Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells

doi:10.1016/j.jechem.2015.10.016

能源化学(英文) ›› 2015, Vol. 21 ›› Issue (6): 779-785.DOI: 10.1016/j.jechem.2015.10.016

Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells

Preeyanut Duanglaor^a, Preecha Thiampanya^a, Taweesak Sudyoadsuk^b, Vinich Promarak^b, Buncha Pulpoka^a

a Supramolecular Chemistry Research Unit and Organic Synthesis Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand;
b Department of Materials Science & Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology(VISTEC), Rayong 21210, Thailand

收稿日期:2015-07-31 修回日期:2015-09-13 出版日期:2015-11-15 发布日期:2015-11-15
通讯作者: Buncha Pulpoka

Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells

Preeyanut Duanglaor^a, Preecha Thiampanya^a, Taweesak Sudyoadsuk^b, Vinich Promarak^b, Buncha Pulpoka^a

a Supramolecular Chemistry Research Unit and Organic Synthesis Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand;
b Department of Materials Science & Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology(VISTEC), Rayong 21210, Thailand

Received:2015-07-31 Revised:2015-09-13 Online:2015-11-15 Published:2015-11-15
Contact: Buncha Pulpoka

摘要/Abstract

摘要： Bipyridylporphyrin derivatives possessing a porphyrin moiety as the electron donor and bipyridyl moiety as the electron-acceptor were designed and synthesized for dye-sensitized solar cells (DSSCs). The photophysical and electrochemical properties were investigated by absorption spectrometry and cyclic voltammetry. Density functional theory (DFT) was employed to study electron distribution. From the photovoltaic performance measurements, a maximum conversion efficiency (η) of 0.38% was achieved based on the bipyridylporphyrin ruthenium dye A7(J_SC=1.33 mA/cm², V_OC=0.45 V, FF=0.64) under 1.5 irradiation (100 mW/cm²).

关键词: Dye-sensitized solar cells (DSSCs), Porphyrin, Ruthenium complex, Energy

Abstract: Bipyridylporphyrin derivatives possessing a porphyrin moiety as the electron donor and bipyridyl moiety as the electron-acceptor were designed and synthesized for dye-sensitized solar cells (DSSCs). The photophysical and electrochemical properties were investigated by absorption spectrometry and cyclic voltammetry. Density functional theory (DFT) was employed to study electron distribution. From the photovoltaic performance measurements, a maximum conversion efficiency (η) of 0.38% was achieved based on the bipyridylporphyrin ruthenium dye A7(J_SC=1.33 mA/cm², V_OC=0.45 V, FF=0.64) under 1.5 irradiation (100 mW/cm²).

Key words: Dye-sensitized solar cells (DSSCs), Porphyrin, Ruthenium complex, Energy

Preeyanut Duanglaor, Preecha Thiampanya, Taweesak Sudyoadsuk, Vinich Promarak, Buncha Pulpoka. Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells[J]. 能源化学(英文), 2015, 21(6): 779-785.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.jenergychem.com/CN/10.1016/j.jechem.2015.10.016

https://www.jenergychem.com/CN/Y2015/V21/I6/779

参考文献

[1] M. Grätzel, Nature 414(2001) 338-344.

[2] M. Grätzel, Inorg. Chem 44(2005) 6841-6851.

[3] B. O'Regan, M. Grätzel, Nature 353(1991) 737-740.

[4] K. Kalyanasundaram, M. Grätzel, Coord. Chem. Rev 177(1998) 347-414.

[5] M.K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Muller, P. Liska, N. Vlachopoulos, M. Grätzel, J. Am. Chem. Soc 115(1993) 6382-6390.

[6] A.J. Mozer, M.J. Griffith, G. Tsekouras, P. Wagner, G.G. Wallace, S. Mori, K. Sunahara, M. Miyashita, J.C. Earles, K.C. Gordon, L. Du, R. Katoh, A. Furube, D.L. Officer, J.Am. Chem. Soc 131(2009) 15621-15623.

[7] J.K. Park, H.R. Lee, J. Chen, H. Shinokubo, A. Osuka, D. Kim, J. Phys. Chem. C 112(2008) 16691-16699.

