Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes

doi:10.1016/S2095-4956(15)60296-0

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (2): 157-170.DOI: 10.1016/S2095-4956(15)60296-0

Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes

Md. Arafat Rahman^a, Xiaojian Wang^a, Cuie Wen^a,b

a. Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia;
b. School of Aerospace, Mechanical and Manufacturing Engineering, RMIT University Bundoora, Victoria 3083, Australia

收稿日期:2014-09-15 修回日期:2014-11-09 出版日期:2015-03-23 发布日期:2015-03-23
通讯作者: Cuie Wen
基金资助:
This work was supported by the Australia-India Strategic Research Fund (AISRF, ST060048)

Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes

Md. Arafat Rahman^a, Xiaojian Wang^a, Cuie Wen^a,b

a. Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia;
b. School of Aerospace, Mechanical and Manufacturing Engineering, RMIT University Bundoora, Victoria 3083, Australia

Received:2014-09-15 Revised:2014-11-09 Online:2015-03-23 Published:2015-03-23
Contact: Cuie Wen
Supported by:
This work was supported by the Australia-India Strategic Research Fund (AISRF, ST060048)

摘要/Abstract

摘要： Nanoporous anatase TiO₂ (np-TiO₂) electrodes have been developed via the anodization of titanium foils in fluoride containing electrolytes, and its application in rechargeable lithium-ion batteries (LIBs) was investigated. Four different types of np-TiO₂ electrodes with different pore diameters of 14.7±8.2nm, 12.8±6.8nm, 11.0±5.5, and 26.7±13.6nm were fabricated for evaluating the effect of nanoporous characteristics on the LIB performance. The discharge capacity of the four battery types 1, 2, 3, and 4 were 132.7 mAh·g^-1, 316.7 mAh·g^-1, 154.3 mAh·g^-1, and 228.4 mAh·g^-1, respectively. In addition, these electrodes 1, 2, 3, and 4 exhibited reversible capacity of 106.9 mAh·g^-1 after 295th, 180.9 mAh·g^-1 after 220th, 126.1 mAh·g^-1 after 150th, and 206.7 mAh·g^-1 after 85th cycle at a rate of 1 C, respectively. It was noted that the cyclic life of the batteries had an inverse relationship, and the capacity had a proportional relationship to the pore diameter. The enhanced electrochemical performance of the nanoporous electrodes can be attributed to the improved conductivity and the enhanced kinetics of lithium insertion/extraction at electrode/electrolyte interfaces because of the large specific surface area of np-TiO₂ electrodes.

关键词: nanoporous TiO₂, negative electrode, capacity, lithium-ion batteries

Abstract: Nanoporous anatase TiO₂ (np-TiO₂) electrodes have been developed via the anodization of titanium foils in fluoride containing electrolytes, and its application in rechargeable lithium-ion batteries (LIBs) was investigated. Four different types of np-TiO₂ electrodes with different pore diameters of 14.7±8.2nm, 12.8±6.8nm, 11.0±5.5, and 26.7±13.6nm were fabricated for evaluating the effect of nanoporous characteristics on the LIB performance. The discharge capacity of the four battery types 1, 2, 3, and 4 were 132.7 mAh·g^-1, 316.7 mAh·g^-1, 154.3 mAh·g^-1, and 228.4 mAh·g^-1, respectively. In addition, these electrodes 1, 2, 3, and 4 exhibited reversible capacity of 106.9 mAh·g^-1 after 295th, 180.9 mAh·g^-1 after 220th, 126.1 mAh·g^-1 after 150th, and 206.7 mAh·g^-1 after 85th cycle at a rate of 1 C, respectively. It was noted that the cyclic life of the batteries had an inverse relationship, and the capacity had a proportional relationship to the pore diameter. The enhanced electrochemical performance of the nanoporous electrodes can be attributed to the improved conductivity and the enhanced kinetics of lithium insertion/extraction at electrode/electrolyte interfaces because of the large specific surface area of np-TiO₂ electrodes.

Key words: nanoporous TiO₂, negative electrode, capacity, lithium-ion batteries

Md. Arafat Rahman, Xiaojian Wang, Cuie Wen. Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes[J]. 能源化学(英文), 2015, 21(2): 157-170.

Md. Arafat Rahman, Xiaojian Wang, Cuie Wen. Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes[J]. Journal of Energy Chemistry, 2015, 21(2): 157-170.

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Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes

Enhanced electrochemical performance of Li-ion batteries with nanoporous titania as negative electrodes

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