Novel application of LiCoO2 as a high-performance candidate material for supercapacitor

doi:10.1016/S2095-4956(15)60300-X

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (2): 193-198.DOI: 10.1016/S2095-4956(15)60300-X

Novel application of LiCoO₂ as a high-performance candidate material for supercapacitor

Yanan Xu^b, Liangzhong Ding^a, Tongsheng Zhong^a, Xiao Han^c, Lifang Jiao^b, Huatang Yuan^b, Yijing Wang^b

a. College of Chemistry and Environment Engineering, Hunan City University, Yiyang 413000, Hunan, China;
b. Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin Key Lab of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China;
c. Maple Leaf International School-Tianjin TEDA, Tianjin 300457, China

收稿日期:2014-09-23 修回日期:2014-12-25 出版日期:2015-03-23 发布日期:2015-03-23
通讯作者: Liangzhong Ding, Yijing Wang
基金资助:
This work was supported by the Scientific Research Fund of Hunan Provincial Science & Technology Department (2012FJ3023) and the Research Fund for the Doctroral Program of Higher Education of China (20120031110001).

Novel application of LiCoO₂ as a high-performance candidate material for supercapacitor

Yanan Xu^b, Liangzhong Ding^a, Tongsheng Zhong^a, Xiao Han^c, Lifang Jiao^b, Huatang Yuan^b, Yijing Wang^b

a. College of Chemistry and Environment Engineering, Hunan City University, Yiyang 413000, Hunan, China;
b. Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin Key Lab of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China;
c. Maple Leaf International School-Tianjin TEDA, Tianjin 300457, China

Received:2014-09-23 Revised:2014-12-25 Online:2015-03-23 Published:2015-03-23
Contact: Liangzhong Ding, Yijing Wang
Supported by:
This work was supported by the Scientific Research Fund of Hunan Provincial Science & Technology Department (2012FJ3023) and the Research Fund for the Doctroral Program of Higher Education of China (20120031110001).

摘要/Abstract

摘要： Electrochemical performances of LiCoO₂ as a candidate material for supercapacitor are systematically investigated. LiCoO₂ nanomaterials are synthesized via hydrothermal reaction with consequent calcination process. And the particle size increases as the calcination temperature rises. LCO-650 sample with the largest particle size displays the maximum capacitances of 817.5 F·g^-1 with the most outstanding capacity retention rate of 96.8% after 2000 cycles. It is shown that large particle size is beneficial to the electrochemical and structural stability of LiCoO₂ materials. We speculate that the micron-sized waste LiCoO₂ materials have great potential for supercapacitor application. It may provide a novel recovered approach for spent LIBs and effectively relieve the burdens on the resource waste and environment pollution.

关键词: lithium cobalt oxide, hydrothermal reaction, supercapacitor, calcination

Abstract: Electrochemical performances of LiCoO₂ as a candidate material for supercapacitor are systematically investigated. LiCoO₂ nanomaterials are synthesized via hydrothermal reaction with consequent calcination process. And the particle size increases as the calcination temperature rises. LCO-650 sample with the largest particle size displays the maximum capacitances of 817.5 F·g^-1 with the most outstanding capacity retention rate of 96.8% after 2000 cycles. It is shown that large particle size is beneficial to the electrochemical and structural stability of LiCoO₂ materials. We speculate that the micron-sized waste LiCoO₂ materials have great potential for supercapacitor application. It may provide a novel recovered approach for spent LIBs and effectively relieve the burdens on the resource waste and environment pollution.

Key words: lithium cobalt oxide, hydrothermal reaction, supercapacitor, calcination

Yanan Xu, Liangzhong Ding, Tongsheng Zhong, Xiao Han, Lifang Jiao, Huatang Yuan, Yijing Wang. Novel application of LiCoO₂ as a high-performance candidate material for supercapacitor[J]. 能源化学(英文), 2015, 21(2): 193-198.

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Novel application of LiCoO₂ as a high-performance candidate material for supercapacitor

Novel application of LiCoO₂ as a high-performance candidate material for supercapacitor

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