Creation of surface defects on carbon nanofibers by steam treatment

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (5): 804-810.

Creation of surface defects on carbon nanofibers by steam treatment

Zhengfeng Shao^a, Min Pang^a, Wei Xia^b, Martin Muhler^b, Changhai Liang^a

a. Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China;
b. Laboratory of Industrial Chemistry, Ruhr University Bochum, Bochum 44780, Germany

收稿日期:2013-01-24 修回日期:2013-03-20 出版日期:2013-09-20 发布日期:2013-09-30
通讯作者: Changhai Liang
基金资助:
This work was supported by the National Natural Science Foundation of China (21073023 and 20906008), the Fundamental Research Funds for the Central Universities (DUT12YQ03), and the CSC and DAAD for a Project Based Personnel Exchange Program.

Creation of surface defects on carbon nanofibers by steam treatment

Zhengfeng Shao^a, Min Pang^a, Wei Xia^b, Martin Muhler^b, Changhai Liang^a

a. Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China;
b. Laboratory of Industrial Chemistry, Ruhr University Bochum, Bochum 44780, Germany

Received:2013-01-24 Revised:2013-03-20 Online:2013-09-20 Published:2013-09-30
Supported by:
This work was supported by the National Natural Science Foundation of China (21073023 and 20906008), the Fundamental Research Funds for the Central Universities (DUT12YQ03), and the CSC and DAAD for a Project Based Personnel Exchange Program.

摘要/Abstract

摘要： A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment. Nitrogen physisorption, XRD, Raman spectra, SEM and TEM analyses proved the existence of the new defects on CNFs. BET surface area of CNFs after steam treatment was enhanced from 20 to 378 m²/g. Pd catalysts supported on CNFs were also prepared by colloidal deposition method. The different activity of Pd/CNFs catalysts in the partial hydrogenation of phenylacetylene further demonstrated the diverse surfaces of CNFs could be formed by steam treatment.

关键词: carbon nanofibers, surface defects, steam treatment, palladium

Abstract: A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment. Nitrogen physisorption, XRD, Raman spectra, SEM and TEM analyses proved the existence of the new defects on CNFs. BET surface area of CNFs after steam treatment was enhanced from 20 to 378 m²/g. Pd catalysts supported on CNFs were also prepared by colloidal deposition method. The different activity of Pd/CNFs catalysts in the partial hydrogenation of phenylacetylene further demonstrated the diverse surfaces of CNFs could be formed by steam treatment.

Key words: carbon nanofibers, surface defects, steam treatment, palladium

Zhengfeng Shao, Min Pang, Wei Xia, Martin Muhler, Changhai Liang. Creation of surface defects on carbon nanofibers by steam treatment[J]. 能源化学(英文), 2013, 22(5): 804-810.

Zhengfeng Shao, Min Pang, Wei Xia, Martin Muhler, Changhai Liang. Creation of surface defects on carbon nanofibers by steam treatment[J]. Journal of Energy Chemistry, 2013, 22(5): 804-810.

参考文献

[1] Rinzler A G, Hafner J H, Nikolaev P, Nordlander P, Colbert D T, Smalley R E, Lou L, Kim S G, Tománek D. Science, 1995, 269(5230): 1550

[2] Yu M F, Lourie O, Dyer M J, Moloni K, Kelly T F, Ruoff R S. Science, 2000, 287(5453): 637

[3] Maciej O, John O, Stefan J, Helmut M, Nicholas K, Krzysztof K, Giersig M. Nano Lett, 2004, 4(10): 1889

[4] Zhang M, Fang S, Zakhidov A A, Lee S B, Aliev A E, Williams C D, Atkinson K R, Baughman R H. Science, 2005, 309(5738): 1215

[5] Bitter J H. J Mater Chem, 2010, 20: 7312

[6] Su D S, Schlögl R. ChemSusChem, 2010, 3(2): 136

[7] Yang W, Chu W, Jiang C F, Wen J, Sun W J. Chin J Catal \emph{\emph{(}Cuihua Xuebao\emph{)}}, 2011, 32(8): 1323

