CO2 capture over molecular basket sorbents:Effects of SiO2 supports and PEG additive

doi:10.1016/j.jechem.2017.09.002

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (5): 1030-1038.DOI: 10.1016/j.jechem.2017.09.002

• ARTICLES • 上一篇

CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive

Lin Zhang^a,b,c, Xiaoxing Wang^b,c, Mamoru Fujii^b,c, Linjun Yang^a, Chunshan Song^b,c

a Key Laboratory of Energy Thermal Conversion and Control, Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu, China;
b Clean Fuels and Catalysis Program, EMS Energy Institute, PSU-DUT Joint Center for Energy Research, USA;
c Department of Energy & Mineral Engineering, Pennsylvania State University, University Park, PA 16802, USA

收稿日期:2017-08-11 修回日期:2017-09-06 出版日期:2017-09-15 发布日期:2017-11-10
通讯作者: Linjun Yang,E-mail addresses:ylj@seu.edu.cn;Chunshan Song,E-mail addresses:csong@psu.edu
基金资助:
We gratefully acknowledge the support of this work at Penn State by the U.S. Department of Energy, National Energy Technology Laboratory. Lin Zhang would like to thank the financial support by the China Scholarship Council, the Natural Science Foundation of China (No. 51176034), the Open Fund of Key Laboratory of Coal-Based CO₂ Capture and Geological Storage of Jiangsu Province (2016A05). Additionally, Lin Zhang would like to specially thank Dr. Song and the EMS Energy Institute at Penn State for hosting her as a visiting scholar.

CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive

Lin Zhang^a,b,c, Xiaoxing Wang^b,c, Mamoru Fujii^b,c, Linjun Yang^a, Chunshan Song^b,c

a Key Laboratory of Energy Thermal Conversion and Control, Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu, China;
b Clean Fuels and Catalysis Program, EMS Energy Institute, PSU-DUT Joint Center for Energy Research, USA;
c Department of Energy & Mineral Engineering, Pennsylvania State University, University Park, PA 16802, USA

Received:2017-08-11 Revised:2017-09-06 Online:2017-09-15 Published:2017-11-10
Contact: Linjun Yang,E-mail addresses:ylj@seu.edu.cn;Chunshan Song,E-mail addresses:csong@psu.edu
Supported by:
We gratefully acknowledge the support of this work at Penn State by the U.S. Department of Energy, National Energy Technology Laboratory. Lin Zhang would like to thank the financial support by the China Scholarship Council, the Natural Science Foundation of China (No. 51176034), the Open Fund of Key Laboratory of Coal-Based CO₂ Capture and Geological Storage of Jiangsu Province (2016A05). Additionally, Lin Zhang would like to specially thank Dr. Song and the EMS Energy Institute at Penn State for hosting her as a visiting scholar.

摘要/Abstract

摘要： The objective of this work is to study the influences of silica supports and PEG additive on the sorption performance of molecular basket sorbent (MBS) for CO₂ capture consisting of polyethylenimine and one of the following supports:SBA-15 (2-D structure), TUD-1 (3-D sponge-like structure) and fumed silica HS-5 (3-D disordered structure). Effects of the supports regarding pore structures and pore properties, the PEI loading amount as well as the sorption temperature were examined. Furthermore, polyethylene glycol (PEG) was introduced as an additive into the sorbents and its effect was investigated at different PEI loadings and sorption temperatures. The results suggest that the pore properties of MBS (after PEI loading) play a more important role in the CO₂ sorption capacity, rather than those of the supports alone. MBS with 3D pore structure exhibits higher CO₂ sorption capacity and amine efficiency than those with 2D-structured support. Among the sorbents studied, fumed silica (HS-5) based MBS showed the highest CO₂ sorption capacity in the temperature range of 30-95℃, probably due to its unique interstitial pores formed by the aggregation of polymer-loaded SiO₂ particles. It was found that the temperature dependence is directly related to the PEI surface coverage layers. The more PEI surface coverage layers, the higher diffusion barrier for CO₂ and the stronger temperature dependence of CO₂ capacity. 3D MBS exceeds 2D MBS at the same PEI coverage layers due to lower diffusion barrier. Adding PEG can significantly enhance the CO₂ sorption capacity and improve amine efficiency of all MBS, most likely by alleviating the diffusion barrier within PEI bulk layers through the inter-molecular interaction between PEI and PEG.

