Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

doi:10.1016/j.jechem.2016.06.003

能源化学(英文) ›› 2016, Vol. 25 ›› Issue (5): 874-879.DOI: 10.1016/j.jechem.2016.06.003

Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

Fan Zhou¹, Ningyue Lu¹, Binbin Fan¹, Huigang Wang¹, Ruifeng Li²

a College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
b Key Laboratory of Coal Science and Technology MOE, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

收稿日期:2016-02-26 修回日期:2016-06-20 出版日期:2016-09-15 发布日期:2016-09-30
通讯作者: Binbin Fan, Ruifeng Li
基金资助:
This work is supported by the National Science Foundation of China (Nos. 20971095 and 21576177), and Research Project Supported by Shanxi Scholarship Council of China (2013-047).

Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

Fan Zhou¹, Ningyue Lu¹, Binbin Fan¹, Huigang Wang¹, Ruifeng Li²

a College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
b Key Laboratory of Coal Science and Technology MOE, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

Received:2016-02-26 Revised:2016-06-20 Online:2016-09-15 Published:2016-09-30
Contact: Binbin Fan, Ruifeng Li
Supported by:
This work is supported by the National Science Foundation of China (Nos. 20971095 and 21576177), and Research Project Supported by Shanxi Scholarship Council of China (2013-047).

摘要/Abstract

摘要： Zirconium-based MOFs of the UiO family have attracted considerable attention due to their high thermal, chemical and mechanical stability. With the aim of further exploring the applications of zirconium-based UiO-66 in acid-catalyzed reactions and elucidating the effects of the defects in UiO-66 materials on their catalytic performances, in this work, a series of zirconium-containing UiO-66 samples were synthesized by varying the synthesis temperatures and BDC/Zr (terephthalic acid/ZrCl₄) ratios in the synthesis system. The synthesized UiO-66 samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, scanning electron microscopy (SEM), thermogravimetrical analysis (TGA), temperature-programmed desorption of NH₃(NH₃-TPD). Their catalytic performances were investigated in transesterification of tributyrin and soybean oil with methanol. The results showed that UiO-66 samples with different amounts of defects could be successfully prepared by varying the synthesis temperatures and/or the BDC/Zr ratios used in the synthesis system. The catalytic activities of the UiO-66 materials greatly depended on their linker defects and enhanced with the increase of the defect amount. The UiO-66 was an efficient catalyst for transesterification of tributyrin and soybean oil with methanol under mild reaction conditions and its catalytic activity was comparable to other solid acid catalysts reported in the literatures. The UiO-66 catalyst was relatively stable and could be reused.

关键词: Metal organic frameworks, Solid acid, Transesterification, UiO-66, Catalyst

Abstract: Zirconium-based MOFs of the UiO family have attracted considerable attention due to their high thermal, chemical and mechanical stability. With the aim of further exploring the applications of zirconium-based UiO-66 in acid-catalyzed reactions and elucidating the effects of the defects in UiO-66 materials on their catalytic performances, in this work, a series of zirconium-containing UiO-66 samples were synthesized by varying the synthesis temperatures and BDC/Zr (terephthalic acid/ZrCl₄) ratios in the synthesis system. The synthesized UiO-66 samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, scanning electron microscopy (SEM), thermogravimetrical analysis (TGA), temperature-programmed desorption of NH₃(NH₃-TPD). Their catalytic performances were investigated in transesterification of tributyrin and soybean oil with methanol. The results showed that UiO-66 samples with different amounts of defects could be successfully prepared by varying the synthesis temperatures and/or the BDC/Zr ratios used in the synthesis system. The catalytic activities of the UiO-66 materials greatly depended on their linker defects and enhanced with the increase of the defect amount. The UiO-66 was an efficient catalyst for transesterification of tributyrin and soybean oil with methanol under mild reaction conditions and its catalytic activity was comparable to other solid acid catalysts reported in the literatures. The UiO-66 catalyst was relatively stable and could be reused.

Key words: Metal organic frameworks, Solid acid, Transesterification, UiO-66, Catalyst

Fan Zhou, Ningyue Lu, Binbin Fan, Huigang Wang, Ruifeng Li. Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol[J]. 能源化学(英文), 2016, 25(5): 874-879.

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Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

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