CO2 absorption with ionic liquids at elevated temperatures

doi:10.1016/j.jechem.2017.07.009

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 1001-1006.DOI: 10.1016/j.jechem.2017.07.009

CO₂ absorption with ionic liquids at elevated temperatures

Lu Bai^a, Dawei Shang^a, Mengdie Li^a, Zhongde Dai^b, Liyuan Deng^b, Xiangping Zhang^a

a Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex System, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
b Department of Chemical Engineering, Norwegian University of Science and Technology(NTNU), Trondheim 7491, Norway

收稿日期:2017-05-31 修回日期:2017-07-13 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Xiangping Zhang,E-mail address:xpzhang@ipe.ac.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21606233, 21436010), the National Natural Science Fund for Distinguished Young Scholars (21425625) and the Research Council of Norway through the CLIMIT program (215732).

CO₂ absorption with ionic liquids at elevated temperatures

Lu Bai^a, Dawei Shang^a, Mengdie Li^a, Zhongde Dai^b, Liyuan Deng^b, Xiangping Zhang^a

a Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex System, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
b Department of Chemical Engineering, Norwegian University of Science and Technology(NTNU), Trondheim 7491, Norway

Received:2017-05-31 Revised:2017-07-13 Online:2017-09-15 Published:2017-11-10
Contact: Xiangping Zhang,E-mail address:xpzhang@ipe.ac.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21606233, 21436010), the National Natural Science Fund for Distinguished Young Scholars (21425625) and the Research Council of Norway through the CLIMIT program (215732).

摘要/Abstract

摘要： CO₂ capture with ionic liquids (ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures. This not only limits the CO₂ absorption application at elevated temperature, but also the determination of the operation condition of the CO₂ desorption generally occurring at higher temperature. This work mainly reported CO₂ solubilities in ILs at elevated temperatures and related properties were also provided. 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C_nMIm] [Tf₂N]) ILs were selected as physical absorbents for CO₂ capture in this work due to their relative higher CO₂ absorption capacities and good thermal stabilities. The long-term stability tests showed that[C_nMIm] [Tf₂N] is thermally stable at 393.15 K for long time. CO₂ solubilities in[C_nMIm] [Tf₂N] were systematically determined at temperatures from 353.15 K to 393.15 K. It demonstrated that CO₂ solubility obviously increases with the increase of pressure while slightly decreases with increase of temperature. As the length of alkyl chain on the cation increases, CO₂ solubility in ILs increases. Additionally, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO₂ were also calculated.

关键词: Ionic liquids, CO₂ capture, Elevated temperature, Pre-combustion

Abstract: CO₂ capture with ionic liquids (ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures. This not only limits the CO₂ absorption application at elevated temperature, but also the determination of the operation condition of the CO₂ desorption generally occurring at higher temperature. This work mainly reported CO₂ solubilities in ILs at elevated temperatures and related properties were also provided. 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C_nMIm] [Tf₂N]) ILs were selected as physical absorbents for CO₂ capture in this work due to their relative higher CO₂ absorption capacities and good thermal stabilities. The long-term stability tests showed that[C_nMIm] [Tf₂N] is thermally stable at 393.15 K for long time. CO₂ solubilities in[C_nMIm] [Tf₂N] were systematically determined at temperatures from 353.15 K to 393.15 K. It demonstrated that CO₂ solubility obviously increases with the increase of pressure while slightly decreases with increase of temperature. As the length of alkyl chain on the cation increases, CO₂ solubility in ILs increases. Additionally, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO₂ were also calculated.

Key words: Ionic liquids, CO₂ capture, Elevated temperature, Pre-combustion

Lu Bai, Dawei Shang, Mengdie Li, Zhongde Dai, Liyuan Deng, Xiangping Zhang. CO₂ absorption with ionic liquids at elevated temperatures[J]. 能源化学(英文), 2017, 26(5): 1001-1006.

Lu Bai, Dawei Shang, Mengdie Li, Zhongde Dai, Liyuan Deng, Xiangping Zhang. CO₂ absorption with ionic liquids at elevated temperatures[J]. Journal of Energy Chemistry, 2017, 26(5): 1001-1006.

参考文献

[1] M. Ramdin, T.W. de Loos, T.J.H. Vlugt, Ind. Eng. Chem. Res. 51(2012) 8149-8177.

[2] S.D. Kenarsari, D.L. Yang, G.D. Jiang, S.J. Zhang, J.J. Wang, A.G. Russell, Q. Wei, M.H. Fan, RSC Adv. 3(2013) 22739-22773.

[3] C.A. Scholes, K.H. Smith, S.E. Kentish, G.W. Stevens, Int. J. Greenhouse Gas Control 4(2010) 739-755.

[4] Z. Dai, L. Deng, Int. J. Greenhouse Gas Control 54(2016) 59-69.

[5] D. Jansen, M. Gazzani, G. Manzolini, E. van Dijk, M. Carbo, Int. J. Greenhouse Gas Control 40(2015) 167-187.

[6] N. Casas, J. Schell, L. Joss, M. Mazzotti, Sep. Purif. Technol. 104(2013) 183-192.

[7] P. Babu, S. Datta, R. Kumar, P. Linga, Energy 78(2014) 458-464.

[8] S.H. Park, S.J. Lee, J.W. Lee, S.N. Chun, J. Bin Lee, Energy 81(2015) 47-55.

