A thiophene-containing covalent triazine-based framework with ultramicropore for CO2 capture

doi:10.1016/j.jechem.2017.07.007

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 902-908.DOI: 10.1016/j.jechem.2017.07.007

A thiophene-containing covalent triazine-based framework with ultramicropore for CO₂ capture

Keke Wang^a, Yuanzhe Tang^a, Qin Jiang^a, Youshi Lan^a, Hongliang Huang^a,b, Dahuan Liu^a, Chongli Zhong^a,b,c

a State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
b State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China;
c Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

收稿日期:2017-05-09 修回日期:2017-07-07 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Hongliang Huang,E-mail addresses:huanghl@mail.buct.edu.cn;Chongli Zhong,E-mail addresses:zhongcl@mail.buct.edu.cn
基金资助:
This work was supported by the National Key R&D Program of China (2016YFB0600901) and the Natural Science Foundation of China (grant nos. 21536001 and 21606007).

A thiophene-containing covalent triazine-based framework with ultramicropore for CO₂ capture

Keke Wang^a, Yuanzhe Tang^a, Qin Jiang^a, Youshi Lan^a, Hongliang Huang^a,b, Dahuan Liu^a, Chongli Zhong^a,b,c

a State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
b State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China;
c Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2017-05-09 Revised:2017-07-07 Online:2017-09-15 Published:2017-11-10
Contact: Hongliang Huang,E-mail addresses:huanghl@mail.buct.edu.cn;Chongli Zhong,E-mail addresses:zhongcl@mail.buct.edu.cn
Supported by:
This work was supported by the National Key R&D Program of China (2016YFB0600901) and the Natural Science Foundation of China (grant nos. 21536001 and 21606007).

摘要/Abstract

摘要： In this work, a 2D covalent triazine-based framework was prepared by using 1,3-dicyanobenzo[c]thiophene (DCBT) as monomer to effectively capture CO₂. The resulting CTF-DCBT was characterized by FT-IR, XPS, PXRD, elemental analysis, SEM, TEM, and N₂ adsorption-desorption. The results indicate that CTF-DCBT is partially crystalline and has ultramicropore (6.5 Å) as well as high heteroatom contents (11.24 wt% and 12.61 wt% for N and S, respectively). In addition, the BET surface area and total pore volume of CTF-DCBT are 500 m²/g and 0.26 cm³/g, respectively. CTF-DCBT possesses excellent thermal stability (450℃) and chemical stability towards boiling water, 4 M HCl, and 1 M NaOH. The CO₂ adsorption capacity of CTF-DCBT is 37.8 cm³/g at 1 bar and 25℃. After six adsorption-desorption cycles, there is no obvious loss of CO₂ uptake observed. Due to the ultramicropore and high heteroatom contents, CTF-DCBT has high isosteric heats of adsorption for CO₂ and high selectivities of CO₂ over N₂ and CH₄. At 25℃, the CO₂/N₂ and CO₂/CH₄ selectivities are 112.5 and 10.3, respectively, which are higher than those of most POFs. Breakthrough curves indicate that CTF-DCBT could effectively separate CO₂/N₂ and CO₂/CH₄ mixtures.

关键词: Covalent triazine-based framework, Ultramicropore, Adsorption, Carbon dioxide

Abstract: In this work, a 2D covalent triazine-based framework was prepared by using 1,3-dicyanobenzo[c]thiophene (DCBT) as monomer to effectively capture CO₂. The resulting CTF-DCBT was characterized by FT-IR, XPS, PXRD, elemental analysis, SEM, TEM, and N₂ adsorption-desorption. The results indicate that CTF-DCBT is partially crystalline and has ultramicropore (6.5 Å) as well as high heteroatom contents (11.24 wt% and 12.61 wt% for N and S, respectively). In addition, the BET surface area and total pore volume of CTF-DCBT are 500 m²/g and 0.26 cm³/g, respectively. CTF-DCBT possesses excellent thermal stability (450℃) and chemical stability towards boiling water, 4 M HCl, and 1 M NaOH. The CO₂ adsorption capacity of CTF-DCBT is 37.8 cm³/g at 1 bar and 25℃. After six adsorption-desorption cycles, there is no obvious loss of CO₂ uptake observed. Due to the ultramicropore and high heteroatom contents, CTF-DCBT has high isosteric heats of adsorption for CO₂ and high selectivities of CO₂ over N₂ and CH₄. At 25℃, the CO₂/N₂ and CO₂/CH₄ selectivities are 112.5 and 10.3, respectively, which are higher than those of most POFs. Breakthrough curves indicate that CTF-DCBT could effectively separate CO₂/N₂ and CO₂/CH₄ mixtures.

Key words: Covalent triazine-based framework, Ultramicropore, Adsorption, Carbon dioxide

Keke Wang, Yuanzhe Tang, Qin Jiang, Youshi Lan, Hongliang Huang, Dahuan Liu, Chongli Zhong. A thiophene-containing covalent triazine-based framework with ultramicropore for CO₂ capture[J]. 能源化学(英文), 2017, 26(5): 902-908.

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A thiophene-containing covalent triazine-based framework with ultramicropore for CO₂ capture

A thiophene-containing covalent triazine-based framework with ultramicropore for CO₂ capture

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