Thermokinetic and conductivity analyzes of the high CO2 chemisorption on Li5AlO4 and alkaline carbonate impregnated Li5AlO4 samples:Effects produced by the use of CO2 partial pressures and oxygen addition

doi:10.1016/j.jechem.2017.05.008

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 919-926.DOI: 10.1016/j.jechem.2017.05.008

Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition

Pedro Sánchez-Camacho, J. Francisco Gómez-García, Heriberto Pfeiffer

Laboratorio de Fisicoquímica y Reactividad de Superficies(LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito exterior s/n, Cd. Universitaria, Del. Coyoacan C. P. 04510, Ciudad de Mexico, Mexico

收稿日期:2017-03-22 修回日期:2017-05-22 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Heriberto Pfeiffer,E-mail addresses:pfeifferperea@gmail.com,pfeiffer@iim.unam.mx
基金资助:
This work was financially supported by the projects PAPⅡTUNAM (IN-101916) and SENER-CONACYT (251801). Authors thank to Adriana Tejeda for technical assistance. PSC and JFGG thank to CONACYT and DGAPA-UNAM for financial support.

Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition

Pedro Sánchez-Camacho, J. Francisco Gómez-García, Heriberto Pfeiffer

Laboratorio de Fisicoquímica y Reactividad de Superficies(LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito exterior s/n, Cd. Universitaria, Del. Coyoacan C. P. 04510, Ciudad de Mexico, Mexico

Received:2017-03-22 Revised:2017-05-22 Online:2017-09-15 Published:2017-11-10
Contact: Heriberto Pfeiffer,E-mail addresses:pfeifferperea@gmail.com,pfeiffer@iim.unam.mx
Supported by:
This work was financially supported by the projects PAPⅡTUNAM (IN-101916) and SENER-CONACYT (251801). Authors thank to Adriana Tejeda for technical assistance. PSC and JFGG thank to CONACYT and DGAPA-UNAM for financial support.

摘要/Abstract

摘要： The effect of CO₂ partial pressure was evaluated during the CO₂ chemisorption in penta lithium aluminate (Li₅AlO₄), using different CO₂ and O₂ partial pressures in the presence or absence of alkaline carbonates. Results showed that using low P_O₂ (0.1) did not affect the kinetic and final CO₂ chemisorption process. Moreover, small additions of oxygen (P_O₂=0.05) into the mixture flue gas, seemed to increase the CO₂ chemisorption. Additionally, the presence of alkaline carbonates modified the CO₂ capture temperature range. CO₂ chemisorption kinetic parameters were determined assuming a double exponential model where direct CO₂ chemisorption and CO₂ chemisorption controlled by diffusion processes are considered. Finally, ionic diffusion was analyzed by ionic conduction analysis, where all the gravimetric and ionic measurements were in good agreement showing different diffusion processes depending on temperature. Finally, the oxygen and alkaline carbonate additions have positive effects during the CO₂ chemisorption process in Li₅AlO₄, and a possible reaction mechanism is presented.

关键词: CO₂ capture, Thermogravimetric analysis, Partial pressure, Ionic conduction

Abstract: The effect of CO₂ partial pressure was evaluated during the CO₂ chemisorption in penta lithium aluminate (Li₅AlO₄), using different CO₂ and O₂ partial pressures in the presence or absence of alkaline carbonates. Results showed that using low P_O₂ (0.1) did not affect the kinetic and final CO₂ chemisorption process. Moreover, small additions of oxygen (P_O₂=0.05) into the mixture flue gas, seemed to increase the CO₂ chemisorption. Additionally, the presence of alkaline carbonates modified the CO₂ capture temperature range. CO₂ chemisorption kinetic parameters were determined assuming a double exponential model where direct CO₂ chemisorption and CO₂ chemisorption controlled by diffusion processes are considered. Finally, ionic diffusion was analyzed by ionic conduction analysis, where all the gravimetric and ionic measurements were in good agreement showing different diffusion processes depending on temperature. Finally, the oxygen and alkaline carbonate additions have positive effects during the CO₂ chemisorption process in Li₅AlO₄, and a possible reaction mechanism is presented.

Key words: CO₂ capture, Thermogravimetric analysis, Partial pressure, Ionic conduction

Pedro Sánchez-Camacho, J. Francisco Gómez-García, Heriberto Pfeiffer. Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition[J]. 能源化学(英文), 2017, 26(5): 919-926.

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Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition

Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition

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