SO2-tolerant Pt-MoO3/C catalyst for oxygen reduction reaction

doi:10.1016/S2095-4956(14)60158-3

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 358-362.DOI: 10.1016/S2095-4956(14)60158-3

SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction

Xiao Liu^a,b, Hongmin Wang^a, Siguo Chen^a, Xueqiang Qi^a, Huiliang Gao^b, Yi Hui^b, Yang Bai^b, Lin Guo^a, Wei Ding^a, Zidong Wei^a

a. The State Key Laboratory of Power Transmission Equipment & System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;
b. Wuhan Sanjiang Aerospace Yuanfang Technology CO. LTD., Wuhan 430034, Hubei, China

收稿日期:2013-11-04 修回日期:2014-01-17 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Zidong Wei
基金资助:
This work was financially supported by China National 973 Program (2012CB720300), and NSFC of China (Grant No. 21276291 and 21176327).

SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction

Xiao Liu^a,b, Hongmin Wang^a, Siguo Chen^a, Xueqiang Qi^a, Huiliang Gao^b, Yi Hui^b, Yang Bai^b, Lin Guo^a, Wei Ding^a, Zidong Wei^a

a. The State Key Laboratory of Power Transmission Equipment & System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;
b. Wuhan Sanjiang Aerospace Yuanfang Technology CO. LTD., Wuhan 430034, Hubei, China

Received:2013-11-04 Revised:2014-01-17 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was financially supported by China National 973 Program (2012CB720300), and NSFC of China (Grant No. 21276291 and 21176327).

摘要/Abstract

摘要： A Pt-MoO₃/C catalyst, aimed to eliminate the harmful effect of sulfur dioxide (SO₂) on the performance of Pt nanoparticles (NPs) for catalysis of oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFC), is developed and characterized by TEM, XRD and XPS. The results reveal that Pt-MoO₃/C catalyst exhibits not only a higher catalytic activity, but also a better SO₂ poisoning resistance and a better recovery performance than the commercial Pt/C catalyst does.

关键词: platinum, molybdenum trioxide, sulfur dioxide, oxygen reduction reaction, fuel cell

Abstract: A Pt-MoO₃/C catalyst, aimed to eliminate the harmful effect of sulfur dioxide (SO₂) on the performance of Pt nanoparticles (NPs) for catalysis of oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFC), is developed and characterized by TEM, XRD and XPS. The results reveal that Pt-MoO₃/C catalyst exhibits not only a higher catalytic activity, but also a better SO₂ poisoning resistance and a better recovery performance than the commercial Pt/C catalyst does.

Key words: platinum, molybdenum trioxide, sulfur dioxide, oxygen reduction reaction, fuel cell

Xiao Liu, Hongmin Wang, Siguo Chen, Xueqiang Qi, Huiliang Gao, Yi Hui, Yang Bai, Lin Guo, Wei Ding, Zidong Wei. SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction[J]. 能源化学(英文), 2014, 23(3): 358-362.

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SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction

SO₂-tolerant Pt-MoO₃/C catalyst for oxygen reduction reaction

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