Dispersing SnO2 nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries

doi:10.1016/S2095-4956(14)60156-X

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 338-345.DOI: 10.1016/S2095-4956(14)60156-X

Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries

Renzong Hu, Wei Sun, Meiqin Zeng, Min Zhu

School of Materials Science and Engineering, South China University of Technology, Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, Guangzhou 510640, Guangdong, China

收稿日期:2013-10-02 修回日期:2014-01-07 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Min Zhu
基金资助:
This work was supported by the National Science Foundation of China (Grant No. 51201065 and No. 51231003), the Natural Science Foundation of Guangdong Province (S2012040008050) and the Doctorate Foundation of Ministry of Education (Grant No. 20120172120007 and No. 2014ZZ0002).

Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries

Renzong Hu, Wei Sun, Meiqin Zeng, Min Zhu

School of Materials Science and Engineering, South China University of Technology, Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, Guangzhou 510640, Guangdong, China

Received:2013-10-02 Revised:2014-01-07 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was supported by the National Science Foundation of China (Grant No. 51201065 and No. 51231003), the Natural Science Foundation of Guangdong Province (S2012040008050) and the Doctorate Foundation of Ministry of Education (Grant No. 20120172120007 and No. 2014ZZ0002).

摘要/Abstract

摘要： We demonstrate a facile route for the massive production of SnO₂/carbon nanocomposite used as high-capacity anode materials of next-generation lithium-ion batteries. The nanocomposite had a unique structure of ultrafine SnO₂ nanocrystals (～5 nm, 80 wt%) homogeneously dispersed in amorphous carbon matrix. This structure design can well accommodate the volume change of Li⁺ insertion/desertion in SnO₂, and prevent the aggregation of the nanosized active materials during cycling, leading to superior cycle performance with stable reversible capacity of 400 mAh/g at a high current rate of 3.3 A/g.

关键词: lithium ion battery, anode, SnO₂ nanocrystals, amorphous carbon, facile strategy

Abstract: We demonstrate a facile route for the massive production of SnO₂/carbon nanocomposite used as high-capacity anode materials of next-generation lithium-ion batteries. The nanocomposite had a unique structure of ultrafine SnO₂ nanocrystals (～5 nm, 80 wt%) homogeneously dispersed in amorphous carbon matrix. This structure design can well accommodate the volume change of Li⁺ insertion/desertion in SnO₂, and prevent the aggregation of the nanosized active materials during cycling, leading to superior cycle performance with stable reversible capacity of 400 mAh/g at a high current rate of 3.3 A/g.

Key words: lithium ion battery, anode, SnO₂ nanocrystals, amorphous carbon, facile strategy

Renzong Hu, Wei Sun, Meiqin Zeng, Min Zhu. Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries[J]. 能源化学(英文), 2014, 23(3): 338-345.

Renzong Hu, Wei Sun, Meiqin Zeng, Min Zhu. Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries[J]. Journal of Energy Chemistry, 2014, 23(3): 338-345.

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https://www.jenergychem.com/CN/Y2014/V23/I3/338

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Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries

Dispersing SnO₂ nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries

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