Synthesis of polymeric ionic liquids material and application in CO2 adsorption

doi:10.1016/j.jechem.2017.06.001

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 909-918.DOI: 10.1016/j.jechem.2017.06.001

Synthesis of polymeric ionic liquids material and application in CO₂ adsorption

Haiying Ran^a, Jiexin Wang^b, Ahmed A. Abdeltawab^c, Xiaochun Chen^a, Guangren Yu^a,b, Yinghao Yu^d

a Beijing Key Laboratory of Membrane Science and Technology & College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
b State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
c Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia;
d School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China

收稿日期:2017-02-28 修回日期:2017-02-28 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Guangren Yu,E-mail addresses:gryu@mail.buct.edu.cn;Yinghao Yu,E-mail addresses:ceyhyu@scut.edu.cn
基金资助:
This work was financially supported by State Key Laboratory of Organic-Inorganic Composites (oic-201601012). The authors extend their appreciation to the International Scientific Partnership Program ISPP at King Saud University for funding this research work through ISPP#0080.

Synthesis of polymeric ionic liquids material and application in CO₂ adsorption

Haiying Ran^a, Jiexin Wang^b, Ahmed A. Abdeltawab^c, Xiaochun Chen^a, Guangren Yu^a,b, Yinghao Yu^d

a Beijing Key Laboratory of Membrane Science and Technology & College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
b State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
c Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia;
d School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China

Received:2017-02-28 Revised:2017-02-28 Online:2017-09-15 Published:2017-11-10
Contact: Guangren Yu,E-mail addresses:gryu@mail.buct.edu.cn;Yinghao Yu,E-mail addresses:ceyhyu@scut.edu.cn
Supported by:
This work was financially supported by State Key Laboratory of Organic-Inorganic Composites (oic-201601012). The authors extend their appreciation to the International Scientific Partnership Program ISPP at King Saud University for funding this research work through ISPP#0080.

摘要/Abstract

摘要： We synthesized one quaternary ammonium polymeric ionic liquids (PILs)P[VBTHEA]Cl and three imidazolium PILs of P[VEIm]Br, P[VEIm]BF₄, P[VEIm]PF₆ by free-radical polymerization in solution. These PILs were characterized by FT-IR, ¹H-NMR, ¹³C-NMR, TGA, XRD and SEM. Their CO₂ adsorption capacities were measured under different pressures and temperatures by constant-volume technique. It was observed that quaternary ammonium PILs of P[VBTHEA]Cl have higher adsorption capacity for CO₂ than those imidazolium PILs, following P[VBTHEA]Cl > P[VEIm]PF₆ > P[VEIm]BF₄ > P[VEIm]Br, which may be ascribed to higher positive charge density on ammonium cation than that on imidazolium cation and thus stronger interaction with CO₂, consistent with the results from dual-mode adsorption model that ammonium PILs have much higher CO₂ bulk absorption than imidazolium PILs. CO₂ adsorption capacity of P[VBTHEA]Cl is 9.02 mg/g under 295 K and 1 bar, which is comparable to that of some other PILs, and is much higher than that of the corresponding ILs monomer. These PILs have good adsorption selectivity for CO₂ over N₂ and regeneration efficiency.

关键词: Polymeric ionic liquids, CO₂, Adsorption

Abstract: We synthesized one quaternary ammonium polymeric ionic liquids (PILs)P[VBTHEA]Cl and three imidazolium PILs of P[VEIm]Br, P[VEIm]BF₄, P[VEIm]PF₆ by free-radical polymerization in solution. These PILs were characterized by FT-IR, ¹H-NMR, ¹³C-NMR, TGA, XRD and SEM. Their CO₂ adsorption capacities were measured under different pressures and temperatures by constant-volume technique. It was observed that quaternary ammonium PILs of P[VBTHEA]Cl have higher adsorption capacity for CO₂ than those imidazolium PILs, following P[VBTHEA]Cl > P[VEIm]PF₆ > P[VEIm]BF₄ > P[VEIm]Br, which may be ascribed to higher positive charge density on ammonium cation than that on imidazolium cation and thus stronger interaction with CO₂, consistent with the results from dual-mode adsorption model that ammonium PILs have much higher CO₂ bulk absorption than imidazolium PILs. CO₂ adsorption capacity of P[VBTHEA]Cl is 9.02 mg/g under 295 K and 1 bar, which is comparable to that of some other PILs, and is much higher than that of the corresponding ILs monomer. These PILs have good adsorption selectivity for CO₂ over N₂ and regeneration efficiency.

Key words: Polymeric ionic liquids, CO₂, Adsorption

Haiying Ran, Jiexin Wang, Ahmed A. Abdeltawab, Xiaochun Chen, Guangren Yu, Yinghao Yu. Synthesis of polymeric ionic liquids material and application in CO₂ adsorption[J]. 能源化学(英文), 2017, 26(5): 909-918.

Haiying Ran, Jiexin Wang, Ahmed A. Abdeltawab, Xiaochun Chen, Guangren Yu, Yinghao Yu. Synthesis of polymeric ionic liquids material and application in CO₂ adsorption[J]. Journal of Energy Chemistry, 2017, 26(5): 909-918.

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Synthesis of polymeric ionic liquids material and application in CO₂ adsorption

Synthesis of polymeric ionic liquids material and application in CO₂ adsorption

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