关键词: CO₂ capture, Molecular basket sorbents, Mesoporous molecular sieve, Polyethylenimine (PEI), Polyethylene glycol (PEG)

Abstract: The objective of this work is to study the influences of silica supports and PEG additive on the sorption performance of molecular basket sorbent (MBS) for CO₂ capture consisting of polyethylenimine and one of the following supports:SBA-15 (2-D structure), TUD-1 (3-D sponge-like structure) and fumed silica HS-5 (3-D disordered structure). Effects of the supports regarding pore structures and pore properties, the PEI loading amount as well as the sorption temperature were examined. Furthermore, polyethylene glycol (PEG) was introduced as an additive into the sorbents and its effect was investigated at different PEI loadings and sorption temperatures. The results suggest that the pore properties of MBS (after PEI loading) play a more important role in the CO₂ sorption capacity, rather than those of the supports alone. MBS with 3D pore structure exhibits higher CO₂ sorption capacity and amine efficiency than those with 2D-structured support. Among the sorbents studied, fumed silica (HS-5) based MBS showed the highest CO₂ sorption capacity in the temperature range of 30-95℃, probably due to its unique interstitial pores formed by the aggregation of polymer-loaded SiO₂ particles. It was found that the temperature dependence is directly related to the PEI surface coverage layers. The more PEI surface coverage layers, the higher diffusion barrier for CO₂ and the stronger temperature dependence of CO₂ capacity. 3D MBS exceeds 2D MBS at the same PEI coverage layers due to lower diffusion barrier. Adding PEG can significantly enhance the CO₂ sorption capacity and improve amine efficiency of all MBS, most likely by alleviating the diffusion barrier within PEI bulk layers through the inter-molecular interaction between PEI and PEG.

Key words: CO₂ capture, Molecular basket sorbents, Mesoporous molecular sieve, Polyethylenimine (PEI), Polyethylene glycol (PEG)

Lin Zhang, Xiaoxing Wang, Mamoru Fujii, Linjun Yang, Chunshan Song. CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive[J]. 能源化学(英文), 2017, 26(5): 1030-1038.

Lin Zhang, Xiaoxing Wang, Mamoru Fujii, Linjun Yang, Chunshan Song. CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive[J]. Journal of Energy Chemistry, 2017, 26(5): 1030-1038.

参考文献

[1] IPCC Climate Change 2014 Synthesis Report Summary for Policymakers, IPCC. https://www.ipcc.ch/pdf/assessment-report/ar5/syr/AR5_SYR_FINAL_SPM.pdf.

[2] The twenty-first session of the Conference of the Parties (COP) and the eleventh session of the Conference of the Parties serving as the meeting of the Parties to the Kyoto Protocol (CMP) took place in Paris, France. .

[3] S.I. Seneviratne, M.G. Donat, A.J. Pitman, R. Knutti, R.L. Wilby, Nature 529(2016) 477-483.

[4] IEA, Energy Technology Perspectives:Scenarios & Strategies to 2050, International Energy Agency OECD/IEA:Paris. www.iea.org,2010.

[5] K.S. Lackner, Science 300(2003) 1677-1678.

[6] C.S. Song, Catal. Today 115(2006) 2-32.

[7] T. Proll, G. Schony, G. Sprachmann, H. Hofbauer, Chem. Eng. Sci. 141(2016) 166-174.

[8] S. Satyapal, T. Filburn, J. Trela, J. Strange, Energy Fuels 15(2001) 250-255.

[9] E.S. Kikkinides, R.T. Yang, S.H. Cho, Ind. Eng. Chem. Res. 32(1993) 2714-2720.

[10] B.K. Na, K.K. Koo, H.M. Eum, H. Lee, H.K. Song, Korean J. Chem. Eng. 18(2001) 220-227.

[11] F.S. Su, C.Y. Lu, Energy Environ. Sci. 5(2012) 9021-9027.

[12] T. Du, L.Y. Liu, P. Xiao, S. Che, H.M. Wang, Int. J. Miner. Metall. Mater. 21(2014) 820-825.

[13] N. Hiyoshi, K. Yogo, T. Yashima, Micropor. Mesopor. Mat. 84(2005) 357-365.

[14] M.L. Gray, Y. Soong, K.J. Champagne, H. Pennline, J.P. Baltrus, R.W. Stevens, R. Khatri, S.S.C. Chuang, T. Filburn, Fuel Process. Technol. 86(2005) 1449-1455.

[15] L.L. Huang, L.Z. Zhang, Q. Shao, L.H. Lu, X.H. Lu, S.Y. Jiang, W.F. Shen, J. Phys. Chem. C 111(2007) 11912-11920.

[16] S.S. Razavi, S.M. Hashemianzadeh, H. Karimi, J. Mol. Model. 17(2011) 1163-1172.

[17] Z.J. Zhang, Y.G. Zhao, Q.H. Gong, Z. Li, J. Li, Chem. Commun. 49(2013) 653-661.

[18] A. Torrisi, R.G. Bell, C. Mellot-Draznieks, Cryst. Growth Des. 10(2010) 2839-2841.

[19] E. Gonzalez-Zamora, I.A. Ibrra, Mater. Chem. Front. 1(2017) 1471-1484.

