Enhanced high temperature cycling performance of LiMn2O4/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism

doi:10.1016/S2095-4956(14)60161-3

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 383-390.DOI: 10.1016/S2095-4956(14)60161-3

Enhanced high temperature cycling performance of LiMn₂O₄/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism

Fengju Bian^a, Zhongru Zhang^a,b, Yong Yang^a,b,c

a. Engineering Research Center of Electrochemical Technology of MOE, Xiamen University, Xiamen 361100, Fujian, China;
b. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
c. School of Energy Research, Xiamen University, Xiamen 361100, Fujian, China

收稿日期:2013-11-29 修回日期:2014-01-14 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Yong Yang
基金资助:
This work was supported by the Key Project of the National Natural Science Foundation of China (Grant No. 21233004).

Enhanced high temperature cycling performance of LiMn₂O₄/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism

Fengju Bian^a, Zhongru Zhang^a,b, Yong Yang^a,b,c

a. Engineering Research Center of Electrochemical Technology of MOE, Xiamen University, Xiamen 361100, Fujian, China;
b. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
c. School of Energy Research, Xiamen University, Xiamen 361100, Fujian, China

Received:2013-11-29 Revised:2014-01-14 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was supported by the Key Project of the National Natural Science Foundation of China (Grant No. 21233004).

摘要/Abstract

摘要： The effects of methylene methanedisulfonate (MMDS) on the high-temperature (～50 ℃) cycle performance of LiMn₂O₄/graphite cells are investigated. By addition of 2 wt% MMDS into a routine electrolyte, the high-temperature cycling performance of LiMn₂O₄/graphite cells can be significantly improved. The analysis of differential capacity curves and energy-dispersive X-ray spectrometry (EDX) indicates that MMDS decomposed on both cathode and anode. The three-electrode system of pouch cell is used to reveal the capacity loss mechanism in the cells. It is shown that the capacity fading of cells without MMDS in the electrolytes is due to irreversible lithium consumption during cycling and irreversible damage of LiMn₂O₄ material, while the capacity fading of cell with 2 wt% MMDS in electrolytes mainly originated from irreversible lithium consumption during cycling.

关键词: methylene methanedisulfonate (MMDS), spinel lithium manganese oxides, electrolyte additives, reference electrode, acting mechanism

Abstract: The effects of methylene methanedisulfonate (MMDS) on the high-temperature (～50 ℃) cycle performance of LiMn₂O₄/graphite cells are investigated. By addition of 2 wt% MMDS into a routine electrolyte, the high-temperature cycling performance of LiMn₂O₄/graphite cells can be significantly improved. The analysis of differential capacity curves and energy-dispersive X-ray spectrometry (EDX) indicates that MMDS decomposed on both cathode and anode. The three-electrode system of pouch cell is used to reveal the capacity loss mechanism in the cells. It is shown that the capacity fading of cells without MMDS in the electrolytes is due to irreversible lithium consumption during cycling and irreversible damage of LiMn₂O₄ material, while the capacity fading of cell with 2 wt% MMDS in electrolytes mainly originated from irreversible lithium consumption during cycling.

Key words: methylene methanedisulfonate (MMDS), spinel lithium manganese oxides, electrolyte additives, reference electrode, acting mechanism

Fengju Bian, Zhongru Zhang, Yong Yang. Enhanced high temperature cycling performance of LiMn₂O₄/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism[J]. 能源化学(英文), 2014, 23(3): 383-390.

参考文献

[1] Goodenough J B, Park K S. J Am Chem Soc, 2013, 135(4): 1167

[2] Tarascon J M, Guromard D. Electrochim Acta, 1993, 38(9): 1221

[3] Mancini M R, Petrucci L, Ronci F, Prosini P P, Passerini S. J Power Sources, 1998, 76(1): 91

[4] Yamada A, Tanaka M, Tanaka K, Sekai K. J Power Sources, 1999, 81-82: 73

[5] Aoshima T, Okahara K, Kiyohara C, Shizuka K. J Power Sources, 2001, 97-98: 377

[6] Wang X, Yagi Y, Lee Y S, Yoshio M, Xia Y, Sakai T. J Power Sources, 2001, 97-98: 427

[7] Aurbach D, Gamolsky K, Markovsky B, Salitra G, Gofer Y, Heider U, Oesten R, Schmidt M. J Electrochem Soc, 2000, 147(4): 1322

[8] Aurbach D, Levi M D, Levi E, Teller H, Markovsky B, Salitra G, Heider U, Heider L. J Electrochem Soc, 1998, 145(9): 3024

[9] Ryu W H, Eom J Y, Yin R Z, Han D W, Kim W K, Kwon H S. J Mater Chem, 2011, 21(39), 15337

[10] Lee D K, Prabakar S J R, Pyo M. J Nanosci Nanotechnol, 2013, 13(8): 5517

[11] Ding Y L, Xie J, Cao G S, Zhu T J, Yu H M, Zhao X B. J Phys Chem C, 2011, 115(19), 9821

[12] Wu Y Q, Zhuo L H, Ming J, Yu Y C, Zhao F Y. J Energy Chem, 2013, 22(3), 468

[13] Kim D K, Muralidharan P, Lee H W, Ruffo R, Yang Y, Chan C K, Peng H L, Huggins R A, Cui Y. Nano Lett, 2008, 8(11): 3948

[14] Liang X, Guo Y L, Qu D Y, Deng B H, Liu H X, Tang D P. J Power Sources, 2013, 225, 286

[15] Zhang X F, Zheng H H, Battaglia V, Axelbaum R L. J Power Sources, 2011, 196(7), 3640

[16] Jia X L, Yan C Z, Chen Z, Wang R R, Zhang Q, Guo L, Wei F, Lu Y F. Chem Comm, 2011, 47(34), 9669

[17] Uehara M, Noguchi T, Sasaki H. US 2013 280 600-A1. 2013

[18] Zuo X X, Fan C J, Xiao X, Liu J S, Nan J M. J Power Sources, 2012, 219, 94

[19] Chan C K, Ruffo R, Hong S S, Huggins R A, Cui Y. J Power Sources, 2009, 189(1): 34

[20] Jansen A N, Dees D W, Abraham D P, Amine K, Henriksen G L. J Power Sources, 2007, 174(2): 373

Enhanced high temperature cycling performance of LiMn₂O₄/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism

Enhanced high temperature cycling performance of LiMn₂O₄/graphite cells with methylene methanedisulfonate (MMDS) as electrolyte additive and its acting mechanism

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

[1]	Jin-Xiu Chen, Xue-Qiang Zhang,bo-Quan Li, Xin-Meng Wang, Peng Shi, Wancheng Zhu, Aibing Chen, Zhehui Jin, Rong Xiang, Jia-Qi Huang, Qiang Zhang. The origin of sulfuryl-containing components in SEI from sulfate additives for stable cycling of ultrathin lithium metal anodes[J]. 能源化学(英文版), 2020, 47(8): 128-131.
[2]	Nawar K.Al-Shara, Farooq Sher, Sania Z.Iqbal, Zaman Sajid, George Z.Chen. Electrochemical study of different membrane materials for the fabrication of stable,reproducible and reusable reference electrode[J]. 能源化学(英文版), 2020, 49(10): 33-41.