[8] Gong Q M, Li Z, Zhou X W, Wu J J, Wang Y, Liang J. Carbon, 2005, 43(11): 2426

[9] Zhang Q, Huang J Q, Zhao M Q, Qian W Z, Wei F. ChemSusChem, 2011, 4(7): 864

[10] Xia W, Jin C, Kundu S, Muhler M. Carbon, 2009, 47(3): 919

[11] Kundu S, Xia W, Busser W, Becker M, Schmidt D A, Havenith M, Muhler M. Phys Chem Chem Phys, 2010, 12: 4351

[12] Gao W J, Guo S J, Zhang H B, Pan X L, Bao X H. Chin J Catal (Cuihua Xuebao), 2011, 32(8): 1418

[13] Darmstadt H, Roy C, Kaliaguine S, Ting J M, Alig R L. Carbon, 1998, 36(7-8): 1183

[14] Rosca I D, Watari F, Uo M, Akasaka T. Carbon, 2005, 43(15): 3124

[15] Lee H J, Han S W, Kwon Y D, Tan L S, Baek J B. Carbon, 2008, 46(14): 1850

[16] Li C, Zhao A Q, Xia W, Liang C H, Muhler M. J Phys Chem C, 2012, 116(39): 20930

[17] Charlier J C. Acc Chem Res, 2002, 35(12): 1063

[18] Li Y H, Zhu Y Q, Zhao Y M, Wu D H, Luan Z K. Diam Relat Mater, 2006, 15(1): 90

[19] Xia W, Yin X L, Kundu S, Sánchez M, Birkner A, Wöll C, Muhler M. Carbon, 2011, 49(1): 299

[20] Zhang S, Mielke S L, Khare R, Troya D, Ruoff R S, Schatz G C, Belytschko T. Phys Rev B, 2005, 71(11): 115403

[21] Xia W, Hagen V, Kundu S, Wang Y, Somsen C, Eggeler G, Sun G, Grundmeier G, Stratmann M, Muhler M. Adv Mater, 2007, 19(21): 3648

[22] Ermakova M A, Ermakov D Y, Chuvilin A L, Kuvshinov G G. J Catal, 2001, 201(2): 183

[23] Li C, Shao Z, Pang M, Williams C T, Zhang X, Liang C. Ind Eng Chem Res, 2012, 51(13): 4934

[24] Dresselhaus M S, Dresselhaus G, Jorio A, Souza Filho A G, Saito R. Carbon, 2002, 40(12): 2043

[25] Rashidi A, Lotfi R, Fakhrmosavi E, Zare M. J Nat Gas Chem, 2011, 20(4): 372

[26] Lee K Y, Yeoh W M, Chai S P, Mohamed A R. J Nat Gas Chem, 2012, 21(6): 620

[27] Sonia D D, Ángel B, Bhabendra K P, Ángel L S, Diego C A. J Phys Chem C, 2008, 112(10): 3827

