A ternary phased SnO2-Fe2O3/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries

doi:10.1016/S2095-4956(14)60160-1

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 376-382.DOI: 10.1016/S2095-4956(14)60160-1

A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries

Wangliang Wu^a,b,c, Yi Zhao^a,b, Jiaxin Li^a,b, Chuxin Wu^a,b, Lunhui Guan^a,b

a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China;
b. Key Laboratory of Design and Assembly of Functional Nanostructures, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China;
c. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2013-11-23 修回日期:2014-01-02 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Lunhui Guan
基金资助:
This work was supported by the National Key Project on Basic Research (Grant No. 2011CB935904), the National Natural Science Foundation of China (Grant No. 21171163, 91127020) and NSF for Distinguished Young Scholars of Fujian Province (Grant No. 2013J06006).

A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries

Wangliang Wu^a,b,c, Yi Zhao^a,b, Jiaxin Li^a,b, Chuxin Wu^a,b, Lunhui Guan^a,b

a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China;
b. Key Laboratory of Design and Assembly of Functional Nanostructures, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China;
c. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-11-23 Revised:2014-01-02 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was supported by the National Key Project on Basic Research (Grant No. 2011CB935904), the National Natural Science Foundation of China (Grant No. 21171163, 91127020) and NSF for Distinguished Young Scholars of Fujian Province (Grant No. 2013J06006).

摘要/Abstract

摘要： A new SnO₂-Fe₂O₃/SWCNTs (single-walled carbon nanotubes) ternary nanocomposite was first synthesized by a facile hydrothermal approach. SnO₂ and Fe₂O₃ nanoparticles (NPs) were homogeneously located on the surface of SWCNTs, as confirmed by X-ray diffraction (XRD), transmission electron microscope (TEM) and energy dispersive X-ray spectroscopy (EDX). Due to the synergistic effect of different components, the as synthesized SnO₂-Fe₂O₃/SWCNTs composite as an anode material for lithium-ion batteries exhibited excellent electrochemical performance with a high capacity of 692 mAh·g^-1 which could be maintained after 50 cycles at 200 mA·g^-1. Even at a high rate of 2000 mA·g^-1, the capacity was still remained at 656 mAh·g^-1.

关键词: SWCNTs, SnO₂, Fe₂O₃, lithium ion batteries, anode materials

Abstract: A new SnO₂-Fe₂O₃/SWCNTs (single-walled carbon nanotubes) ternary nanocomposite was first synthesized by a facile hydrothermal approach. SnO₂ and Fe₂O₃ nanoparticles (NPs) were homogeneously located on the surface of SWCNTs, as confirmed by X-ray diffraction (XRD), transmission electron microscope (TEM) and energy dispersive X-ray spectroscopy (EDX). Due to the synergistic effect of different components, the as synthesized SnO₂-Fe₂O₃/SWCNTs composite as an anode material for lithium-ion batteries exhibited excellent electrochemical performance with a high capacity of 692 mAh·g^-1 which could be maintained after 50 cycles at 200 mA·g^-1. Even at a high rate of 2000 mA·g^-1, the capacity was still remained at 656 mAh·g^-1.

Key words: SWCNTs, SnO₂, Fe₂O₃, lithium ion batteries, anode materials

Wangliang Wu, Yi Zhao, Jiaxin Li, Chuxin Wu, Lunhui Guan. A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries[J]. 能源化学(英文), 2014, 23(3): 376-382.

Wangliang Wu, Yi Zhao, Jiaxin Li, Chuxin Wu, Lunhui Guan. A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries[J]. Journal of Energy Chemistry, 2014, 23(3): 376-382.

参考文献

[1] Goodenough J B, Park K S. J Am Chem Soc, 2013, 135(4): 1167

[2] Armand M, Tarascon J M. Nature, 2008, 451(7179): 652

[3] Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J M. Nature, 2000, 407(6803): 496

[4] Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaka M. Science, 1997, 276(5317): 1395

[5] Huang J Y, Zhong L, Wang C M, Sullivan J P, Xu W, Zhang L Q, Mao S X, Hudak N S, Liu X H, Subramanian A. Science, 2010, 330(6010): 1515

[6] Wang C M, Xu W, Liu J, Zhang J G, Saraf L V, Arey B W, Choi D W, Yang Z G, Xiao J, Thevuthasan S. Nano Lett, 2011, 11(5): 1874

[7] Yin X M, Li C C, Zhang M, Hao Q Y, Liu S, Chen L B, Wang T H. J Phys Chem C, 2010, 114(17): 8084

[8] Wang Y, Wu M H, Jiao Z, Lee J Y. Nanotechnology, 2009, 20(34): 345704

[9] Wang C, Zhou Y, Ge M Y, Xu X B, Zhang Z L, Jiang J Z. J Am Chem Soc, 2010, 132(1): 46

[10] Wang Z Y, Luan D Y, Boey F Y C, Lou X W. J Am Chem Soc, 2011, 133(13): 4738

[11] Fan J, Wang T, Yu C Z, Tu B, Jiang Z Y, Zhao D Y. Adv Mater, 2004, 16(16): 1432

[12] Tian Q H, Zhang Z X, Chen J Z, Yang L, Hirano S I. J Power Sources, 2014, 246: 587

[13] Hu R Z, Sun W, Liu H, Zeng M Q, Zhu M. Nanoscale, 2013, 5(23): 11971

[14] Zhang H K, Song H H, Chen X H, Zhou J S, Zhang H J. Electrochimica Acta, 2012, 59: 160

[15] Li J X, Zhao Y, Wang N, Guan L H. Chem Commun, 2011, 47(18): 5238

[16] Zhao Y, Li J X, Wang N, Wu C X, Dong G F, Guan L H. J Phys Chem C, 2012, 116(35): 18612

[17] Vomiero A, Ferroni M, Comini E, Faglia G, Sberveglieri G. Nano Lett, 2007, 7(12): 3553

[18] Xing L L, Cui C X, Deng P, Nie Y X, Zhao Y Y, He B, Xue X Y. RSC Adv, 2013, 3(26): 10379

[19] Zhu J X, Lu Z Y, Oo M O, Hng H H, Ma J, Zhang H, Yan Q Y. J Mater Chem, 2011, 21(34): 12770

[20] Wu C X, Li J X, Dong G F, Guan L H. J Phys Chem C, 2009, 113(9): 3612

[21] Zhao Y, Li J X, Ding Y H, Guan L H. J Mater Chem, 2011, 21(47): 19101

[22] Reddy M V, Yu T, Sow C H, Shen Z X, Lim C T, Rao G V S, Chowdari B V R. Adv Funct Mater, 2007, 17(15): 2792

[23] Zhu J X, Yin Z Y, Yang D, Sun T, Yu H, Hoster H E, Hng H H, Zhang H, Yan Q Y. Energy Environ Sci, 2013, 6(3): 987

[24] Courtney I A, Dahn J R. J Electrochem Soc, 1997, 144(6): 2045

[25] Jiang X, Yang X L, Zhu Y H, Fan K C, Zhao P, Li C Z. New J Chem, 2013, 37(11): 3671

[26] Wang L, Wang D, Dong Z H, Zhang F X, Jin J. Nano Lett, 2013, 13(4): 1711

A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries

A ternary phased SnO₂-Fe₂O₃/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries

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