Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (4): 659-664.

Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

Lipeng Zhou^a, Beibei Dong^a, Si Tang^a, Hong Ma^a, Chen Chen^b, Xiaomei Yang^a, Jie Xu^b

a. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China;
b. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

收稿日期:2012-06-06 修回日期:2012-09-09 出版日期:2013-07-20 发布日期:2013-07-27
通讯作者: Xiaomei Yang
基金资助:
This work was supported by the National Nature Science Foundation of China (J1210060, 21143002).

Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

Lipeng Zhou^a, Beibei Dong^a, Si Tang^a, Hong Ma^a, Chen Chen^b, Xiaomei Yang^a, Jie Xu^b

a. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China;
b. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2012-06-06 Revised:2012-09-09 Online:2013-07-20 Published:2013-07-27
Supported by:
This work was supported by the National Nature Science Foundation of China (J1210060, 21143002).

摘要/Abstract

摘要： Sulfonated carbon as a strong and stable solid acid catalyst exhibited excellent catalytic performance in various acid-catalyzed reactions. Here, sulfonated carbon, as catalyst for oxidation reaction, was prepared via the carbonization of starch followed by sulfonation with concentrated sulfuric acid. N₂ physisorption, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray fluorescence and acid-base titration were used to characterize the obtained materials. The catalytic activity of sulfonated carbon was studied in the oxidation of aldehydes to carboxylic acids using 30 wt% H₂O₂ as oxidant. This oxidation protocol works well for various aldehydes including aromatic and aliphatic aldehydes. The sulfonated carbon can be recycled for three times without obvious loss of activity.

关键词: aldehyde, carboxylic acid, oxidation, hydrogen peroxide, sulfonated carbon

Abstract: Sulfonated carbon as a strong and stable solid acid catalyst exhibited excellent catalytic performance in various acid-catalyzed reactions. Here, sulfonated carbon, as catalyst for oxidation reaction, was prepared via the carbonization of starch followed by sulfonation with concentrated sulfuric acid. N₂ physisorption, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray fluorescence and acid-base titration were used to characterize the obtained materials. The catalytic activity of sulfonated carbon was studied in the oxidation of aldehydes to carboxylic acids using 30 wt% H₂O₂ as oxidant. This oxidation protocol works well for various aldehydes including aromatic and aliphatic aldehydes. The sulfonated carbon can be recycled for three times without obvious loss of activity.

Key words: aldehyde, carboxylic acid, oxidation, hydrogen peroxide, sulfonated carbon

Lipeng Zhou, Beibei Dong, Si Tang, Hong Ma, Chen Chen, Xiaomei Yang, Jie Xu. Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide[J]. 能源化学(英文), 2013, 22(4): 659-664.

Lipeng Zhou, Beibei Dong, Si Tang, Hong Ma, Chen Chen, Xiaomei Yang, Jie Xu. Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide[J]. Journal of Energy Chemistry, 2013, 22(4): 659-664.

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Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

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