Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate

doi:10.1016/j.jechem.2017.08.010

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 825-829.DOI: 10.1016/j.jechem.2017.08.010

Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate

Qiankun Li^a, Zhuo Wang^a, Miao Zhang^a, Pengfei Hou^a,b, Peng Kang^a,b,

a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhongguancun East Road, Haidian District, Beijing 100190, China;
b University of Chinese Academy of Sciences, 19 A Yuquan Road, Beijing 100049, China

收稿日期:2017-07-28 修回日期:2017-08-25 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Peng Kang,E-mail address:pkang@mail.ipc.ac.cn
基金资助:
This work was financially supported by Key Research Program of the Chinese Academy of Sciences (ZDRW-ZS-2016-3), the National Key Research and Development Program of China (2016YFB0600901), and the Instrument Developing Project of the Chinese Academy of Sciences.

Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate

Qiankun Li^a, Zhuo Wang^a, Miao Zhang^a, Pengfei Hou^a,b, Peng Kang^a,b,

a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhongguancun East Road, Haidian District, Beijing 100190, China;
b University of Chinese Academy of Sciences, 19 A Yuquan Road, Beijing 100049, China

Received:2017-07-28 Revised:2017-08-25 Online:2017-09-15 Published:2017-11-10
Contact: Peng Kang,E-mail address:pkang@mail.ipc.ac.cn
Supported by:
This work was financially supported by Key Research Program of the Chinese Academy of Sciences (ZDRW-ZS-2016-3), the National Key Research and Development Program of China (2016YFB0600901), and the Instrument Developing Project of the Chinese Academy of Sciences.

摘要/Abstract

摘要： Tin/tin oxide materials are key electrocatalysts for selective conversion of CO₂ to formate/formic acid. Herein we report a tin oxide material with nitrogen doping by using ammonia treatment at elevated temperature. The N doped material demonstrated enhanced electrocatalytic CO₂ reduction activity, showing high Faradaic efficiency (90%) for formate at -0.65 V vs. RHE with partial current density of 4 mA/cm². The catalysis was contributed to increased electron negativity of N atom compared to O atom. Additionally, the N-doped catalyst demonstrates sulfur tolerance with retained formate selectivity. The analysis after electrolysis shows that the catalyst structure partially converts to metallic Sn, and thus the combined Sn/N-SnO₂ is the key for the active CO₂ catalysis.

关键词: CO₂ reduction, Electrocatalysis, Formate, Tin oxide, Nitrogen doping

Abstract: Tin/tin oxide materials are key electrocatalysts for selective conversion of CO₂ to formate/formic acid. Herein we report a tin oxide material with nitrogen doping by using ammonia treatment at elevated temperature. The N doped material demonstrated enhanced electrocatalytic CO₂ reduction activity, showing high Faradaic efficiency (90%) for formate at -0.65 V vs. RHE with partial current density of 4 mA/cm². The catalysis was contributed to increased electron negativity of N atom compared to O atom. Additionally, the N-doped catalyst demonstrates sulfur tolerance with retained formate selectivity. The analysis after electrolysis shows that the catalyst structure partially converts to metallic Sn, and thus the combined Sn/N-SnO₂ is the key for the active CO₂ catalysis.

Key words: CO₂ reduction, Electrocatalysis, Formate, Tin oxide, Nitrogen doping

Qiankun Li, Zhuo Wang, Miao Zhang, Pengfei Hou, Peng Kang. Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate[J]. 能源化学(英文), 2017, 26(5): 825-829.

参考文献

[1] D.G. Streets, K. Jiang, X. Hu, J.E. Sinton, X.-Q. Zhang, D. Xu, M.Z. Jacobson, J.E. Hansen, Science 294(2001) 1835-1837.

[2] M. Schreier, L. Curvat, F. Giordano, L. Steier, A. Abate, S.M. Zakeeruddin, J. Luo, M.T. Mayer, M. Gratzel, Nat. Commun. 6(2015) 7326.

[3] J. Wei, Q. Ge, R. Yao, Z. Wen, C. Fang, L. Guo, H. Xu, J. Sun, Nat. Commun. 8(2017) 15174.

[4] Z. Zhan, W. Kobsiriphat, J.R. Wilson, M. Pillai, I. Kim, S.A. Barnett, Energy Fuels 23(2009) 3089-3096.

[5] E.E. Benson, C.P. Kubiak, A.J. Sathrum, J.M. Smieja, Chem. Soc. Rev. 38(2009) 89-99.

[6] Y. Chen, C.W. Li, M.W. Kanan, J. Am. Chem. Soc. 134(2012) 19969-19972.

[7] C.W. Li, J. Ciston, M.W. Kanan, Nature 508(2014) 504-507.

[8] X. Feng, K. Jiang, S. Fan, M.W. Kanan, J. Am. Chem. Soc. 137(2015) 4606-4609.

