Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO2 catalysts at low-temperature

能源化学(英文) ›› 2013, Vol. 22 ›› Issue (6): 861-868.

Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature

Xue Han, Yunbo Yu, Hong He, Jiaojiao Zhao

Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuangqing Road, Haidian District, Beijing 100085, China

收稿日期:2013-02-25 修回日期:2013-04-18 出版日期:2013-11-20 发布日期:2013-11-28
通讯作者: Hong He
基金资助:
This work was supported by the National Basic Research Program of China (2010CB732304) and the National Natural Science Foundation of China (21177142 and 20973193).

Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature

Xue Han, Yunbo Yu, Hong He, Jiaojiao Zhao

Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuangqing Road, Haidian District, Beijing 100085, China

Received:2013-02-25 Revised:2013-04-18 Online:2013-11-20 Published:2013-11-28
Supported by:
This work was supported by the National Basic Research Program of China (2010CB732304) and the National Natural Science Foundation of China (21177142 and 20973193).

摘要/Abstract

摘要： CuO-CeO₂ catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature. The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy, X-ray diffraction, temperature-programmed reduction, field emission scanning electron microscopy and thermo-gravimetric analysis. Over CuO-CeO₂ catalysts, H₂ with low CO content was produced in the whole tested temperature range of 250-450 ℃. The non-noble metal catalyst 20CuCe showed higher H₂ production rate than 1%Rh/CeO₂ catalyst at 300-400 ℃ and the advantage was more obvious after 20 h testing at 400 ℃. These results further confirmed that CuO-CeO₂ catalysts may be suitable candidates for low temperature hydrogen production from ethanol.

关键词: CuO-CeO₂ catalyst, hydrogen production, oxidative steam reforming, low-temperature

Abstract: CuO-CeO₂ catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature. The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy, X-ray diffraction, temperature-programmed reduction, field emission scanning electron microscopy and thermo-gravimetric analysis. Over CuO-CeO₂ catalysts, H₂ with low CO content was produced in the whole tested temperature range of 250-450 ℃. The non-noble metal catalyst 20CuCe showed higher H₂ production rate than 1%Rh/CeO₂ catalyst at 300-400 ℃ and the advantage was more obvious after 20 h testing at 400 ℃. These results further confirmed that CuO-CeO₂ catalysts may be suitable candidates for low temperature hydrogen production from ethanol.

Key words: CuO-CeO₂ catalyst, hydrogen production, oxidative steam reforming, low-temperature

Xue Han, Yunbo Yu, Hong He, Jiaojiao Zhao. Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature[J]. 能源化学(英文), 2013, 22(6): 861-868.

Xue Han, Yunbo Yu, Hong He, Jiaojiao Zhao. Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature[J]. Journal of Energy Chemistry, 2013, 22(6): 861-868.

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Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature

Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO₂ catalysts at low-temperature

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