Co/Fe oxide and Ce0.8Gd0.2O2-δ composite interlayer for solid oxide electrolysis cell

doi:10.1016/j.jechem.2016.05.002

能源化学(英文) ›› 2016, Vol. 25 ›› Issue (5): 840-844.DOI: 10.1016/j.jechem.2016.05.002

Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell

Jingbo Yan^1,2, Lei Shang^1,2, Zhe Zhao¹, Dingrong Ou¹, Mojie Cheng¹

a Division of Fuel Cells, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2016-03-07 修回日期:2016-04-17 出版日期:2016-09-15 发布日期:2016-09-30
通讯作者: Mojie Cheng
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 21506208, 21476230 and 21376238) and DICP DMTO201405.

Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell

Jingbo Yan^1,2, Lei Shang^1,2, Zhe Zhao¹, Dingrong Ou¹, Mojie Cheng¹

a Division of Fuel Cells, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2016-03-07 Revised:2016-04-17 Online:2016-09-15 Published:2016-09-30
Contact: Mojie Cheng
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 21506208, 21476230 and 21376238) and DICP DMTO201405.

摘要/Abstract

摘要： A composite interlayer comprised of gadolinia doped ceria (GDC) and Co/Fe oxide was prepared and investigated for solid oxide electrolysis cell with yttrium stabilized zirconia (YSZ) electrolyte and La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) anode. The interlayer was constructed of a base layer of GDC and a top layer of discrete Co₃O₄/FeCo₂O₄ particles. The presence of the GDC layer drastically alleviated the undesired reactions between LSCF and YSZ, and the presence of Co/Fe oxide led to further performance improvement. At 800 ℃ and 45% humidity, the cell with 70% Co/Fe-GDC interlayer achieved 0.98 A/cm² at 1.18 V, 14% higher than the cell without Co/Fe oxide. Electrochemical impedance spectroscopy (EIS) revealed that with higher Co/Fe content, both the ohmic resistance and the polarization resistance of the cell were reduced. It is suggested that Co/Fe oxide can react with the Sr species segregated from LSCF and Sr_1-x (Co,Fe)O_3-δ, a compound with high catalytic activity and electronic conductivity. The Sr-capturing ability of Co/Fe oxide in combination with the Sr-blocking ability of GDC layer can effectively suppress the undesired reaction between LSCF and YSZ, and consequently improve the cell performance.

关键词: Solid oxide electrolysis cell, Ceria interlayer, Cobalt oxide, Sr segregation

Abstract: A composite interlayer comprised of gadolinia doped ceria (GDC) and Co/Fe oxide was prepared and investigated for solid oxide electrolysis cell with yttrium stabilized zirconia (YSZ) electrolyte and La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) anode. The interlayer was constructed of a base layer of GDC and a top layer of discrete Co₃O₄/FeCo₂O₄ particles. The presence of the GDC layer drastically alleviated the undesired reactions between LSCF and YSZ, and the presence of Co/Fe oxide led to further performance improvement. At 800 ℃ and 45% humidity, the cell with 70% Co/Fe-GDC interlayer achieved 0.98 A/cm² at 1.18 V, 14% higher than the cell without Co/Fe oxide. Electrochemical impedance spectroscopy (EIS) revealed that with higher Co/Fe content, both the ohmic resistance and the polarization resistance of the cell were reduced. It is suggested that Co/Fe oxide can react with the Sr species segregated from LSCF and Sr_1-x (Co,Fe)O_3-δ, a compound with high catalytic activity and electronic conductivity. The Sr-capturing ability of Co/Fe oxide in combination with the Sr-blocking ability of GDC layer can effectively suppress the undesired reaction between LSCF and YSZ, and consequently improve the cell performance.

Key words: Solid oxide electrolysis cell, Ceria interlayer, Cobalt oxide, Sr segregation

Jingbo Yan, Lei Shang, Zhe Zhao, Dingrong Ou, Mojie Cheng. Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell[J]. 能源化学(英文), 2016, 25(5): 840-844.

Jingbo Yan, Lei Shang, Zhe Zhao, Dingrong Ou, Mojie Cheng. Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell[J]. Journal of Energy Chemistry, 2016, 25(5): 840-844.

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Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell

Co/Fe oxide and Ce_0.8Gd_0.2O_2-δ composite interlayer for solid oxide electrolysis cell

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