Resorcinol-formaldehyde resin-based porous carbon spheres with high CO2 capture capacities

doi:10.1016/j.jechem.2017.07.010

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 1007-1013.DOI: 10.1016/j.jechem.2017.07.010

Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities

Xuan Wang^a, Jin Zhou^a, Wei Xing^b, Boyu Liu^a, Jianlin Zhang^a, Hongtao Lin^a, Hongyou Cui^a, Shuping Zhuo^a

a School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong, China;
b School of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, Shandong, China

收稿日期:2017-05-04 修回日期:2017-07-13 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Jin Zhou,E-mail addresses:zhoujin@sdut.edu.cn;Shuping Zhuo,E-mail addresses:zhuosp@sdut.edu.cn
基金资助:
We are grateful for the financial supports by the Natural Science Foundation of China (NSFC21576158, 21476132, 21576159 and 21403130) and Shandong Provincial Natural Science Foundation, China (No. 2015 ZRB01765).

Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities

Xuan Wang^a, Jin Zhou^a, Wei Xing^b, Boyu Liu^a, Jianlin Zhang^a, Hongtao Lin^a, Hongyou Cui^a, Shuping Zhuo^a

a School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong, China;
b School of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, Shandong, China

Received:2017-05-04 Revised:2017-07-13 Online:2017-09-15 Published:2017-11-10
Contact: Jin Zhou,E-mail addresses:zhoujin@sdut.edu.cn;Shuping Zhuo,E-mail addresses:zhuosp@sdut.edu.cn
Supported by:
We are grateful for the financial supports by the Natural Science Foundation of China (NSFC21576158, 21476132, 21576159 and 21403130) and Shandong Provincial Natural Science Foundation, China (No. 2015 ZRB01765).

摘要/Abstract

摘要： Porous carbon spheres are prepared by direct carbonization of potassium salt of resorcinol-formaldehyde resin spheres, and are investigated as CO₂ adsorbents. It is found that the prepared carbon materials still maintain the typical spherical shapes after the activation, and have highly developed ultra-microporosity with uniform pore size, indicating that almost the activation takes place in the interior of the polymer spheres. The narrow-distributed ultra-micropores are attributed to the "in-situ homogeneous activation" effect produced by the mono-dispersed potassium ions as a form of -OK groups in the bulk of polymer spheres. The CS-1 sample prepared under a KOH/resins weight ratio of 1 shows a very high CO₂ capture capacity of 4.83 mmol/g and good CO₂/N₂ selectivity of ～17-45. We believe that the presence of a welldeveloped ultra-microporosity is responsible for excellent CO₂ sorption performance at room temperature and ambient pressure.

关键词: CO₂ capture, Porous carbon, Carbon sphere, Ultra-micropore, Resorcinol formaldehyde resins

Abstract: Porous carbon spheres are prepared by direct carbonization of potassium salt of resorcinol-formaldehyde resin spheres, and are investigated as CO₂ adsorbents. It is found that the prepared carbon materials still maintain the typical spherical shapes after the activation, and have highly developed ultra-microporosity with uniform pore size, indicating that almost the activation takes place in the interior of the polymer spheres. The narrow-distributed ultra-micropores are attributed to the "in-situ homogeneous activation" effect produced by the mono-dispersed potassium ions as a form of -OK groups in the bulk of polymer spheres. The CS-1 sample prepared under a KOH/resins weight ratio of 1 shows a very high CO₂ capture capacity of 4.83 mmol/g and good CO₂/N₂ selectivity of ～17-45. We believe that the presence of a welldeveloped ultra-microporosity is responsible for excellent CO₂ sorption performance at room temperature and ambient pressure.

Key words: CO₂ capture, Porous carbon, Carbon sphere, Ultra-micropore, Resorcinol formaldehyde resins

Xuan Wang, Jin Zhou, Wei Xing, Boyu Liu, Jianlin Zhang, Hongtao Lin, Hongyou Cui, Shuping Zhuo. Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities[J]. 能源化学(英文), 2017, 26(5): 1007-1013.

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Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities

Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities

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