NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming

doi:10.1016/j.jechem.2017.07.002

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 942-947.DOI: 10.1016/j.jechem.2017.07.002

NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming

Alejandra Cruz-Hernández, J. Arturo Mendoza-Nieto, Heriberto Pfeiffer

Laboratorio de Fisicoquímica y Reactividad de Superficies(LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Ciudad Universitaria, Del. Coyoacán, CP 04510, Ciudad de México, Mexico

收稿日期:2017-05-23 修回日期:2017-07-02 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Heriberto Pfeiffer,E-mail addresses:pfeifferperea@gmail.com,pfeiffer@iim.unam.mx
基金资助:
This work was financially supported by the projects PAPⅡTUNAM (IN-101916) and SENER-CONACyT. A. Cruz-Hernández thanks CONACyT and J. A. Mendoza-Nieto thanks DGAPA-UNAM for financial support. Authors thank A. Tejeda for technical help.

NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming

Alejandra Cruz-Hernández, J. Arturo Mendoza-Nieto, Heriberto Pfeiffer

Laboratorio de Fisicoquímica y Reactividad de Superficies(LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Ciudad Universitaria, Del. Coyoacán, CP 04510, Ciudad de México, Mexico

Received:2017-05-23 Revised:2017-07-02 Online:2017-09-15 Published:2017-11-10
Contact: Heriberto Pfeiffer,E-mail addresses:pfeifferperea@gmail.com,pfeiffer@iim.unam.mx
Supported by:
This work was financially supported by the projects PAPⅡTUNAM (IN-101916) and SENER-CONACyT. A. Cruz-Hernández thanks CONACyT and J. A. Mendoza-Nieto thanks DGAPA-UNAM for financial support. Authors thank A. Tejeda for technical help.

摘要/Abstract

摘要： In this work, CaO-NiO mixed oxide powders were evaluated as consecutive CO₂ chemisorbents and catalytic materials for hydrogen production thought the CH₄ reforming process. Between the NiOimpregnated CaO and CaO-NiO mechanical composite, the first one presented better chemical behaviors during the CO₂ capture and CH₄ reforming processes, obtaining syngas (H₂ + CO) as final product. Results showed that syngas was produced at two different temperature ranges, between 400 and 600℃ and at T > 800℃, where the first temperature range corresponds to the CH₄ reforming process but the second temperature range was attributed to a different catalytic reaction process:CH₄ partial oxidation. These results were confirmed through different isothermal and cyclic experiments as well as by XRD analysis of the final catalytic products, where the nickel reduction was evidenced. Moreover, when a CO-O₂ flow was used during the carbonation process a triple process was achieved:(i) CO oxidation, (ii) CO₂ chemisorption and (iii) CH₄ reforming. Using this gas flow the hydrogen production was always higher than that obtained with CO₂.

关键词: Methane reforming, CO₂ capture, Calcium oxide, H₂ production, NiO supported

Abstract: In this work, CaO-NiO mixed oxide powders were evaluated as consecutive CO₂ chemisorbents and catalytic materials for hydrogen production thought the CH₄ reforming process. Between the NiOimpregnated CaO and CaO-NiO mechanical composite, the first one presented better chemical behaviors during the CO₂ capture and CH₄ reforming processes, obtaining syngas (H₂ + CO) as final product. Results showed that syngas was produced at two different temperature ranges, between 400 and 600℃ and at T > 800℃, where the first temperature range corresponds to the CH₄ reforming process but the second temperature range was attributed to a different catalytic reaction process:CH₄ partial oxidation. These results were confirmed through different isothermal and cyclic experiments as well as by XRD analysis of the final catalytic products, where the nickel reduction was evidenced. Moreover, when a CO-O₂ flow was used during the carbonation process a triple process was achieved:(i) CO oxidation, (ii) CO₂ chemisorption and (iii) CH₄ reforming. Using this gas flow the hydrogen production was always higher than that obtained with CO₂.

Key words: Methane reforming, CO₂ capture, Calcium oxide, H₂ production, NiO supported

Alejandra Cruz-Hernández, J. Arturo Mendoza-Nieto, Heriberto Pfeiffer. NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming[J]. 能源化学(英文), 2017, 26(5): 942-947.

参考文献

[1] P. Pall, T. Aina, D.A. Stone, P.A. Stott, T. Nozawa, A.G.J. Hilberts, D. Lohmann, M.R. Allen, Nature 470(2011) 382-385.

[2] S.-K. Min, X. Zhang, F.W. Zwiers, G.C. Hegerl, Nature 470(2011) 378-381.

[3] C.S. Martavaltzi, E.P. Pampaka, E.S. Korkakaki, A.A. Lemonidou, Energy Fuels 24(2010) 2589-2595.

[4] D. Das, T.N. Veziroglu, Int. J. Hydrog. Energy 33(2008) 6046-6057.

[5] A. Heinzel, B. Vogel, P. Hübner, J. Power Sour. 105(2002) 202-207.

[6] T. Zhang, M.D. Amiridis, Appl. Catal. A 167(1998) 161-172.

[7] J.R. Rostrup-Nielsen, T. Rostrup-Nielsen, Cattech 6(2002) 150-159.

[8] S. Lin, M. Harada, Y. Suzuki, H. Hatano, Fuel 81(2002) 2079-2085.

