Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (6): 826-832.

Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

Boonrat Pholjaroen^a,b, Ning Li^a, Zhiqiang Wang^a,c, Aiqin Wang^a, Tao Zhang^a

a. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b. University of Chinese Academy of Sciences, Beijing 100049, China;
c. Department of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

收稿日期:2013-02-28 修回日期:2013-04-12 出版日期:2013-11-20 发布日期:2013-11-28
通讯作者: Ning Li
基金资助:
This work was supported by the Natural Science Foundation of China (No. 21106143), 100-talent project of Dalian Institute of Chemical Physics (DICP), and the Independent Innovation Foundation of State Key Laboratory of Catalysis (No. R201113).

Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

Boonrat Pholjaroen^a,b, Ning Li^a, Zhiqiang Wang^a,c, Aiqin Wang^a, Tao Zhang^a

a. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b. University of Chinese Academy of Sciences, Beijing 100049, China;
c. Department of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

Received:2013-02-28 Revised:2013-04-12 Online:2013-11-20 Published:2013-11-28
Supported by:
This work was supported by the Natural Science Foundation of China (No. 21106143), 100-talent project of Dalian Institute of Chemical Physics (DICP), and the Independent Innovation Foundation of State Key Laboratory of Catalysis (No. R201113).

摘要/Abstract

摘要： Phosphoric acid treated niobic acid (NbP) was used for the dehydration of xylose to furfural in biphasic solvent system, which was found to exhibit the best performance among the tested catalysts. The excellent performance of NbP could be explained by the better synergistic cooperation between Brönsted and Lewis acid sites. Moreover, NbP showed good stability and no obvious deactivation or leaching of Nb could be observed after six continuous recycles.

关键词: xylose, furfural, dehydration, biphasic solvent system, solid acid catalyst, niobium phosphate

Abstract: Phosphoric acid treated niobic acid (NbP) was used for the dehydration of xylose to furfural in biphasic solvent system, which was found to exhibit the best performance among the tested catalysts. The excellent performance of NbP could be explained by the better synergistic cooperation between Brönsted and Lewis acid sites. Moreover, NbP showed good stability and no obvious deactivation or leaching of Nb could be observed after six continuous recycles.

Key words: xylose, furfural, dehydration, biphasic solvent system, solid acid catalyst, niobium phosphate

Boonrat Pholjaroen, Ning Li, Zhiqiang Wang, Aiqin Wang, Tao Zhang. Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system[J]. 能源化学(英文), 2013, 22(6): 826-832.

Boonrat Pholjaroen, Ning Li, Zhiqiang Wang, Aiqin Wang, Tao Zhang. Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system[J]. Journal of Energy Chemistry, 2013, 22(6): 826-832.

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Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

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