TiO2 nanocrystals/graphene hybrids with enhanced Li-ion storage performance

doi:10.1016/S2095-4956(14)60164-9

能源化学(英文) ›› 2014, Vol. 23 ›› Issue (3): 403-410.DOI: 10.1016/S2095-4956(14)60164-9

• ARTICLES • 上一篇

TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance

Qingqing Zhang, Rong Li, Mengmeng Zhang, Bianli Zhang, Xinglong Gou

Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan, China

收稿日期:2014-01-24 修回日期:2014-04-10 出版日期:2014-05-24 发布日期:2014-05-25
通讯作者: Xinglong Gou
基金资助:
This work was supported by the National Natural Science Foundation of China (51071131) and the Program for New Century Excellent Talents in University (NCET-10-0890).

TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance

Qingqing Zhang, Rong Li, Mengmeng Zhang, Bianli Zhang, Xinglong Gou

Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan, China

Received:2014-01-24 Revised:2014-04-10 Online:2014-05-24 Published:2014-05-25
Supported by:
This work was supported by the National Natural Science Foundation of China (51071131) and the Program for New Century Excellent Talents in University (NCET-10-0890).

摘要/Abstract

摘要： TiO₂ nanocrystals/graphene hybrids (TiO₂-G) with ultrafine TiO₂ nanocrystals (～7 nm in size) conformally coated on ultrathin graphene nanosheets (～2 layers thick) were successfully prepared via a facile one-pot solvothermal route under mediated conditions. With the feature of large surface area, abundant mesopores and high thermal stability, the TiO₂-G nanohybrids exhibited large reversible Li-ion storage capacity with excellent cycling stability (629 mAh·g^-1 after 400 cycles at a current of 60 mA·g^-1) and good rate capability (184 mAh·g^-1 at a current density of 3 A·g^-1) due to the synergetic effects and strong interactions between the components, showing great promise in applications for advanced energy storage devices.

关键词: titania, graphene, nanohybrids, anode materials, rechargeable Li-ion battery

Abstract: TiO₂ nanocrystals/graphene hybrids (TiO₂-G) with ultrafine TiO₂ nanocrystals (～7 nm in size) conformally coated on ultrathin graphene nanosheets (～2 layers thick) were successfully prepared via a facile one-pot solvothermal route under mediated conditions. With the feature of large surface area, abundant mesopores and high thermal stability, the TiO₂-G nanohybrids exhibited large reversible Li-ion storage capacity with excellent cycling stability (629 mAh·g^-1 after 400 cycles at a current of 60 mA·g^-1) and good rate capability (184 mAh·g^-1 at a current density of 3 A·g^-1) due to the synergetic effects and strong interactions between the components, showing great promise in applications for advanced energy storage devices.

Key words: titania, graphene, nanohybrids, anode materials, rechargeable Li-ion battery

Qingqing Zhang, Rong Li, Mengmeng Zhang, Bianli Zhang, Xinglong Gou. TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance[J]. 能源化学(英文), 2014, 23(3): 403-410.

Qingqing Zhang, Rong Li, Mengmeng Zhang, Bianli Zhang, Xinglong Gou. TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance[J]. Journal of Energy Chemistry, 2014, 23(3): 403-410.

参考文献

[1] Chen X B, Mao S S. Chem Rev, 2007, 107: 2891

[2] Chen X B, Liu L, Yu P Y, Mao S S. Science, 2011, 331: 746

[3] Zhou Y H, Li X Y, Pan X L, Bao X H. J Mater Chem, 2012, 22: 14155

[4] Yang, H G, Sun C H, Qiao S Z, Zou J, Liu G, Smith S C, Cheng H M, Lu G Q. Nature, 2008, 453: 638

[5] Wang Z, Yang C Y, Lin T Q, Yin H, Chen P, Wan D Y, Xu F F, Huang F Q, Lin J H, Xie X M, Jiang M H. Energy Environ Sci, 2013, 6: 3007

[6] Fröschl T, Hömann U, Kubiak P, Ku?erová G, Pfanzelt M, Weiss C K, Behm R J, H黶ing N, Kaiser U, Landfester K, Wohlfahrt-Mehrens M. Chem Soc Rev, 2012, 41: 5313

[7] Deng D, Kim M G, Lee J Y, Cho J. Energy Environ Sci, 2009, 2: 818

[8] Chen J S, Tan Y L, Li C M, Cheah Y L, Luan D, Madhavi S, Boey F Y C, Archer L A, Lou X W. J Am Chem Soc, 2010, 132: 6124

