Activity and basic properties of KOH/mordenite for transesterification of palm oil

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (5): 690-700.

Activity and basic properties of KOH/mordenite for transesterification of palm oil

Pisitpong Intarapong^a, Sotsanan Iangthanarat^a, Pitchaya Phanthong^a, Apanee Luengnaruemitchai^a,b, Samai Jai-In^c

a. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand;
b. Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, Bangkok 10330, Thailand;
c. The Royal Thai Navy, Bangkok 10700, Thailand

收稿日期:2013-01-15 修回日期:2013-03-13 出版日期:2013-09-20 发布日期:2013-09-30
通讯作者: Apanee Luengnaruemitchai
基金资助:
This work was supported financially by the National Metal and Materials Technology Center, Thailand, and the Center of Excellence on Petrochemical and Materials Technology, Thailand.

Activity and basic properties of KOH/mordenite for transesterification of palm oil

Pisitpong Intarapong^a, Sotsanan Iangthanarat^a, Pitchaya Phanthong^a, Apanee Luengnaruemitchai^a,b, Samai Jai-In^c

a. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand;
b. Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, Bangkok 10330, Thailand;
c. The Royal Thai Navy, Bangkok 10700, Thailand

Received:2013-01-15 Revised:2013-03-13 Online:2013-09-20 Published:2013-09-30
Supported by:
This work was supported financially by the National Metal and Materials Technology Center, Thailand, and the Center of Excellence on Petrochemical and Materials Technology, Thailand.

摘要/Abstract

摘要： The catalytic performance of KOH/mordenite has been studied for transesterification of palm oil using a batch reactor and a packed-bed reactor at 60℃ and atmospheric pressure. The KOH/mordenite processed transesterification in the batch reactor gave the highest methyl ester yield of 96.7% under optimum conditions, while a methyl ester content over 94.5% was obtained in the packed-bed reactor. This comparison indicates that transesterification in a batch-type reactor gives a higher methyl ester yield than that of a continuous-flow reactor. Dealumination was found in the calcined catalysts and had a significant effect on the physical structure and chemical composition of the catalysts. Leaching of the potassium species was negligible, whereas depositing and washing of the reacted mixture with acetone on the catalyst surface were observed by FTIR.

关键词: transesterification, biodiesel, mordenite, KOH, solid base catalyst

Abstract: The catalytic performance of KOH/mordenite has been studied for transesterification of palm oil using a batch reactor and a packed-bed reactor at 60℃ and atmospheric pressure. The KOH/mordenite processed transesterification in the batch reactor gave the highest methyl ester yield of 96.7% under optimum conditions, while a methyl ester content over 94.5% was obtained in the packed-bed reactor. This comparison indicates that transesterification in a batch-type reactor gives a higher methyl ester yield than that of a continuous-flow reactor. Dealumination was found in the calcined catalysts and had a significant effect on the physical structure and chemical composition of the catalysts. Leaching of the potassium species was negligible, whereas depositing and washing of the reacted mixture with acetone on the catalyst surface were observed by FTIR.

Key words: transesterification, biodiesel, mordenite, KOH, solid base catalyst

Pisitpong Intarapong, Sotsanan Iangthanarat, Pitchaya Phanthong, Apanee Luengnaruemitchai, Samai Jai-In. Activity and basic properties of KOH/mordenite for transesterification of palm oil[J]. 能源化学(英文), 2013, 22(5): 690-700.

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Activity and basic properties of KOH/mordenite for transesterification of palm oil

Activity and basic properties of KOH/mordenite for transesterification of palm oil

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