[9] J.Y. Xu, Z. Wang, C.X. Zhang, S. Zhao, Z.H. Qiao, P.Y. Li, J.X. Wang, S.C. Wang, Chem. Eng. Sci. 135(2015) 202-216.

[10] K. Atsonios, K.D. Panopoulos, A. Doukelis, A. Koumanakos, E. Kakaras, Energy 53(2013) 106-113.

[11] J.B. Gao, L.D. Cao, H.F. Dong, X.P. Zhang, S.J. Zhang, Appl. Energy 154(2015) 771-780.

[12] N.S. Siefert, S. Agarwal, F. Shi, W. Shi, E.A. Roth, D. Hopkinson, V.A. Kusuma, R.L. Thompson, D.R. Luebke, H.B. Nulwala, Int. J. Greenhouse Gas Control 49(2016) 364-371.

[13] M.B. Miller, D.R. Luebke, R.M. Enick, Energy Fuel 24(2010) 6214-6219.

[14] W.H. Chen, S.M. Chen, C.I. Hung, Appl. Energy 111(2013) 731-741.

[15] I. Sharma, A.F.A. Hoadley, S.M. Mahajani, A. Ganesh, J. Cleaner Prod. 119(2016) 196-206.

[16] M.C. Romano, P. Chiesa, G. Lozza, Int. J. Greenhouse Gas Control 4(2010) 785-797.

[17] L.A. Blanchard, D. Hancu, E.J. Beckman, J.F. Brennecke, Nature 399(1999) 28-29.

[18] S. Aki, B.R. Mellein, E.M. Saurer, J.F. Brennecke, J. Phys. Chem. B 108(2004) 20355-20365.

[19] N.M. Yunus, M.I.A. Mutalib, Z. Man, M.A. Bustam, T. Murugesan, Chem. Eng. J. 189(2012) 94-100.

[20] D. Almantariotis, T. Gefflaut, A.A.H. Padua, J.Y. Coxam, M.F.C. Gomes, J. Phys. Chem. B 114(2010) 3608-3617.

[21] E.K. Shin, B.C. Lee, J.S. Lim, J. Supercrit. Fluid. 45(2008) 282-292.

[22] Y.H. Jung, J.Y. Jung, Y.R. Jin, B.C. Lee, I.H. Baek, S.H. Kim, J. Chem. Eng. Data 57(2012) 3321-3329.

[23] E.D. Bates, R.D. Mayton, I. Ntai, J.H. Davis, J. Am. Chem. Soc. 124(2002) 926-927.

[24] B.E. Gurkan, J.C. de la Fuente, E.M. Mindrup, L.E. Ficke, B.F. Goodrich, E.A. Price, W.F. Schneider, J.F. Brennecke, J. Am. Chem. Soc. 132(2010) 2116-2117.

[25] G. Gurau, H. Rodriguez, S.P. Kelley, P. Janiczek, R.S. Kalb, R.D. Rogers, Angew. Chem. Int. Ed. 50(2011) 12024-12026.

[26] Y.Q. Zhang, S.J. Zhang, X.M. Lu, Q. Zhou, W. Fan, X.P. Zhang, Chem.-Eur. J. 15(2009) 3003-3011.

[27] J.Z. Zhang, C. Jia, H.F. Dong, J.Q. Wang, X.P. Zhang, S.J. Zhang, Ind. Eng. Chem. Res. 52(2013) 5835-5841.

[28] C.M. Wang, H.M. Luo, D.E. Jiang, H.R. Li, S. Dai, Angew. Chem. Int. Ed. 49(2010) 5978-5981.

[29] C.M. Wang, H.M. Luo, H.R. Li, X. Zhu, B. Yu, S. Dai, Chem.-Eur. J. 18(2012) 2153-2160.

[30] X.Y. Luo, Y. Guo, F. Ding, H.Q. Zhao, G.K. Cui, H.R. Li, C.M. Wang, Angew. Chem. Int. Ed. 53(2014) 7053-7057.

[31] S. Bhattacharyya, F.U. Shah, ACS Sustain. Chem. Eng. 4(2016) 5441-5449.

[32] F.F. Chen, K. Huang, Y. Zhou, Z.Q. Tian, X. Zhu, D.J. Tao, D.E. Jiang, S. Dai, Angew. Chem. Int. Ed. 55(2016) 7166-7170.

[33] M.J. Muldoon, S. Aki, J.L. Anderson, J.K. Dixon, J.F. Brennecke, J. Phys. Chem. B 111(2007) 9001-9009.

[34] S.J. Zeng, J. Wang, L. Bai, B.Q. Wang, H.S. Gao, D.W. Shang, X.P. Zhang, S.J. Zhang, Energy Fuel 29(2015) 6039-6048.

[35] J.L. Anthony, J.L. Anderson, E.J. Maginn, J.F. Brennecke, J. Phys. Chem. B 109(2005) 6366-6374.

[36] J. Jacquemin, M.F.C. Gomes, P. Husson, V. Majer, J. Chem. Thermodyn. 38(2006) 490-502.

[37] X.H. Huang, C.J. Margulis, Y.H. Li, B.J. Berne, J. Am. Chem. Soc. 127(2005) 17842-17851.

CO₂ absorption with ionic liquids at elevated temperatures

CO₂ absorption with ionic liquids at elevated temperatures

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