[8] S. Cherian, C.C. Wamser, J. Phys. Chem. B 104(2000) 3624-3629.

[9] D.F. Watson, A. Marton, A.M. Stux, G.J. Meyer, J. Phys. Chem. B 107(2003) 10971-10973.

[10] D.F. Watson, A. Marton, A.M. Stux, G.J. Meyer, J. Phys. Chem. B 108(2004) 11680-11688.

[11] J. Rochford, D. Chu, A. Hagfeldt, E. Galoppini, J. Am. Chem. Soc 129(2007) 4655-4665.

[12] J. Rochford, E. Galoppini, Langmuir 24(2008) 5366-5374.

[13] Z. Zeng, B. Zhang, C. Lee, X. Peng, X. Liu, S. Meng, Y. Feng, Dyes Pigments 100(2014) 278-285.

[14] T. Higashino, H. Imahori, Dalton Trans 44(2015) 448-463.

[15] P. Chawla, M. Tripathi, Int. J. Energy Res 39(2015) 1579-1596.

[16] M.K. Nazeeruddin, P. Pechy, T. Renouard, S.K. Zakeeruddin, R. Humphry-Baker, P. Comte, J. Am. Chem. Soc 123(2001) 1613-1624.

[17] M.K. Nazeeruddin, F. De Angelis, S. Fantacci, A. Selloni, G. Viscardi, P. Liska, J. Am. Chem. Soc 127(2005) 16835-16847.

[18] T. Duan, K. Fan, Y. Fu, C. Zhong, X. Chen, T. Peng, J. Qin, Dyes Pigments 94(2012) 28-33.

[19] K.D. Seo, M.J. Lee, H.M. Song, H.S. Kang, H.K. Kim, Dyes Pigments 94(2012) 143-149.

[20] C. Wang, J. Li, S. Cai, Z. Ning, D. Zhao, Q. Zhang, J.H. Su, Dyes Pigments 94(2012) 40-48.

[21] K.D. Seo, H.M. Song, M.J. Lee, M. Pastore, C. Anselmi, F.D. Angelis, Dyes Pigments 90(2011) 304-310.

[22] S. Ito, S.M. Zakeeruddin, R. Humphry-Baker, P. Liska, R. Charvet, P. Comte, Adv. Mater 18(2006) 1202-1205.

[23] M.K. Nazeeruddin, R. Humphry-Baker, P. Liska, M. Grätzel, J. Phys. Chem. B 107(2003) 8981-8987.

[24] Q. Wang, W.M. Campbell, E.E. Bonfantani, K.W. Jolley, D.L. Officer, P.J. Walsh, K. Gordon, R. Humphry-Baker, M.K. Nazeeruddin, M. Grätzel, J. Phys. Chem. B 109(2005) 15397-15409.

[25] A. Kay, M. Grätzel, J. Phys. Chem 97(1993) 6272-6277.

[26] R. Chen, X. Yang, H. Tian, X. Wang, A. Hagfeldt, S. Licheng, Chem. Mat 19(2007) 4007-4015.

[27] W. Xu, J. Pei, J. Shi, S. Peng, J. Chen, J. Power Sources 183(2008) 792-798.

[28] J. Li, W.J. Wu, J.B. Yanh, J. Tang, Y.T. Long, J.L. Hua, Sci. China Chem 54(2011) 699-706.

Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells

Synthesis and photophysical properties of donor-acceptor system based bipyridylporphyrins for dye-sensitized solar cells