[9] S. Yaman, Energy Convers. Manag. 45(2004) 651-671.

[10] S. Rapagna, Int. J. Hydrog. Energy. 23(1998) 551-557.

[11] A.F. Lucrédio, E.M. Assaf, J. Power Sour. 159(2006) 667-672.

[12] M.H. Halabi, J.M. De Croon, J. Van Der Schaaf, P.D. Cobden, J.C. Schouten, Chem. Eng. J. 168(2011) 872-882.

[13] J.R. Hufton, S. Mayorga, S. Sircar, AIChE J. 45(1999) 248-256.

[14] A. López Ortiz, M.A. Escobedo Bretado, J. Salinas Gutiérrez, M. Meléndez Zaragoza, R.H. Lara Castro, V. Collins Martínez, Int. J. Hydrog. Energy 40(2015) 17192-17199.

[15] C. Zhao, Z. Zhou, Z. Cheng, X. Fang, Appl. Catal. B. 196(2016) 16-26.

[16] K. Essaki, T. Muramatsu, M. Kato, Int. J. Hydrog. Energy 33(2008) 6612-6618.

[17] R. Williams, Process Catalysis Synthesis, U.S. Pat. (1933) 1,909,442.

[18] W.B.R.E. Gorin, Method for the production of hydrogen, U.S. Pat. (1963) 3,108,857.

[19] J.A. Mendoza-Nieto, E. Vera, H. Pfeiffer, Chem. Lett. 45(2016) 3-6.

[20] S. Wang, S. Yan, X. Ma, J. Gong, Energy Environ. Sci. 4(2011) 3805.

[21] R.V. Siriwardane, C. Robinson, M. Shen, T. Simonyi, Energy Fuels 21(2007) 2088-2097.

[22] E. Ochoa-Fernández, M. Rønning, T. Grande, D. Chen, Chem. Mater. 18(2006) 1383-1385.

[23] H.A. Lara-García, M.J. Ramírez-Moreno, J. Ortiz-Landeros, H. Pfeiffer, RSC Adv. 6(2016) 57880-57888.

[24] S.M. Amorim, M.D. Domenico, T.L.P. Dantas, H.J. José, R.F.P.M. Moreira, Chem. Eng. J. 283(2016) 388-396.

[25] J.A. Mendoza-Nieto, H. Pfeiffer, RSC Adv. 6(2016) 66579-66588.

[26] S.C. Lee, B.Y. Choi, C.K. Ryu, Y.S. Ahn, T.J. Lee, J.C. Kim, Korean J. Chem. Eng. 23(2006) 374-379.

[27] G.S. Grasa, J.C. Abanades, Ind. Eng. Chem. Res. 45(2006) 8846-8851.

[28] L. Li, X. Wen, X. Fu, F. Wang, N. Zhao, F. Xiao, W. Wei, Y. Sun, Energy Fuels 24(2010) 5773-5780.

[29] A. Cruz-Hernández, B. Alcántar-Vázquez, J. Arenas, H. Pfeiffer, React. Kinet. Mech. Catal. 119(2016) 445-455.

[30] S. Kumar, S.K. Saxena, Mater. Renew. Sustain. Energy 3(2014) 30.

[31] J. Wang, L. Huang, R. Yang, Z. Zhang, J. Wu, Y. Gao, Q. Wang, D. O'Hare, Z. Zhong, Energy Environ. Sci. 7(2014) 3478-3518.

[32] V. Manovic, E.J. Anthony, Environ. Sci. Technol. 43(2009) 7117-7122.

[33] J.C. Abanades, E.J. Anthony, J. Wang, J.E. Oakey, Environ. Sci. Technol. 39(2005) 2861-2866.

[34] Y.H. Hu, E. Ruckenstein, Catal. Lett. 36(1996) 145-149.

[35] C. Han, D.P. Harrison, Chem. Eng. Sci. 49(1994) 5875-5883.

[36] M. Specht, A. Bandi, F., Baumgart, T. Weimer, PCT Pat. WO01/23302(2001).

[37] Y. Kato, K. Otsuka, C.Y. Liu, Chem. Eng. Res. Des. 83(2005) 900-904.

[38] Y. Kato, K. Ando, Y. Yoshizawa, J. Chem. Eng. Jpn. 36(2003) 860-866.

[39] L. Xu, H. Song, L. Chou, ACS Catal. 8(2012) 1331-1342.

[40] V.R. Choudhary, A.M. Rajput, Ind. Eng. Chem. Res. 35(1996) 3934-3939.

[41] V.R. Choudhary, A.M. Rajput, B. Prabhakar, Catal. Lett. 15(1992) 363-370.

[42] Z.H. Lee, S. Ichikawa, K.T. Lee, A.R. Mohamed, J. Energy Chem. 24(2015) 225-231.

[43] K. Johnsen, H.J. Ryu, J.R. Grace, C.J. Lim, Chem. Eng. Sci. 61(2006) 1195-1202.

[44] S. Brun-Tsekhovoi, A.R. Zadorin, A.N. Katsobashvili, Y.R. Kourdyumov, in:Proceedings of the World Hydrogen Energy Conference, 1988, pp. 885-900.

[45] B. Balasubramanian, A. Lopez Ortiz, S. Kaytakoglu, D.P. Harrison, Chem. Eng. Sci. 54(1999) 3543-3552.

NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming

NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming

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