Preparation of nano-PANI@MnO2 by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (4): 388-393.

Preparation of nano-PANI@MnO₂ by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance

Fen Ran^a,b, Yunlong Yang^a, Lei Zhao^a, Xiaoqin Niu^b, Dingjun Zhang^a, Lingbin Kong^a, Yongchun Luo^a, Long Kang^a

a State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, Gansu, China;
b Department of Chemistry and Biochemistry, University of California, 1156 High Street, Santa Cruz, CA 95064, USA

收稿日期:2015-03-21 修回日期:2015-07-01 发布日期:2015-08-21
通讯作者: Fen Ran
基金资助:
This work was supported by the National Natural Science Foundation of China (51203071, 51363014 and 51362018), China Postdoctoral Science Foundation (2014M552509), the Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) (sklpme2014-4-25), the Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology (J201402), and the University Scientific Research Project of Gansu Province (2014B-025).

Preparation of nano-PANI@MnO₂ by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance

Fen Ran^a,b, Yunlong Yang^a, Lei Zhao^a, Xiaoqin Niu^b, Dingjun Zhang^a, Lingbin Kong^a, Yongchun Luo^a, Long Kang^a

a State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, Gansu, China;
b Department of Chemistry and Biochemistry, University of California, 1156 High Street, Santa Cruz, CA 95064, USA

Received:2015-03-21 Revised:2015-07-01 Published:2015-08-21
Contact: Fen Ran
Supported by:
This work was supported by the National Natural Science Foundation of China (51203071, 51363014 and 51362018), China Postdoctoral Science Foundation (2014M552509), the Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) (sklpme2014-4-25), the Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology (J201402), and the University Scientific Research Project of Gansu Province (2014B-025).

摘要/Abstract

摘要： In this study, nano-polyanline and manganese oxide nanometer tubular composites (nano-PANI@MnO₂) were prepared by a surface initiated polymerization method and used as electrochemical capacitor electrode materials; and the effect of aniline amount on the microstructure and electrochemical performance was investigated. The microstructures and surface morphologies of nano-PANI@MnO₂ were characterized by X-ray diffraction, scanning electron microscopy and fourier transformation infrared spectroscope. The electrochemical performance of these composite materials was performed with cyclic voltammetry, charge-discharge test and electrochemical impedance spectroscopy, respectively. The results demonstrate that the feed ratio of aniline to MnO₂ played a very important role in constructing the hierarchically nano-structure, which would, hence, determine the electrochemical performance of the materials. Using the templateassisted strategy and controlling the feed ratio of aniline to MnO₂, the nanometer tubular structure of nano-PANI@MnO₂ was obtained. A maximum specific capacitance of 386 F/g was achieved in aqueous 1 mol/L NaNO₃ electrolyte with the potential range from 0 to 0.6 V (vs. SCE).

关键词: Electrochemical capacitors, Nano-PANI@MnO₂, Electrode materials

Abstract: In this study, nano-polyanline and manganese oxide nanometer tubular composites (nano-PANI@MnO₂) were prepared by a surface initiated polymerization method and used as electrochemical capacitor electrode materials; and the effect of aniline amount on the microstructure and electrochemical performance was investigated. The microstructures and surface morphologies of nano-PANI@MnO₂ were characterized by X-ray diffraction, scanning electron microscopy and fourier transformation infrared spectroscope. The electrochemical performance of these composite materials was performed with cyclic voltammetry, charge-discharge test and electrochemical impedance spectroscopy, respectively. The results demonstrate that the feed ratio of aniline to MnO₂ played a very important role in constructing the hierarchically nano-structure, which would, hence, determine the electrochemical performance of the materials. Using the templateassisted strategy and controlling the feed ratio of aniline to MnO₂, the nanometer tubular structure of nano-PANI@MnO₂ was obtained. A maximum specific capacitance of 386 F/g was achieved in aqueous 1 mol/L NaNO₃ electrolyte with the potential range from 0 to 0.6 V (vs. SCE).

Key words: Electrochemical capacitors, Nano-PANI@MnO₂, Electrode materials

Fen Ran, Yunlong Yang, Lei Zhao, Xiaoqin Niu, Dingjun Zhang, Lingbin Kong, Yongchun Luo, Long Kang. Preparation of nano-PANI@MnO₂ by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance[J]. 能源化学(英文), 2015, 21(4): 388-393.

参考文献

[1] M. Winter, R.J. Brodd, Chem. Rev 104 (10) (2004) 4245.

[2] G.H. Yuan, H.D.Wang, J. Energy Chem 23 (5) (2014) 657-661.

[3] B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals And Technological Applications, Kluwer Academic/Plenum, New York, 1999 (Chapter 15).

[4] L. Cao, F. Xu, Y.Y. Liang, H.L. Li, Adv. Mater 16 (20) (2004) 1853-1857.