[9] S. Liu, H. Tao, L. Zeng, Q. Liu, Z. Xu, Q. Liu, J.L. Luo, J. Am. Chem. Soc. 139(2017) 2160-2163.

[10] M. Ma, K. Djanashvili, W.A. Smith, Angew. Chem. Int. Ed. Engl 55(2016) 6680-6684.

[11] B. Kumar, M. Asadi, D. Pisasale, S. Sinha-Ray, B.A. Rosen, R. Haasch, J. Abiade, A.L. Yarin, A. Salehi-Khojin, Nat. Commun. 4(2013) 2819.

[12] S. Gao, Z. Sun, W. Liu, X. Jiao, X. Zu, Q. Hu, Y. Sun, T. Yao, W. Zhang, S. Wei, Y. Xie, Nat. Commun. 8(2017) 14503.

[13] Y. Hori, H. Wakebe, T. Tsukamoto, O. Koga, Electrochim. Acta 39(1994) 1833-1839.

[14] Y. Hori, Electrochemical CO₂ reduction on metal electrodes, in:C.G. Vayenas, R.E. White, M.E. Gamboa-Aldeco (Eds.), Modern Aspects of Electrochemistry, Springer, New York, NY, 2008, pp. 89-189.

[15] H. Li, C. Oloman, J. Appl. Electrochem. 37(2007) 1107-1117.

[16] H. Li, C. Oloman, J. Appl. Electrochem. 36(2006) 1105-1115.

[17] M. Jitaru, D.A. Lowy, M. Toma, B.C. Toma, L. Oniciu, J. Appl. Electrochem. 27(1997) 875-889.

[18] Y. Chen, M.W. Kanan, J. Am. Chem. Soc. 134(2012) 1986-1989.

[19] S. Zhang, P. Kang, T.J. Meyer, J. Am. Chem. Soc. 136(2014) 1734-1737.

[20] B. Kumar, V. Atla, J.P. Brian, S. Kumari, T.Q. Nguyen, M. Sunkara, J.M. Spurgeon, Angew. Chem. Int. Ed. 56(2017) 3645-3649.

[21] F. Li, L. Chen, G.P. Knowles, D.R. MacFarlane, J. Zhang, Angew. Chem. Int. Ed. Engl. 56(2017) 505-509.

[22] Q. Li, J. Fu, W. Zhu, Z. Chen, B. Shen, L. Wu, Z. Xi, T. Wang, G. Lu, J.J. Zhu, S. Sun, J. Am. Chem. Soc. 139(2017) 4290-4293.

[23] C. Zhao, J. Wang, J.B. Goodenough, Electrochem. Commun. 65(2016) 9-13.

[24] Y. Li, J. Qiao, X. Zhang, T. Lei, A. Girma, Y. Liu, J. Zhang, ChemElectroChem 3(2016) 1618-1628.

[25] H. Won da, C.H. Choi, J. Chung, M.W. Chung, E.H. Kim, S.I. Woo, ChemSusChem 8(2015) 3092-3098.

[26] Y. Fu, Y. Li, X. Zhang, Y. Liu, J. Qiao, J. Zhang, D.P. Wilkinson, Appl. Energy 175(2016) 536-544.

[27] F. Lei, W. Liu, Y. Sun, J. Xu, K. Liu, L. Liang, T. Yao, B. Pan, S. Wei, Y. Xie, Nat. Commun. 7(2016) 12697.

[28] C. Zhao, J. Wang, Chem. Eng. J. 293(2016) 161-170.

[29] V.S.K. Yadav, M.K. Purkait, RSC Adv. 5(2015) 68551-68557.

[30] S. Lee, H. Ju, R. Machunda, S. Uhm, J.K. Lee, H.J. Lee, J. Lee, J. Mater. Chem. A 3(2015) 3029-3034.

[31] G.K.S. Prakash, F.A. Viva, G.A. Olah, J. Power Sources 223(2013) 68-73.

[32] J. Wu, F.G. Risalvato, S. Ma, X.-D. Zhou, J. Mater. Chem. A 2(2014) 1647-1651.

[33] W. Luc, C. Collins, S. Wang, H. Xin, K. He, Y. Kang, F. Jiao, J. Am. Chem. Soc. 139(2017) 1885-1893.

[34] S. Sarfraz, A.T. Garcia-Esparza, A. Jedidi, L. Cavallo, K. Takanabe, ACS Catal. 6(2016) 2842-2851.

[35] C. Hu, L. Dai, Angew. Chem. Int. Ed. 55(2016) 11736-11758.

[36] L. Dai, Y. Xue, L. Qu, H.-J. Choi, J.-B. Baek, Chem. Rev. 115(2015) 4823-4892.

[37] Y. Cao, Z. Xing, Y. Shen, Z. Li, X. Wu, X. Yan, J. Zou, S. Yang, W. Zhou, Chem. Eng. J. 325(2017) 199-207.

[38] X. Huang, Y. Zhao, Z. Ao, G. Wang, Sci. Rep. 4(2014) 7557.

Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate

Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate

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