Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO2 to epoxides under mild conditions

doi:10.1016/j.jechem.2017.07.022

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 821-824.DOI: 10.1016/j.jechem.2017.07.022

• COMMUNICATIONS • 上一篇下一篇

Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO₂ to epoxides under mild conditions

Caijuan Liu^a, Xiao-Huan Liu^a, Bo Li^a, Lei Zhang^b, Jian-Gong Ma^a, Peng Cheng^a

a College of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University, Tianjin 300071, China;
b School of Electronic Information & Optical Engineering, Nankai University, Tianjin 300350, China

收稿日期:2017-05-19 修回日期:2017-07-31 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Jian-Gong Ma,E-mail address:mvbasten@nankai.edu.cn
基金资助:
This work was supported by the National Key Projects for Fundamental R&D Program of China (2016YFB0600902) and the NFSC of Tianjin (16JCZDJC36700 and 14JCQNJC03000).

Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO₂ to epoxides under mild conditions

Caijuan Liu^a, Xiao-Huan Liu^a, Bo Li^a, Lei Zhang^b, Jian-Gong Ma^a, Peng Cheng^a

a College of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University, Tianjin 300071, China;
b School of Electronic Information & Optical Engineering, Nankai University, Tianjin 300350, China

Received:2017-05-19 Revised:2017-07-31 Online:2017-09-15 Published:2017-11-10
Contact: Jian-Gong Ma,E-mail address:mvbasten@nankai.edu.cn
Supported by:
This work was supported by the National Key Projects for Fundamental R&D Program of China (2016YFB0600902) and the NFSC of Tianjin (16JCZDJC36700 and 14JCQNJC03000).

摘要/Abstract

摘要： A double active center system, namely Salen-Cu(Ⅱ)@MIL-101(Cr), was successfully synthesized via the "ship in a bottle" approach, which acted as a bifunctional material for both capture and conversion of CO₂ in a single process. For the first time, Salen-Cu(Ⅱ)@MIL-101(Cr) catalyst was developed for the synthesis of propylene carbonate from CO₂ and propylene oxide under room temperature and ambient pressure with a yield of 87.8% over 60 h. Furthermore, the reaction mechanism was also discussed.

关键词: Metal-organic frameworks, Carbon dioxide cycloaddition, Cyclic carbonate, Heterogeneous catalyst

Abstract: A double active center system, namely Salen-Cu(Ⅱ)@MIL-101(Cr), was successfully synthesized via the "ship in a bottle" approach, which acted as a bifunctional material for both capture and conversion of CO₂ in a single process. For the first time, Salen-Cu(Ⅱ)@MIL-101(Cr) catalyst was developed for the synthesis of propylene carbonate from CO₂ and propylene oxide under room temperature and ambient pressure with a yield of 87.8% over 60 h. Furthermore, the reaction mechanism was also discussed.

Key words: Metal-organic frameworks, Carbon dioxide cycloaddition, Cyclic carbonate, Heterogeneous catalyst

Caijuan Liu, Xiao-Huan Liu, Bo Li, Lei Zhang, Jian-Gong Ma, Peng Cheng. Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO₂ to epoxides under mild conditions[J]. 能源化学(英文), 2017, 26(5): 821-824.

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Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO₂ to epoxides under mild conditions

Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO₂ to epoxides under mild conditions

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