Graphene oxide assisted facile hydrothermal synthesis of LiMn0.6Fe0.4PO4 nanoparticles as cathode material for lithium ion battery

doi:10.1016/S2095-4956(14)60163-7

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 397-402.DOI: 10.1016/S2095-4956(14)60163-7

Graphene oxide assisted facile hydrothermal synthesis of LiMn_0.6Fe_0.4PO₄ nanoparticles as cathode material for lithium ion battery

Changchang Xu, Li Li, Fangyuan Qiu, Cuihua An, Yanan Xu, Ying Wang, Yijing Wang, Lifang Jiao, Huatang Yuan

Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Key Laboratory of Advanced Energy Materials Chemistry, Nankai University, Tianjin 300071, China

收稿日期:2013-12-16 修回日期:2014-03-18 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Yijing Wang
基金资助:
This work was financially supported by 973 (2011CB935900, 2010CB631303), NSFC (21231005, 51071087), 111 Project (B12015), MOE(IRT13R30), the Research Fund for the Doctoral Program of Higher Education of China (20120031110001), Tianjin Sci & Tech Project (10SYSYJC27600) and the Nature Science Foundation of Tianjin (11JCYBJC07700).

Graphene oxide assisted facile hydrothermal synthesis of LiMn_0.6Fe_0.4PO₄ nanoparticles as cathode material for lithium ion battery

Changchang Xu, Li Li, Fangyuan Qiu, Cuihua An, Yanan Xu, Ying Wang, Yijing Wang, Lifang Jiao, Huatang Yuan

Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Key Laboratory of Advanced Energy Materials Chemistry, Nankai University, Tianjin 300071, China

Received:2013-12-16 Revised:2014-03-18 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was financially supported by 973 (2011CB935900, 2010CB631303), NSFC (21231005, 51071087), 111 Project (B12015), MOE(IRT13R30), the Research Fund for the Doctoral Program of Higher Education of China (20120031110001), Tianjin Sci & Tech Project (10SYSYJC27600) and the Nature Science Foundation of Tianjin (11JCYBJC07700).

摘要/Abstract

摘要： Assisted by graphene oxide (GO), nano-sized LiMn_0.6Fe_0.4PO₄ with excellent electrochemical performance was prepared by a facile hydrothermal method as cathode material for lithium ion battery. SEM and TEM images indicate that the particle size of LiMn_0.6Fe_0.4PO₄ (S2) was about 80 nm in diameter. The discharge capacity of LiMn_0.6Fe_0.4PO₄ nanoparticles was 140.3 mAh·g^-1 in the first cycle. It showed that graphene oxide was able to restrict the growth of LiMn_0.6Fe_0.4PO₄ and it in situ reduction of GO could improve the electrical conductivity of LiMn_0.6Fe_0.4PO₄ material.

关键词: hydrothermal method, cathode material, lithium-ion batteries, graphene oxide, nano-particles

Abstract: Assisted by graphene oxide (GO), nano-sized LiMn_0.6Fe_0.4PO₄ with excellent electrochemical performance was prepared by a facile hydrothermal method as cathode material for lithium ion battery. SEM and TEM images indicate that the particle size of LiMn_0.6Fe_0.4PO₄ (S2) was about 80 nm in diameter. The discharge capacity of LiMn_0.6Fe_0.4PO₄ nanoparticles was 140.3 mAh·g^-1 in the first cycle. It showed that graphene oxide was able to restrict the growth of LiMn_0.6Fe_0.4PO₄ and it in situ reduction of GO could improve the electrical conductivity of LiMn_0.6Fe_0.4PO₄ material.

Key words: hydrothermal method, cathode material, lithium-ion batteries, graphene oxide, nano-particles

Changchang Xu, Li Li, Fangyuan Qiu, Cuihua An, Yanan Xu, Ying Wang, Yijing Wang, Lifang Jiao, Huatang Yuan. Graphene oxide assisted facile hydrothermal synthesis of LiMn_0.6Fe_0.4PO₄ nanoparticles as cathode material for lithium ion battery[J]. 能源化学(英文), 2014, 23(3): 397-402.

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Graphene oxide assisted facile hydrothermal synthesis of LiMn_0.6Fe_0.4PO₄ nanoparticles as cathode material for lithium ion battery

Graphene oxide assisted facile hydrothermal synthesis of LiMn_0.6Fe_0.4PO₄ nanoparticles as cathode material for lithium ion battery

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