Cu-enriched alloys were investigated in the bulk and on the surface during the growth of nitrogen-doped carbon nanofibers (N-CNFs) by decomposition of a 50%C₂H₄/50%NH₃ mixture using in situ X-ray diffraction (XRD) analysis, ex situ X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) techniques. It was shown that N-CNF growth at 450-650 ℃ is accompanied by dissolution of carbon and nitrogen in the Ni-enriched alloy, whereas Cu-enriched alloy remains inactive. A correlation between nickel and copper surface concentrations and properties of N-CNFs in relation to the nitrogen content was found. It was demonstrated that phase composition of the catalyst during N-CNF growth determines the type of N-CNFs structure.

关键词: carbon nanofibers, nitrogen-doped carbon nanofibers, XRD in situ, XPS, catalyst

Abstract: Changes of a 65Ni25Cu10Al₂O₃ catalyst consisting of Ni-enriched and Cu-enriched alloys were investigated in the bulk and on the surface during the growth of nitrogen-doped carbon nanofibers (N-CNFs) by decomposition of a 50%C₂H₄/50%NH₃ mixture using in situ X-ray diffraction (XRD) analysis, ex situ X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) techniques. It was shown that N-CNF growth at 450-650 ℃ is accompanied by dissolution of carbon and nitrogen in the Ni-enriched alloy, whereas Cu-enriched alloy remains inactive. A correlation between nickel and copper surface concentrations and properties of N-CNFs in relation to the nitrogen content was found. It was demonstrated that phase composition of the catalyst during N-CNF growth determines the type of N-CNFs structure.

Key words: carbon nanofibers, nitrogen-doped carbon nanofibers, XRD in situ, XPS, catalyst

O. Yu. Podyacheva, A. N. Shmakov, A. I. Boronin, L. S. Kibis, S. V. Koscheev, E. Yu. Gerasimov, Z. R. Ismagilov. A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers[J]. 能源化学(英文), 2013, 22(2): 270-278.

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A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers

A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers

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