Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (4): 624-632.

Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis

Tingzhen Li^a,b,c, Hulin Wang^a, Yong Yang^a, Hongwei Xiang^a, Yongwang Li^a

a. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China;
b. College of Chemistry and Environmental Engineering, Chongqing Three Gorges University, Chongqing 404000, China;
c. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, Jiangsu, China

收稿日期:2013-04-06 修回日期:2013-06-20 出版日期:2013-07-20 发布日期:2013-07-27
通讯作者: Hongwei Xiang
基金资助:
This work was supported by Natural Science Foundation of Chongqing Three Gorges University (12ZD14) and Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University.

Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis

Tingzhen Li^a,b,c, Hulin Wang^a, Yong Yang^a, Hongwei Xiang^a, Yongwang Li^a

a. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China;
b. College of Chemistry and Environmental Engineering, Chongqing Three Gorges University, Chongqing 404000, China;
c. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, Jiangsu, China

Received:2013-04-06 Revised:2013-06-20 Online:2013-07-20 Published:2013-07-27
Supported by:
This work was supported by Natural Science Foundation of Chongqing Three Gorges University (12ZD14) and Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University.

摘要/Abstract

摘要： A systematic study was carried out to investigate the promotion effect of manganese on the performance of a coprecipitated iron-manganese bimetallic catalyst for the light olefins synthesis from syngas. The catalyst samples were characterized by N₂ physisorption, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), Mössbauer spectroscopy, H₂-differential thermogravimetric analysis (H₂-DTG), CO temperature-programmed reduction (CO-TPR) and CO₂ temperature-programmed desorption (CO₂-TPD). The Fischer-Tropsch synthesis (FTS) performance of the catalyst was measured at 1.5 MPa, 250 ℃ and syngas with H₂/CO ratio of 2.0. The characterization results indicated that the addition of manganese decreases the catalyst crystallite size, and improves the catalyst BET surface area and pore volume. The presence of manganese suppresses the catalyst reduction and carburization in H₂, CO and syngas, respectively. The addition of manganese improves the catalytic activity of water-gas shift reaction and suppresses the oxidation of iron carbides in the FTS reaction. The incorporation of manganese improves the catalyst surface basicity and results in a significant improvement in the selectivities to light olefins and heavy hydrocarbons (C₅₊), and furthermore an inhibition of methane formation in FTS. The pure iron catalyst (Mn-00) has the highest initial FTS catalytic activity (65%) and the lowest selectivity (17.35 wt%) to light olefins (C₂⁼—C₄⁼). The addition of an appropriate amount of manganese can improve the catalyst FTS activity.

关键词: light olefin, Fischer-Tropsch synthesis, iron-manganese, bimetallic catalyst, carburization

Abstract: A systematic study was carried out to investigate the promotion effect of manganese on the performance of a coprecipitated iron-manganese bimetallic catalyst for the light olefins synthesis from syngas. The catalyst samples were characterized by N₂ physisorption, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), Mössbauer spectroscopy, H₂-differential thermogravimetric analysis (H₂-DTG), CO temperature-programmed reduction (CO-TPR) and CO₂ temperature-programmed desorption (CO₂-TPD). The Fischer-Tropsch synthesis (FTS) performance of the catalyst was measured at 1.5 MPa, 250 ℃ and syngas with H₂/CO ratio of 2.0. The characterization results indicated that the addition of manganese decreases the catalyst crystallite size, and improves the catalyst BET surface area and pore volume. The presence of manganese suppresses the catalyst reduction and carburization in H₂, CO and syngas, respectively. The addition of manganese improves the catalytic activity of water-gas shift reaction and suppresses the oxidation of iron carbides in the FTS reaction. The incorporation of manganese improves the catalyst surface basicity and results in a significant improvement in the selectivities to light olefins and heavy hydrocarbons (C₅₊), and furthermore an inhibition of methane formation in FTS. The pure iron catalyst (Mn-00) has the highest initial FTS catalytic activity (65%) and the lowest selectivity (17.35 wt%) to light olefins (C₂⁼—C₄⁼). The addition of an appropriate amount of manganese can improve the catalyst FTS activity.

Key words: light olefin, Fischer-Tropsch synthesis, iron-manganese, bimetallic catalyst, carburization

Tingzhen Li, Hulin Wang, Yong Yang, Hongwei Xiang, Yongwang Li. Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis[J]. 能源化学(英文), 2013, 22(4): 624-632.

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Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis

Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis

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