Investigation of the role of Ca(OH)2 in the catalytic Alkaline Thermal Treatment of cellulose to produce H2 with integrated carbon capture

doi:10.1016/j.jechem.2017.07.013

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 984-1000.DOI: 10.1016/j.jechem.2017.07.013

Investigation of the role of Ca(OH)₂ in the catalytic Alkaline Thermal Treatment of cellulose to produce H₂ with integrated carbon capture

Maxim R. Stonor^a,c, Nicholas Ouassil^a, Jingguang G. Chen^a,c, Ah-Hyung Alissa Park^a,b,c

a Department of Chemical Engineering, Columbia University, NY, USA;
b Department of Earth and Environmental Engineering, Columbia University, NY, USA;
c Lenfest Center for Sustainable Energy, Columbia University, NY, USA

收稿日期:2017-05-29 修回日期:2017-07-20 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Jingguang G. Chen,E-mail addresses:jgchen@columbia.edu;Ah-Hyung Alissa Park,E-mail addresses:ap2622@columbia.edu
基金资助:
The authors acknowledge funding support from NSF CBET 1336567. We also would like to thank Hui Zhou and Dan Paley for their expertise and help with this project.

Investigation of the role of Ca(OH)₂ in the catalytic Alkaline Thermal Treatment of cellulose to produce H₂ with integrated carbon capture

Maxim R. Stonor^a,c, Nicholas Ouassil^a, Jingguang G. Chen^a,c, Ah-Hyung Alissa Park^a,b,c

a Department of Chemical Engineering, Columbia University, NY, USA;
b Department of Earth and Environmental Engineering, Columbia University, NY, USA;
c Lenfest Center for Sustainable Energy, Columbia University, NY, USA

Received:2017-05-29 Revised:2017-07-20 Online:2017-09-15 Published:2017-11-10
Contact: Jingguang G. Chen,E-mail addresses:jgchen@columbia.edu;Ah-Hyung Alissa Park,E-mail addresses:ap2622@columbia.edu
Supported by:
The authors acknowledge funding support from NSF CBET 1336567. We also would like to thank Hui Zhou and Dan Paley for their expertise and help with this project.

摘要/Abstract

摘要： The Alkaline Thermal Treatment (ATT) of biomass is one of the few biomass conversion processes that has a potential for BECCS (bio-energy with carbon capture and storage). Combining in-situ carbon capture with H₂ production creates a carbon-neutral process that has the potential to be carbon-negative. This study has shown that the conversion of cellulose to H₂ with suppressed CO₂ formation can be achieved through the reforming of gaseous intermediates in a fixed bed of Ca(OH)₂ and 10% Ni/ZrO₂. Reforming occurs at low temperatures ≤ 773 K, which could allow for improved sustainability.

关键词: Hydrogen Biomass, Alkaline Thermal Treatment, Calcium hydroxide, Calcium carbonate, Carbon capture utilization storage, Nickel, Heterogeneous catalysis, Catalytic reforming

Abstract: The Alkaline Thermal Treatment (ATT) of biomass is one of the few biomass conversion processes that has a potential for BECCS (bio-energy with carbon capture and storage). Combining in-situ carbon capture with H₂ production creates a carbon-neutral process that has the potential to be carbon-negative. This study has shown that the conversion of cellulose to H₂ with suppressed CO₂ formation can be achieved through the reforming of gaseous intermediates in a fixed bed of Ca(OH)₂ and 10% Ni/ZrO₂. Reforming occurs at low temperatures ≤ 773 K, which could allow for improved sustainability.

Key words: Hydrogen Biomass, Alkaline Thermal Treatment, Calcium hydroxide, Calcium carbonate, Carbon capture utilization storage, Nickel, Heterogeneous catalysis, Catalytic reforming

Maxim R. Stonor, Nicholas Ouassil, Jingguang G. Chen, Ah-Hyung Alissa Park. Investigation of the role of Ca(OH)₂ in the catalytic Alkaline Thermal Treatment of cellulose to produce H₂ with integrated carbon capture[J]. 能源化学(英文), 2017, 26(5): 984-1000.

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Investigation of the role of Ca(OH)₂ in the catalytic Alkaline Thermal Treatment of cellulose to produce H₂ with integrated carbon capture

Investigation of the role of Ca(OH)₂ in the catalytic Alkaline Thermal Treatment of cellulose to produce H₂ with integrated carbon capture

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