Catalytic conversion of guaiacol to alcohols for bio-oil upgrading

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (4): 425-431.

Catalytic conversion of guaiacol to alcohols for bio-oil upgrading

Minghao Zhou, Yuan Wang, Yanbin Wang, Guomin Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China

收稿日期:2015-02-13 修回日期:2015-06-30 发布日期:2015-08-21
通讯作者: Guomin Xiao
基金资助:
Authors are grateful for the financial support from the National Hi-tech Research and Development Program of China (863 Program) (2012AA051801), the Fundamental Research Funds for the Central Universities (No. CXZZ13_0112) and the Scientific Research Foundation of Graduate School of Southeast University (YBPY1408).

Catalytic conversion of guaiacol to alcohols for bio-oil upgrading

Minghao Zhou, Yuan Wang, Yanbin Wang, Guomin Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China

Received:2015-02-13 Revised:2015-06-30 Published:2015-08-21
Contact: Guomin Xiao
Supported by:
Authors are grateful for the financial support from the National Hi-tech Research and Development Program of China (863 Program) (2012AA051801), the Fundamental Research Funds for the Central Universities (No. CXZZ13_0112) and the Scientific Research Foundation of Graduate School of Southeast University (YBPY1408).

摘要/Abstract

摘要： Guaiacol was chosen to represent O-containing chemicals with lower effective hydrogen carbon ratio (H/C_eff factor) in bio-oil, and the hydrodeoxygenation of guaiacol was investigated over non-precious and nonsulfided catalysts. Effects of metal composition, reaction temperature, and hydrogen pressure on conversion and selectivity were investigated systematically. Among various compositions of catalysts, NiCo/CNT exhibited best performance of guaiacol conversion with higher selectivity towards desired alcohols with higher H/C_eff factor. The reaction pathways of guaiacol in aqueous were proposed based on the product analyzed. Results show that metal composition and temperature have great effects on the conversion of guaiacol and the yields of desired products.

关键词: Hydrogenation, Hydrodeoxygenation, Guaiacol, Bio-oil upgrading, Biofuel

Abstract: Guaiacol was chosen to represent O-containing chemicals with lower effective hydrogen carbon ratio (H/C_eff factor) in bio-oil, and the hydrodeoxygenation of guaiacol was investigated over non-precious and nonsulfided catalysts. Effects of metal composition, reaction temperature, and hydrogen pressure on conversion and selectivity were investigated systematically. Among various compositions of catalysts, NiCo/CNT exhibited best performance of guaiacol conversion with higher selectivity towards desired alcohols with higher H/C_eff factor. The reaction pathways of guaiacol in aqueous were proposed based on the product analyzed. Results show that metal composition and temperature have great effects on the conversion of guaiacol and the yields of desired products.

Key words: Hydrogenation, Hydrodeoxygenation, Guaiacol, Bio-oil upgrading, Biofuel

Minghao Zhou, Yuan Wang, Yanbin Wang, Guomin Xiao. Catalytic conversion of guaiacol to alcohols for bio-oil upgrading[J]. 能源化学(英文), 2015, 21(4): 425-431.

Minghao Zhou, Yuan Wang, Yanbin Wang, Guomin Xiao. Catalytic conversion of guaiacol to alcohols for bio-oil upgrading[J]. Journal of Energy Chemistry, 2015, 21(4): 425-431.

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Catalytic conversion of guaiacol to alcohols for bio-oil upgrading

Catalytic conversion of guaiacol to alcohols for bio-oil upgrading

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