Direct conversion of natural gas to higher hydrocarbons: A review

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (4): 543-554.

• Review • 下一篇

Direct conversion of natural gas to higher hydrocarbons: A review

Sachchit Majhi^a,b, Pravakar Mohanty^a, Hui Wang^b, K. K. Pant^a

a. Department of Chemical Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India;
b. Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5C5, Canada

收稿日期:2012-09-03 修回日期:2012-12-24 出版日期:2013-07-20 发布日期:2013-07-27
通讯作者: Hui Wang, K. K. Pant
作者简介:Sachchit Majhi is currently a Ph.D. student in the Chemical Engineering Department at the Indian Institute of Technology Delhi (India). He recently worked at the University of Saskatchewan (Canada) as a visiting Ph.D. student with support of the Canadian Commonwealth Scholarship. Sachchit Majhi started his research career with M.Tech. from Birla Institute of Technology Mesra Ranchi (India). He is working on natural gas conversion through direct and indirect routes. His main research interests include Gas-to-Liqud and Carbon-to-Liquid for green fuel production.
基金资助:
The authors would like to thank the Canadian Bureau of International Education (CBIE) on behalf of Foreign Affairs and International Trade Canada (DFAIT) for the Canadian Commonwealth Scholarship Program that supported Sachchit Majhi to work in Canada for this project.

Direct conversion of natural gas to higher hydrocarbons: A review

Sachchit Majhi^a,b, Pravakar Mohanty^a, Hui Wang^b, K. K. Pant^a

a. Department of Chemical Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India;
b. Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5C5, Canada

Received:2012-09-03 Revised:2012-12-24 Online:2013-07-20 Published:2013-07-27
Supported by:
The authors would like to thank the Canadian Bureau of International Education (CBIE) on behalf of Foreign Affairs and International Trade Canada (DFAIT) for the Canadian Commonwealth Scholarship Program that supported Sachchit Majhi to work in Canada for this project.

摘要/Abstract

摘要： Direct conversion of methane to higher hydrocarbons is an effective process to solve the problem of natural gas utilization. Although remarkable progress has been achieved on the dehydro-aromatization of methane (DAM), low conversion caused by severe thermodynamic limitations, coke formation, and catalysis deactivation remain important drawbacks to the direct conversion process. Molybdenum catalysts supported on HZSM-5 type zeolite support are among the most promising catalysts. This review focuses on the aspects of direct methane conversion, in terms of catalysts containing metal and support, reaction conditions, and conversion in different types of reactors. The reaction mechanism for this catalytic process is also discussed.

关键词: methane dehydroaromatization, Mo/HZSM-5, higher hydrocarbon, kinetics, mechanism

Abstract: Direct conversion of methane to higher hydrocarbons is an effective process to solve the problem of natural gas utilization. Although remarkable progress has been achieved on the dehydro-aromatization of methane (DAM), low conversion caused by severe thermodynamic limitations, coke formation, and catalysis deactivation remain important drawbacks to the direct conversion process. Molybdenum catalysts supported on HZSM-5 type zeolite support are among the most promising catalysts. This review focuses on the aspects of direct methane conversion, in terms of catalysts containing metal and support, reaction conditions, and conversion in different types of reactors. The reaction mechanism for this catalytic process is also discussed.

Key words: methane dehydroaromatization, Mo/HZSM-5, higher hydrocarbon, kinetics, mechanism

Sachchit Majhi, Pravakar Mohanty, Hui Wang, K. K. Pant. Direct conversion of natural gas to higher hydrocarbons: A review[J]. 能源化学(英文), 2013, 22(4): 543-554.

Sachchit Majhi, Pravakar Mohanty, Hui Wang, K. K. Pant. Direct conversion of natural gas to higher hydrocarbons: A review[J]. Journal of Energy Chemistry, 2013, 22(4): 543-554.

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Direct conversion of natural gas to higher hydrocarbons: A review

Direct conversion of natural gas to higher hydrocarbons: A review

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