Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries

doi:10.1016/S2095-4956(14)60146-7

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 269-273.DOI: 10.1016/S2095-4956(14)60146-7

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Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries

Xiaoyan Wu, Jie Ma, Yong-Sheng Hu, Hong Li, Liquan Chen

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2013-11-04 修回日期:2013-12-06 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Yong-Sheng Hu
基金资助:
This work was supported by the funding from "863" Project (2011AA11A235), "973" Projects (2010CB833102 and 2012CB932900), NSFC (No. 51222210 and 11234013), and the 100 Talent Project of the Chinese Academy of Sciences.

Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries

Xiaoyan Wu, Jie Ma, Yong-Sheng Hu, Hong Li, Liquan Chen

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Received:2013-11-04 Revised:2013-12-06 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was supported by the funding from "863" Project (2011AA11A235), "973" Projects (2010CB833102 and 2012CB932900), NSFC (No. 51222210 and 11234013), and the 100 Talent Project of the Chinese Academy of Sciences.

摘要/Abstract

摘要： Nano-sized carboxylates Na₂C₇H₃NO₄ and Na₂C₆H₂N₂O₄ were prepared and investigated as anode materials for lithium-ion batteries. Both carboxylates exhibit high reversible capacities around 190 mAh/g above a cut-off voltage of 0.8 V vs. Li⁺/Li, potentially improving the safety of the batteries. In addition, good rate performance and long cycle life of these carboxylates make them promising candidates as anode materials for lithium-ion batteries.

关键词: carboxylates, Na₂C₇H₃NO₄, Na₂C₆H₂N₂O₄, anode, lithium-ion batteries

Abstract: Nano-sized carboxylates Na₂C₇H₃NO₄ and Na₂C₆H₂N₂O₄ were prepared and investigated as anode materials for lithium-ion batteries. Both carboxylates exhibit high reversible capacities around 190 mAh/g above a cut-off voltage of 0.8 V vs. Li⁺/Li, potentially improving the safety of the batteries. In addition, good rate performance and long cycle life of these carboxylates make them promising candidates as anode materials for lithium-ion batteries.

Key words: carboxylates, Na₂C₇H₃NO₄, Na₂C₆H₂N₂O₄, anode, lithium-ion batteries

Xiaoyan Wu, Jie Ma, Yong-Sheng Hu, Hong Li, Liquan Chen. Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries[J]. 能源化学(英文), 2014, 23(3): 269-273.

Xiaoyan Wu, Jie Ma, Yong-Sheng Hu, Hong Li, Liquan Chen. Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries[J]. Journal of Energy Chemistry, 2014, 23(3): 269-273.

参考文献

[1] Tarascon J M, Armand M. Nature, 2001, 414(6861): 359

[2] Li H, Wang Z X, Chen L Q, Huang X J. Adv Mater, 2009, 21(45): 4593

[3] Suo L M, Hu Y S, Li H, Armand M, Chen L Q. Nat Commun, 2013, 4: 1481

[4] Pan H L, Hu Y S, Chen L Q. Energy & Environ Sci, 2013, 6(8): 2338

[5] Poizot P, Dolhem F. Energy & Environ Sci, 2011, 4(6): 2003

[6] Liang Y L, Tao Z L, Chen J. Adv Energy Mater, 2012, 2(7): 742

[7] Liang Y L, Zhang P, Chen J. Chem Sci, 2013, 4(3): 1330

[8] Visco S J, Mailhe C C, Dejonghe L C, Armand M B. J Electrochem Soc, 1989, 136(3): 661

[9] Liu M L, Visco S J, Dejonghe L C. J Electrochem Soc, 1989, 136(9): 2570

[10] Zhang J Y, Song Z P, Zhan L Z, Tang J, Zhan H, Zhou Y H, Zhan C M. J Power Sources, 2009, 186(2): 496

[11] Sarukawa T, Oyama N. J Electrochem Soc, 2010, 157(2): F23

[12] Nakahara K, Iwasa S, Satoh M, Morioka Y, Iriyama J, Suguro M, Hasegawa E. Chem Phys Lett, 2002, 359(5-6): 351

[13] Suga T, Ohshiro H, Sugita S, Oyaizu K, Nishide H. Adv Mater, 2009, 21(16): 1627

[14] Choi W, Ohtani S, Oyaizu K, Nishide H, Geckeler K E. Adv Mater, 2011, 23(38): 4440

[15] Guo W, Yin Y X, Xin S, Guo Y G, Wan L J. Energy & Environ Sci, 2012, 5(1): 5221

[16] Guo W, Su J, Li Y H, Wan L J, Guo Y G. Electrochim Acta, 2012, 72(30): 81

[17] Nigrey P J, Macinnes D, Nairns D P, MacDiarmid A G, Heeger A J. J Electrochem Soc, 1981, 128(8): 1651

[18] Park K S, Schougaard S B, Goodenough J B. Adv Mater, 2007, 19(6): 848

[19] Zhou M, Qian J F, Ai X P, Yang H X. Adv Mater, 2011, 23(42): 4913

[20] Williams D L, Byrne J J, Driscoll J S. J Electrochem Soc, 1969, 116(1): 2

[21] Chen H, Armand M, Demailly G, Dolhem F, Poizot P, Tarascon J M. Chemsuschem, 2008, 1(4): 348

[22] Renault S, Geng J Q, Dolhem F, Poizot P. Chem Commun, 2011, 47(8): 2414

[23] Suga T, Sugita S, Ohshiro H, Oyaizu K, Nishide H. Adv Mater, 2011, 23(6): 751

[24] Zhu L M, Lei A W, Cao Y L, Ai X P, Yang H X. Chem Commun, 2013, 49(6): 567

[25] Armand M, Grugeon S, Vezin H, Laruelle S, Ribiere P, Poizot P, Tarascon J M. Nat Mater, 2009, 8(2): 120

[26] Walker W, Grugeon S, Vezin H, Laruelle S, Armand M, Wudl F, Tarascon J M. J Mater Chem, 2011, 21(5): 1615

[27] Zhao L, Zhao J M, Hu Y S, Li H, Zhou Z B, Armand M, Chen L Q. Adv Energy Mater, 2012, 2(8): 962

[28] Goodenough J B, Kim Y. Chem Mater, 2009, 22(3): 587

[29] Burkhardt S E, Bois J, Tarascon J M, Hennig R G, Abruna H D. Chem Mater, 2013, 25(2): 132

[30] Kaduk J A. Acta Crystallogr Sect B: Struct Sci, 2000, 56: 474

[31] Arenas J F, Marcos J I. Spectrochim Acta Part A, 1980, 36(12): 1075

Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries

Nano-sized carboxylates as anode materials for rechargeable lithium-ion batteries

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