[9] Ren Y, Liu Z, Pourpoint F, Armstrong A R, Grey C P, Bruce P G. Angew Chem Int Ed, 2012, 51: 2164

[10] Weng Z Y, Guo H, Liu X M, Wu S L, Yeung K W K, Chu P K. RSC Adv, 2013, 3: 24758

[11] Dylla A G, Henkelman G, Stevenson K J. Acc Chem Res, 2013, 46: 1104

[12] Wagemaker M, Kentgens A P M, Mulder F M. Nature, 2002, 418: 397

[13] He B L, Dong B, Li H L. Electrochem Commun, 2007, 9: 425

[14] Liu S H, Wang Z Y, Yu C, Wu H B, Wang G, Dong, Qiu J S, Eychm黮ler A, Lou X W. Adv Mater, 2013, 25: 3462

[15] Su D S, Centi G. J Energy Chem, 2013, 22: 151

[16] Kim Y A, Hayashi T, Kim J H, Endo M. J Energy Chem, 2013, 22: 183

[17] Qiu Y C, Yan K Y, Yang S H, Jin L M, Deng H, Li W S. ACS Nano, 2010, 4: 6515

[18] Sun Y Q, Wu Q O, Shi G Q. Energy Environ Sci, 2011, 4: 1113

[19] Li N, Zhou G M, Fang R P, Li F, Cheng H M. Nanoscale, 2013, 5: 7780

[20] Ding S J, Chen J S, Luan D Y, Boey F Y C, Madhavi S, Lou X W. Chem Commun, 2011, 47: 5780

[21] Wang J, Zhou Y K, Xiong B, Zhao Y Y, Huang X J, Shao Z P. Electrochim Acta, 2013, 88: 847

[22] Huang H, Fang J W, Xia Y, Tao X Y, Gan Y P, Du J, Zhu W J, Zhang W K. J Mater Chem A, 2013, 1: 2495

[23] He L F, Ma R G, Du N, Ren J G, Wong T L, Li Y Y, Lee S T. J Mater Chem, 2012, 22: 19061

[24] Li N, Liu G, Zhen C, Li F, Zhang L L, Cheng H M. Adv Funct Mater, 2011, 21: 1717

[25] Hu T, Sun X, Sun H T, Yu M P, Lu F Y, Liu C S, Lian J. Carbon, 2013, 51: 322

[26] Yu S X, Yang L W, Tian Y, Yang P, Jiang F, Hu S W, Wei X L, Zhong J X. J Mater Chem A, 2013, 1: 12750

[27] Yang S B, Feng X L, M黮len K. Adv Mater, 2011, 23: 3575

[28] Qiu J X, Zhang P, Ling M, Li S, Liu P R, Zhao H J, Zhang S Q. ACS App Mater Interfaces, 2012, 4: 3636

[29] Li W, Wang F, Feng S S, Wang J X, Sun Z K, Li B, Li Y H, Yang J P, Elzatahry A A, Xia Y Y, Zhao D Y. J Am Chem Soc, 2013, 135: 18300

[30] Li R, Wei Z D, Gou X L, Xu W. RSC Adv, 2013, 3: 9978

[31] Huang X, Qi X Y, Boey F, Zhang H. Chem Soc Rev, 2012, 41: 666

[32] Zhang Q Q, Li R, Zhang M M, Zhang B L, Gou X L. Electrochim Acta, 2014, 115: 425

[33] Chang K, Chen W X. ACS Nano, 2011, 5: 4720

[34] Wang H L, Dai H J. Chem Soc Rev, 2013, 42: 3088

[35] Yang S, Cai Y, Cheng Y W, Varanasi C V, Liu J. J Power Sources, 2012, 218: 140

[36] Chang P Y, Huang C H, Doong R A. Carbon, 2012, 50: 4259

[37] Yoo E, Kim J, Hosono E, Zhou H, Kudo T, Honma I. Nano Lett, 2008, 8: 2277

[38] Xu C H, Xu B H, Gu Y, Xiong Z G, Sun J, Zhao X S. Energy Environ Sci, 2013, 6: 1388

[39] Liu J H, Chen J S, Wei X F, Lou X W, Liu X W. Adv Mater, 2011, 23: 998

[40] Zhang F, Cao H Q, Yue D M, Zhang J X, Qu M Z. Inorg Chem, 2012, 51: 9544

[41] Liu L C, Fan Q, Sun C Z, Gu X R, Li H, Gao F, Chen Y F, Dong L. J Power Sources, 2013, 221: 141

TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance

TiO₂ nanocrystals/graphene hybrids with enhanced Li-ion storage performance

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