[5] D.D. Zhao,W.J. Zhou, H.L. Li, Chem. Mater 19 (16) (2007) 3882-3891.

[6] G.W. Yang, C.L. Xu, H.L. Li, Chem. Commun 48 (2008) 6537-6539.

[7] A. Burke, J. Power Sour. 91 (1) (2000) 37.

[8] L.B. Kong, M.C. Liu, J.W. Lang, J. Solid State Electrochem 15 (3) (2011) 571-577.

[9] D.L. Ma, Z.Wu, Z.Y. Cao, J. Energy Chem 23 (3) (2014) 346.

[10] S.W. Phang, N. Kuramoto, Polym. Compos 30 (7) (2009) 970.

[11] A. Subramania, S.L. Devi, Polym. Adv. Technol. 19 (7) (2008) 725.

[12] R.N. Reddy, R.G. Reddy, J. Power Sour. 124 (1) (2003) 330.

[13] H.L. Fan, F. Ran, X.X. Zhang, H.M. Song, W.X. Jing, K.W. Shen, L.B. Kong, L. Kang, J. Energy Chem 23 (6) (2014) 684.

[14] X.F. Lu, H. Mao, D.M. Chao,W.J. Zhang, Y.Wei, J. Solid State Chem. 179 (8) (2006) 2609.

[15] M. Malta, R.M. Torresi, Electrochim. Acta 50 (25-26) (2005) 5009-5014.

[16] X. Zhang, L.Y. Ji, S.C. Zhang,W.S. Yang, J. Power Sour. 173 (2) (2007) 1017.

[17] F.J. Liu, J. Power Sour. 182 (1) (2008) 383.

[18] Q.Q. Sun, S.J. Bao, Nano-Micro Lett 5 (4) (2013) 289.

[19] R.K. Sharma, A.C. Rastog, S.B. Desu, Electrochim. Acta 53 (26) (2008) 7690.

[20] C.Z. Yuan, L.H. Su, B. Gao, X.G. Zhang, Electrochim. Acta 53 (24) (2008) 7039.

[21] F. Ran, H.L. Fan, L.R.Wang, J. Energy Chem 22 (6) (2013) 928-934.

[22] S.R. Sivakkumar, J.M. Ko, D.Y. Kim, B.C. Kim, G.G. Wallace, Electrochim. Acta 52 (25) (2007) 7377.

[23] K.Q. Ding, F.M. Cheng, Synth. Metals 159 (21-22) (2009) 2122.

[24] Y. Sun, S.R. Wilson, D.I. Schuster, J. Am. Chem. Soc. 123 (22) (2001) 5348.

[25] Q.W. Li, H. Yan, Y. Cheng, J. Zhang, Z.F. Liu, J. Mater. Chem 12 (4) (2002) 1179.

[26] H.L. Fan, F. Ran, X.X. Zhang, Electrochim. Acta 138 (2014) 368-375.

[27] S. Quillard, G. Louarn, S. Lefrant, A.G. MacDiarmid, Phys. Rev. B 50 (8) (1994) 12496.

[28] H. Zengin, W. Zhou, J. Jin, R. Cserw, D.W. Smith Jr, L. Echegoyen, D.L. Carroll, S.H. Foulger, J. Ballato, Adv. Mater. 14 (20) (2002) 1480.

[29] L.B. Kong, J. Zhang, J.J. An, Y.C. Luo, L. Kang, J. Mater. Sci. 43 (10) (2008) 3664.

[30] L.J. Pan, L. Pu, Y. Shi, S.Y. Song, Z. Xu, R. Zhang, Y.D. Zheng, Adv.Mater. 19 (3) (2007) 461.

[31] J.K. Yuan,W.N. Li, S. Gomez, S.L. Suib, J. Am. Chem. Soc. 127 (30) (2005) 14184.

[32] Y.T. Tan, F. Ran, L.B. Kong, J. Liu, L. Kang, Synth. Metals 162 (1-2) (2012) 114.

[33] H.Y. Mi, X.G. Zhang, X.G. Ye, S.D. Yang, J. Power Sour. 176 (1) (2008) 403.

[34] J. Li, X.Y.Wang, Q.H. Huang, J. Power Sour. 158 (1) (2006) 784.

[35] L.B. Kong, M. Liu, J.W. Lang, Y.C. Luo, L. Kang, J. Electrochem. Soc 156 (12) (2009) A1000.

[36] W.B. Zhong, J.Y. Deng, Y.S. Yang, W.T. Yang, Macromol. Rapid Commun 26 (5) (2005) 395.

[37] K.K. Liu, Z.L. Hu, R. Xue, J.R. Zhang, Z.J. Zhu, J. Power Sour. 179 (2) (2008) 858.

Preparation of nano-PANI@MnO₂ by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance

Preparation of nano-PANI@MnO₂ by surface initiated polymerization method using as a nano-tubular electrode material: The amount effect of aniline on the microstructure and electrochemical performance

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