Creation of surface defects on carbon nanofibers by steam treatment

Creation of surface defects on carbon nanofibers by steam treatment

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Fei Huang, Zhimin Jia, Jiangyong Diao, Hua Yuan, Dangsheng Su, Hongyang Liu. Palladium nanoclusters immobilized on defective nanodiamondgraphene core-shell supports for semihydrogenation of phenylacetylene[J]. 能源化学(英文), 2019, 28(6): 31-36.
[2]	Long Kong, Qiang Zhang. Three-dimensional matrix for lithium metal anode for nextgeneration rechargeable batteries: Structure design and interface engineering[J]. 能源化学(英文), 2019, 28(6): 167-168.
[3]	Kai Tie, Xiulian Pan, Tie Yu, Pan Li, Limin He, Xinhe Bao. A highly active and stable Pd/B-doped carbon catalyst for the hydrogenation of 4-carboxybenzaldehyde[J]. 能源化学(英文), 2019, 28(4): 154-158.
[4]	Ehteram Hasheminejad, Reza Ojani, Jahan Bakhsh Raoof. A rapid synthesis of high surface area PdRu nanosponges: Composition-dependent electrocatalytic activity for formic acid oxidation[J]. 能源化学(英文), 2017, 26(4): 703-711.
[5]	Qi Wang, Neeraj Gupta, Guodong Wen, Sharifah Bee Abd Hamid, Dang Sheng Su. Palladium and carbon synergistically catalyzed room-temperature hydrodeoxygenation (HDO) of vanillyl alcohol-A typical lignin model molecule[J]. 能源化学(英文), 2017, 26(1): 8-16.
[6]	Myounghoon Choun, Jaeyoung Lee. Electro-oxidation of mixed reactants of ethanol and formate on Pd/C in alkaline fuel cells[J]. 能源化学(英文), 2016, 25(4): 683-690.
[7]	Ming Zhao, Hailong Zhang, Xue Li, Yaoqiang Chen. Co-modified Pd/CeO₂-ZrO₂ catalysts for methanol decomposition[J]. 能源化学(英文), 2014, 23(6): 755-760.
[8]	Yun Wang, Haidi Xu, Hongyan Shang, Maochu Gong, Yaoqiang Chen. Excellent complete conversion activity for methane and CO of Pd/TiO₂-Zr_0.5Al_0.5O_1.75 catalyst used in lean-burn natural gas vehicles[J]. 能源化学(英文), 2014, 23(4): 461-467.
[9]	Xiqiang Pan, Yibo Zhang, Zhenzhen Miao, Xiangguang Yang. A novel PdNi/Al₂O₃ catalyst prepared by galvanic deposition for low temperature methane combustion[J]. 能源化学(英文), 2013, 22(4): 610-616.
[10]	O. Yu. Podyacheva, A. N. Shmakov, A. I. Boronin, L. S. Kibis, S. V. Koscheev, E. Yu. Gerasimov, Z. R. Ismagilov. A correlation between structural changes in a Ni-Cu catalyst during decomposition of ethylene/ammonia mixture and properties of nitrogen-doped carbon nanofibers[J]. 能源化学(英文), 2013, 22(2): 270-278.
[11]	Bruno F. Machado, Andrea Marchionni, Revathi R. Bacsa, Marco Bellini, Julien Beausoleil, Werner Oberhauser, Francesco Vizza, Philippe Serp. Synergistic effect between few layer graphene and carbon nanotube supports for palladium catalyzing electrochemical oxidation of alcohols[J]. 能源化学(英文), 2013, 22(2): 296-304.
[12]	Kim Yang Lee wei ming Dr Chai Siang Piao Abdul Rahman Mohamed. Utilization of compressed natural gas for the production of carbon nanotubes[J]. 能源化学(英文), 2012, 21(6): 620-624.
[13]	Weina Zhao, Huaxiang Lin, Yi Li, Yongfan Zhang, Xin Huang, Wenkai Chen*. Growth mechanism of palladium clusters on rutile TiO₂(110) surface [J]. 能源化学(英文), 2012, 21(5): 544-555.
[14]	Hongyan Shang, Yun Wang, Maochu Gong, Yaoqiang Chen* . Pd catalysts supported on modified Zr_0.5Al_0.5O_1.75 used for lean-burn natural gas vehicles exhaust purification[J]. 能源化学(英文), 2012, 21(4): 393-399.
[15]	Yonghua Zhou, Jing Liu, Xingyun Li, Xiulian Pan, Xinhe Bao. Selectivity modulation in the consecutive hydrogenation of benzaldehyde via functionalization of carbon nanotubes (Special Column)[J]. 能源化学(英文), 2012, 21(3): 241-245.