Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass

doi:10.1016/S2095-4956(15)60302-3

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (2): 207-212.DOI: 10.1016/S2095-4956(15)60302-3

Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass

Zhibao Huo^a, Yan Fang^b, Guodong Yao^a, Xu Zeng^a, Dezhang Ren^a, Fangming Jin^a

a. School of Environmental Science and Engineering, the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China;
b. State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

收稿日期:2014-08-25 修回日期:2014-10-23 出版日期:2015-03-23 发布日期:2015-03-23
通讯作者: Fangming Jin
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 21277091), the State Key Program of National Natural Science Foundation of China (No. 21436007), key Basic Research Projects of Science and Technology Commission of Shanghai (14JC1403100), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (ZXDF160002) and the Project-sponsored by SRF for ROCS, SEM (BG1600002).

Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass

Zhibao Huo^a, Yan Fang^b, Guodong Yao^a, Xu Zeng^a, Dezhang Ren^a, Fangming Jin^a

a. School of Environmental Science and Engineering, the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China;
b. State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

Received:2014-08-25 Revised:2014-10-23 Online:2015-03-23 Published:2015-03-23
Contact: Fangming Jin
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 21277091), the State Key Program of National Natural Science Foundation of China (No. 21436007), key Basic Research Projects of Science and Technology Commission of Shanghai (14JC1403100), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (ZXDF160002) and the Project-sponsored by SRF for ROCS, SEM (BG1600002).

摘要/Abstract

摘要： An improved two-step process for converting carbohydrate biomass to acetic acid under hydrothermal conditions is proposed. The first step consists of the production of lactic acid from carbohydrate biomass, and the second step consists of conversion of the lactic acid obtained in the first step to acetic acid using CuO as an oxidant. The results indicated that CuO as an oxidant in the second step can significantly improve the production of high-purity acetic acid from lactic acid, and the maximum yield of acetic acid was 61%, with a purity of 90%. The yield of acetic acid obtained using the improved two-step hydrothermal process from carbohydrate biomass, such as glucose, cellulose and starch, was greater than that obtained using traditional two-step process with H₂O₂ or O₂. In addition, a proposed pathway for the production of acetic acid from lactic acid in the second step with CuO was also discussed. The present study provides a useful two-step process for the production of acetic acid from carbohydrate biomass.

关键词: carbohydrate biomass, lactic acid, CuO, acetic acid, hydrothermal reactions

Abstract: An improved two-step process for converting carbohydrate biomass to acetic acid under hydrothermal conditions is proposed. The first step consists of the production of lactic acid from carbohydrate biomass, and the second step consists of conversion of the lactic acid obtained in the first step to acetic acid using CuO as an oxidant. The results indicated that CuO as an oxidant in the second step can significantly improve the production of high-purity acetic acid from lactic acid, and the maximum yield of acetic acid was 61%, with a purity of 90%. The yield of acetic acid obtained using the improved two-step hydrothermal process from carbohydrate biomass, such as glucose, cellulose and starch, was greater than that obtained using traditional two-step process with H₂O₂ or O₂. In addition, a proposed pathway for the production of acetic acid from lactic acid in the second step with CuO was also discussed. The present study provides a useful two-step process for the production of acetic acid from carbohydrate biomass.

Key words: carbohydrate biomass, lactic acid, CuO, acetic acid, hydrothermal reactions

Zhibao Huo, Yan Fang, Guodong Yao, Xu Zeng, Dezhang Ren, Fangming Jin. Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass[J]. 能源化学(英文), 2015, 21(2): 207-212.

Zhibao Huo, Yan Fang, Guodong Yao, Xu Zeng, Dezhang Ren, Fangming Jin. Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass[J]. Journal of Energy Chemistry, 2015, 21(2): 207-212.

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Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass

Improved two-step hydrothermal process for acetic acidproduction from carbohydrate biomass

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