Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (2): 305-311.

Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF

A. Villa^a, M. Schiavoni^a, P. F. Fulvio^b, S. M. Mahurin^b, S. Dai^b, R. T. Mayes^b, G. M. Veith^c, L. Prati^a

a. Dipartimento di Chimica, Universita'degli Studi di Milano, via Golgi 19-20133 Milano, Italy;
b. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States;
c. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States

收稿日期:2012-11-01 修回日期:2013-02-14 出版日期:2013-03-20 发布日期:2013-04-04
通讯作者: L. Prati
基金资助:
This work was supported by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. Department of Energy (GMV). TEM studies were performed through Oak Ridge National Laboratory’s Center for Nanophase Materials Science (CNMS) which is sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U. S. Department of Energy. Fondazione Cariplo is also gratefully acknowledged for financial support.

Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF

A. Villa^a, M. Schiavoni^a, P. F. Fulvio^b, S. M. Mahurin^b, S. Dai^b, R. T. Mayes^b, G. M. Veith^c, L. Prati^a

a. Dipartimento di Chimica, Universita'degli Studi di Milano, via Golgi 19-20133 Milano, Italy;
b. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States;
c. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States

Received:2012-11-01 Revised:2013-02-14 Online:2013-03-20 Published:2013-04-04
Supported by:
This work was supported by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. Department of Energy (GMV). TEM studies were performed through Oak Ridge National Laboratory’s Center for Nanophase Materials Science (CNMS) which is sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U. S. Department of Energy. Fondazione Cariplo is also gratefully acknowledged for financial support.

摘要/Abstract

摘要： Phosphorylated mesoporous carbons (PMCs) were investigated as catalysts in the dehydration of fructose to hydroxymethylfurfural (HMF). The acidic PMCs show better selectivity to HMF compared to sulfonated carbon catalyst (SC) despite lower activity. The concentration of P-O groups on the PMC was correlated with the activity/selectivity of the catalysts; the higher the P-O concentration, the higher the activity. However, the higher the P-O content, the lower the selectivity to HMF. Indeed, a lower concentration of the P-O groups minimized the degradation of HMF to levulinic acid and the formation of by-products, such as humines. Stability tests showed that these systems deactivate due to the formation of humines and water insoluble by-products derived from the dehydration of fructose which blocked the catalytically active sites.

关键词: phosphorylated mesoporous carbons, fructose dehydration, hydroxymethylfurfural

Abstract: Phosphorylated mesoporous carbons (PMCs) were investigated as catalysts in the dehydration of fructose to hydroxymethylfurfural (HMF). The acidic PMCs show better selectivity to HMF compared to sulfonated carbon catalyst (SC) despite lower activity. The concentration of P-O groups on the PMC was correlated with the activity/selectivity of the catalysts; the higher the P-O concentration, the higher the activity. However, the higher the P-O content, the lower the selectivity to HMF. Indeed, a lower concentration of the P-O groups minimized the degradation of HMF to levulinic acid and the formation of by-products, such as humines. Stability tests showed that these systems deactivate due to the formation of humines and water insoluble by-products derived from the dehydration of fructose which blocked the catalytically active sites.

Key words: phosphorylated mesoporous carbons, fructose dehydration, hydroxymethylfurfural

A. Villa, M. Schiavoni, P. F. Fulvio, S. M. Mahurin, S. Dai, R. T. Mayes, G. M. Veith, L. Prati. Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF[J]. 能源化学(英文), 2013, 22(2): 305-311.

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Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF

Phosphorylated mesoporous carbon as effective catalyst for the selective fructose dehydration to HMF

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