Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO2 adsorbent

doi:10.1016/S2095-4956(15)60293-5

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (2): 127-137.DOI: 10.1016/S2095-4956(15)60293-5

• ARTICLES • 下一篇

Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent

Junya Wang^a, Xueyi Mei^a, Liang Huang^a, Qianwen Zheng^a, Yaqian Qiao^a, Ketao Zang^b, Shengcheng Mao^b, Ruoyan Yang^a, Zhang Zhang^a, Yanshan Gao^a, Zhanhu Guo^c, Zhanggen Huang^d, Qiang Wang^a,d

a. College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China;
b. Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing 100124, China;
c. Integrated Composites Laboratory, Dan F Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710, USA;
d. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China

收稿日期:2014-10-17 修回日期:2014-11-23 出版日期:2015-03-23 发布日期:2015-03-23
通讯作者: Qiang Wang
基金资助:
This work was supported by the Fundamental Research Funds for the Central Universities (BLYJ201509), the Fundamental Research Funds for the Central Universities (TD-JC-2013-3), the Program for New Century Excellent Talents in University (NCET-12-0787), Beijing Nova Programme (Z131109000413013), the National Natural Science Foundation of China (51308045), and the Foundation of State Key Laboratory of Coal Conversion (Grant No. J14-15-309), Institute of Coal Chemistry, Chinese Academy of Sciences.

Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent

Junya Wang^a, Xueyi Mei^a, Liang Huang^a, Qianwen Zheng^a, Yaqian Qiao^a, Ketao Zang^b, Shengcheng Mao^b, Ruoyan Yang^a, Zhang Zhang^a, Yanshan Gao^a, Zhanhu Guo^c, Zhanggen Huang^d, Qiang Wang^a,d

a. College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China;
b. Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing 100124, China;
c. Integrated Composites Laboratory, Dan F Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710, USA;
d. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China

Received:2014-10-17 Revised:2014-11-23 Online:2015-03-23 Published:2015-03-23
Contact: Qiang Wang
Supported by:
This work was supported by the Fundamental Research Funds for the Central Universities (BLYJ201509), the Fundamental Research Funds for the Central Universities (TD-JC-2013-3), the Program for New Century Excellent Talents in University (NCET-12-0787), Beijing Nova Programme (Z131109000413013), the National Natural Science Foundation of China (51308045), and the Foundation of State Key Laboratory of Coal Conversion (Grant No. J14-15-309), Institute of Coal Chemistry, Chinese Academy of Sciences.

摘要/Abstract

摘要： In this contribution, a novel high-temperature CO₂ adsorbent consisting of Mg-Al layered double hydroxide (LDH) and graphene oxide (GO) nanosheets was prepared and evaluated. The nanocomposite-type adsorbent was synthesized based on the electrostatically driven self-assembly between positively charged Mg-Al LDH single sheet and negatively charged GO monolayer. The characteristics of this novel adsorbent were investigated using XRD, FE-SEM, HRTEM, FT-IR, BET and TGA. The results showed that both the CO₂ adsorption capacity and the multi-cycle stability of LDH were increased with the addition of GO owing to the enhanced particle dispersion and stabilization. In particular, the absolute CO₂ capture capacity of LDH was increased by more than twice by adding 6.54 wt% GO as support. GO appeared to be especially effective for supporting LDH sheets. Moreover, the CO₂ capture capacity of the adsorbent could be further increased by doping with 15 wt% K₂CO₃. This work demonstrated a new approach for the preparation of LDH-based hybrid-type adsorbents for CO₂ capture.

关键词: CO₂ capture, global warming, graphene oxide, hybrid materials, recycling

Abstract: In this contribution, a novel high-temperature CO₂ adsorbent consisting of Mg-Al layered double hydroxide (LDH) and graphene oxide (GO) nanosheets was prepared and evaluated. The nanocomposite-type adsorbent was synthesized based on the electrostatically driven self-assembly between positively charged Mg-Al LDH single sheet and negatively charged GO monolayer. The characteristics of this novel adsorbent were investigated using XRD, FE-SEM, HRTEM, FT-IR, BET and TGA. The results showed that both the CO₂ adsorption capacity and the multi-cycle stability of LDH were increased with the addition of GO owing to the enhanced particle dispersion and stabilization. In particular, the absolute CO₂ capture capacity of LDH was increased by more than twice by adding 6.54 wt% GO as support. GO appeared to be especially effective for supporting LDH sheets. Moreover, the CO₂ capture capacity of the adsorbent could be further increased by doping with 15 wt% K₂CO₃. This work demonstrated a new approach for the preparation of LDH-based hybrid-type adsorbents for CO₂ capture.

Key words: CO₂ capture, global warming, graphene oxide, hybrid materials, recycling

Junya Wang, Xueyi Mei, Liang Huang, Qianwen Zheng, Yaqian Qiao, Ketao Zang, Shengcheng Mao, Ruoyan Yang, Zhang Zhang, Yanshan Gao, Zhanhu Guo, Zhanggen Huang, Qiang Wang. Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent[J]. 能源化学(英文), 2015, 21(2): 127-137.

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Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent

Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent

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