Coating of Al2O3 on layered Li(Mn1/3Ni1/3Co1/3)O2 using CO2 as green precipitant and their improved electrochemical performance for lithium ion batteries

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (3): 468-476.

Coating of Al₂O₃ on layered Li(Mn_1/3Ni_1/3Co_1/3)O₂ using CO₂ as green precipitant and their improved electrochemical performance for lithium ion batteries

Yingqiang Wu^a,b,c, Linhai Zhuo^a,b, Jun Ming^a,b, Yancun Yu^a,b, Fengyu Zhao^a,b

a. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;
b. Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;
c. University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2012-12-03 修回日期:2013-01-15 出版日期:2013-05-20 发布日期:2013-05-31
通讯作者: Linhai Zhuo, Fengyu Zhao
基金资助:
This work was financial supported by the National Natural Science Foundation of China (21273222).

Coating of Al₂O₃ on layered Li(Mn_1/3Ni_1/3Co_1/3)O₂ using CO₂ as green precipitant and their improved electrochemical performance for lithium ion batteries

Yingqiang Wu^a,b,c, Linhai Zhuo^a,b, Jun Ming^a,b, Yancun Yu^a,b, Fengyu Zhao^a,b

a. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;
b. Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;
c. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2012-12-03 Revised:2013-01-15 Online:2013-05-20 Published:2013-05-31
Supported by:
This work was financial supported by the National Natural Science Foundation of China (21273222).

摘要/Abstract

摘要： Li(Mn_1/3Ni_1/3Co_1/3)O₂ cathode materials were fabricated by a hydroxide precursor method. Al₂O₃ was coated on the surface of the Li(Mn_1/3Ni_1/3Co_1/3)O₂ through a simple and effective one-step electrostatic self-assembly method. In the coating process, a NaHCO₃-H₂CO₃ buffer was formed spontaneously when CO₂ was introduced into the NaAlO₂ solution. Compared with bare Li(Mn_1/3Ni_1/3Co_1/3)O₂, the surface-modified samples exhibited better cycling performance, rate capability and rate capability retention. The Al₂O₃-coated Li(Mn_1/3Ni_1/3Co_1/3)O₂ electrodes delivered a discharge capacity of about 115 mAh穏^-1 at 2 A穏^-1, but only 84 mAh穏^-1 for the bare one. The capacity retention of the Al₂O₃-coated Li(Mn_1/3Ni_1/3Co_1/3)O₂ was 90.7% after 50 cycles, about 30% higher than that of the pristine one.

关键词: electrochemistry, alumina, coating, layered cathode, lithium-ion batteries

Abstract: Li(Mn_1/3Ni_1/3Co_1/3)O₂ cathode materials were fabricated by a hydroxide precursor method. Al₂O₃ was coated on the surface of the Li(Mn_1/3Ni_1/3Co_1/3)O₂ through a simple and effective one-step electrostatic self-assembly method. In the coating process, a NaHCO₃-H₂CO₃ buffer was formed spontaneously when CO₂ was introduced into the NaAlO₂ solution. Compared with bare Li(Mn_1/3Ni_1/3Co_1/3)O₂, the surface-modified samples exhibited better cycling performance, rate capability and rate capability retention. The Al₂O₃-coated Li(Mn_1/3Ni_1/3Co_1/3)O₂ electrodes delivered a discharge capacity of about 115 mAh穏^-1 at 2 A穏^-1, but only 84 mAh穏^-1 for the bare one. The capacity retention of the Al₂O₃-coated Li(Mn_1/3Ni_1/3Co_1/3)O₂ was 90.7% after 50 cycles, about 30% higher than that of the pristine one.

Key words: electrochemistry, alumina, coating, layered cathode, lithium-ion batteries

Yingqiang Wu, Linhai Zhuo, Jun Ming, Yancun Yu, Fengyu Zhao. Coating of Al₂O₃ on layered Li(Mn_1/3Ni_1/3Co_1/3)O₂ using CO₂ as green precipitant and their improved electrochemical performance for lithium ion batteries[J]. 能源化学(英文), 2013, 22(3): 468-476.

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Coating of Al₂O₃ on layered Li(Mn_1/3Ni_1/3Co_1/3)O₂ using CO₂ as green precipitant and their improved electrochemical performance for lithium ion batteries

Coating of Al₂O₃ on layered Li(Mn_1/3Ni_1/3Co_1/3)O₂ using CO₂ as green precipitant and their improved electrochemical performance for lithium ion batteries

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