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Hong Yuan, Qiang Zhang. Practical fuel cells enabled by unprecedented oxygen reduction reaction on 3D nanostructured electrocatalysts[J]. 能源化学(英文版), 2020, 48(9): 107-108.
[2]	Xue Liu, Qiu He, Hong Yuan, chong Yan, Yan Zhao, Xu Xu, Jia-Qi Huang, Yu-Lun Chueh, Qiang Zhang, Liqiang Mai. Interface enhanced well-dispersed Co₉S₈ nanocrystals as an efficient polysulfide host in lithium-sulfur batteries[J]. 能源化学(英文版), 2020, 48(9): 109-115.
[3]	Aili Wang, Zhiyuan Cao, Jianwei Wang, Shurong Wang, chengbo Li, Nuo Li, Lisha Xie, Yong Xiang, Tingshuai Li, Xiaobin Niu, Liming Ding, feng Hao. Vacancy defect modulation in hot-casted NiO_x film for efficient inverted planar perovskite solar cells[J]. 能源化学(英文版), 2020, 48(9): 426-434.
[4]	Yun Qiao, Jiawei Wu, Xiaoguang Cheng, Yudong Pang, Zhansheng Lu, Xiangdong Lou, Qingling Li, Jin Zhao, Shuting Yang, Yang Liu. Construction of robust coupling interface between MoS₂ and nitrogen doped graphene for high performance sodium ion batteries[J]. 能源化学(英文版), 2020, 48(9): 435-442.
[5]	Jing Lv, Jing Ye, Gaole Dai, Zhihui Niu, Yi Sun, Xiaohong Zhang, Yu Zhao. Flame-retarding battery cathode materials based on reversible multi-electron redox chemistry of phenothiazine-based polymer[J]. 能源化学(英文版), 2020, 47(8): 256-262.
[6]	Shangqian Zhao, Li Zhang, Gangning Zhang, Haobo Sun, Juanyu Yang, Shigang Lu. Failure analysis of pouch-type Li-O₂ batteries with superior energy density[J]. 能源化学(英文版), 2020, 45(6): 74-82.
[7]	Zhikai Li, Tao Yang, Shaojun Yuan, Yongxiang Yin, Edwin J. Devid, Qiang Huang, Daniel Auerbach, Aart W. Kleyn. Boudouard reaction driven by thermal plasma for efficient CO₂ conversion and energy storage[J]. 能源化学(英文版), 2020, 45(6): 128-134.
[8]	Xiaoyuan Shi, Shansheng Yu, Ting Deng, Wei Zhang, Weitao Zheng. Unlock the potential of Li₄Ti₅O₁₂ for high-voltage/long-cycling-life and high-safety batteries: Dual-ion architecture superior to lithium-ion storage[J]. 能源化学(英文版), 2020, 44(5): 13-18.
[9]	Mengqi Yuan, Kai Liu. Rational design on separators and liquid electrolytes for safer lithium-ion batteries[J]. 能源化学(英文版), 2020, 43(4): 58-70.
[10]	Yanhong Feng, Suhua Chen, Jue Wang, Bingan Lu. Carbon foam with microporous structure for high performance symmetric potassium dual-ion capacitor[J]. 能源化学(英文版), 2020, 43(4): 129-138.
[11]	Ting Xing, Yinghui Ouyang, Liping Zheng, Xianyou Wang, Hong Liu, Manfang Chen, Ruizhi Yu, Xingyan Wang, Chun Wu. Free-standing ternary metallic sulphides/Ni/C-nanofiber anodes for high-performance lithium-ion capacitors[J]. 能源化学(英文版), 2020, 42(3): 108-115.
[12]	Le Liu, Saisai Zhou, Chengjie Zhao, Tonggang Jiu, Fuzhen Bi, Hongmei Jian, Min Zhao, Guodong Zhang, Lejia Wang, Fenfen Li, Xunwen Xiao. TTA as a potential hole transport layer for application in conventional polymer solar cells[J]. 能源化学(英文版), 2020, 42(3): 210-216.
[13]	Wei Zhang, Dong Wang, Weitao Zheng. A semiconductor-electrochemistry model for design of high-rate Li ion battery[J]. 能源化学(英文版), 2020, 41(2): 100-106.
[14]	Na Liu, Zhenghui Pan, Xiaoyu Ding, Jie Yang, Guoguang Xu, Linge Li, Qi Wang, Meinan Liu, Yuegang Zhang. In-situ growth of vertically aligned nickel cobalt sulfide nanowires on carbon nanotube fibers for high capacitance all-solid-state asymmetric fiber-supercapacitors[J]. 能源化学(英文版), 2020, 41(2): 209-215.
[15]	Nawar K.Al-Shara, Farooq Sher, Sania Z.Iqbal, Zaman Sajid, George Z.Chen. Electrochemical study of different membrane materials for the fabrication of stable,reproducible and reusable reference electrode[J]. 能源化学(英文版), 2020, 49(10): 33-41.