Efficient production of biodiesel from both esterification and transesterification over supported SO42--MoO3-ZrO2-Nd2O3/SiO2 catalysts

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (4): 463-471.

Efficient production of biodiesel from both esterification and transesterification over supported SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ catalysts

Xiuqin Li, Dongmei Tong, Changwei Hu

Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China

收稿日期:2015-01-22 修回日期:2015-05-25 发布日期:2015-08-21
通讯作者: Dongmei Tong, Changwei Hu
基金资助:
This work is financially supported by the National Nature Science Foundation of China (no. 21106089). The characterization of catalysts from Analytical and Testing Center of Sichuan University is greatly appreciated.

Efficient production of biodiesel from both esterification and transesterification over supported SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ catalysts

Xiuqin Li, Dongmei Tong, Changwei Hu

Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China

Received:2015-01-22 Revised:2015-05-25 Published:2015-08-21
Contact: Dongmei Tong, Changwei Hu
Supported by:
This work is financially supported by the National Nature Science Foundation of China (no. 21106089). The characterization of catalysts from Analytical and Testing Center of Sichuan University is greatly appreciated.

摘要/Abstract

摘要： SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ (SMZN/SiO₂) catalysts for the production of biodiesel via both esterification and transesterification were prepared and characterized by N₂ adsorption-desorption isotherms, X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry analysis (TGA), ammonia adsorption Fourier transform infrared spectra (NH₃-FTIR), and ammonia adsorption temperature programmed desorption (NH₃-TPD) to reveal the dependence of the stable catalytic activity on calcination time. The reason for catalyst deactivation was also studied. The calcination time remarkably affected the types of active centers on SMZN/SiO₂, and 4 h was found to be the optimal calcination time. SO₄^2- species bonded with small size ZrO₂ were found to be the stable active centers, where the leaching of SO₄^2- and the deposition of coke were inhibited. The deposition of coke was easier on large size ZrO₂ than on small size ones. Calcination in air flow could eliminate the deposited coke to recover the deactivated catalysts.

关键词: Biodiesel, SMZN/SiO₂ solid acids, Stable active centers, Small size ZrO₂

Abstract: SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ (SMZN/SiO₂) catalysts for the production of biodiesel via both esterification and transesterification were prepared and characterized by N₂ adsorption-desorption isotherms, X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry analysis (TGA), ammonia adsorption Fourier transform infrared spectra (NH₃-FTIR), and ammonia adsorption temperature programmed desorption (NH₃-TPD) to reveal the dependence of the stable catalytic activity on calcination time. The reason for catalyst deactivation was also studied. The calcination time remarkably affected the types of active centers on SMZN/SiO₂, and 4 h was found to be the optimal calcination time. SO₄^2- species bonded with small size ZrO₂ were found to be the stable active centers, where the leaching of SO₄^2- and the deposition of coke were inhibited. The deposition of coke was easier on large size ZrO₂ than on small size ones. Calcination in air flow could eliminate the deposited coke to recover the deactivated catalysts.

Key words: Biodiesel, SMZN/SiO₂ solid acids, Stable active centers, Small size ZrO₂

Xiuqin Li, Dongmei Tong, Changwei Hu. Efficient production of biodiesel from both esterification and transesterification over supported SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ catalysts[J]. 能源化学(英文), 2015, 21(4): 463-471.

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Efficient production of biodiesel from both esterification and transesterification over supported SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ catalysts

Efficient production of biodiesel from both esterification and transesterification over supported SO₄^2--MoO₃-ZrO₂-Nd₂O₃/SiO₂ catalysts

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