[20] X.C. Xu, C.S. Song, J.M. Andresen, B.G. Miller, A.W. Scaroni, Energy Fuels 16(2002) 1463-1469.

[21] X.C. Xu, C.S. Song, J.M. Andresen, B.G. Miller, A.W. Scaroni, Micropor. Mesopor. Mater. 62(2003) 29-45.

[22] X.C. Xu, C.S. Song, B.G. Miller, A.W. Scaroni, Ind. Eng. Chem. Res. 44(2005) 8113-8119.

[23] X.L. Ma, X.X. Wang, C.S. Song, J. Am. Chem. Soc. 131(2009) 5777-5783.

[24] X.X. Wang, X.L. Ma, L. Sun, C.S. Song, Green Chem. 9(2007) 695-702.

[25] X.X. Wang, V. Schwartz, J.C. Clark, X.L. Ma, S.H. Overbury, X.C. Xu, C.S. Song, J. Phys. Chem. C 113(2009) 7260-7268.

[26] X.X. Wang, X.L. Ma, C.S. Song, D.R. Locke, S. Siefert, R.E. Winans, J. Mollmer, M. Lange, A. Moller, R. Glaser, Micropor. Mesopor. Mater. 169(2013) 103-111.

[27] W.L. Wang, X.X. Wang, C.S. Song, X.L. Wei, J. Ding, J. Xiao, Energy Fuels 27(2013) 1538-1546.

[28] D.X. Wang, X.L. Ma, C. Sentorun-Shalaby, C.S. Song, Ind. Eng. Chem. Res. 51(2012) 3048-3057.

[29] X.X. Wang, C.S. Song, A.M. Gaffney, R.Z. Song, Catal. Today 238(2014) 95-102.

[30] D.X. Wang, X.X. Wang, X.L. Ma, E. Fillerup, C.S. Song, Catal. Today 233(2014) 100-107.

[31] X.X. Wang, C.S. Song, Energy Fuels 28(2014) 7742-7745.

[32] B. Yoosuk, T. Wongsanga, P. Prasassarakich, Fuel 168(2016) 47-53.

[33] J.C. Jansen, Z. Shan, L. Marchese, W. Zhou, N.V.D. Puil, T. Maschmeyer, Chem. Commun. (2001) 713-714.

[34] A.B. Fuertes, Micropor. Mesopor. Mater. 67(2004) 273-281.

[35] V.M. Gun'ko, V.I. Zarko, D.J. Sheeran, S.M. Augustine, J.P. Blitz, Adsorpt. J. Int. Adsorpt. Soc. 11(2005) 703-708.

[36] K.M. Li, J.G. Jiang, S.C. Tian, X.J. Chen, F. Yan, J. Phys. Chem. C 118(2014) 2454-2462.

[37] A. Dietrich, A. Neubrand, J. Am. Ceramic Soc. 84(2001) 806-812.

[38] X.X. Wang, X.L. Ma, V. Schwartz, J.C. Clark, S.H. Overbury, S.Q. Zhao, X.C. Xu, C.S. Song, Phys. Chem. Chem. Phys. 14(2012) 1485-1492.

[39] X.X. Wang, C.S. Song, Catal. Today 194(2012) 44-52.

[40] J. Tanthana, S.S.C. Chuang, Chemsuschem 3(2010) 957-964.

[41] A.L. Chaffee, S.W. Delaney, G.P. Knowles, Abstr. Pap. Am. Chem. Soc. 223(2002) U572-U573.

[42] M. Caplow, J. Am. Chem. Soc. 90(1968) 6795-&.

[43] P.V. Danckwerts, Chem. Eng. Sci. 34(1979) 443-446.

[44] A. Arenillas, K.M. Smith, T.C. Drage, C.E. Snape, Fuel 84(2005) 2204-2210.

[45] M.A. Sakwa-Novak, S. Tan, C.W. Jones, ACS Appl. Mater. Interfaces 7(2015) 24748-24759.

[46] P.J. Soltys, M.R. Etzel, Biomaterials 21(2000) 37-48.

CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive

CO₂ capture over molecular basket sorbents:Effects of SiO₂ supports and PEG additive

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Fei Huang, Ming Tian, Yanyan Zhu, Xiaodong Wang, Aiqin Wang, Lin Li, Jian Lin, Junhu Wang. Fe-substituted Ba-hexaaluminate with enhanced oxygen mobility for CO₂ capture by chemical looping combustion of methane[J]. 能源化学(英文), 2019, 28(2): 50-57.
[2]	Pedro Sánchez-Camacho, J. Francisco Gómez-García, Heriberto Pfeiffer. Thermokinetic and conductivity analyzes of the high CO₂ chemisorption on Li₅AlO₄ and alkaline carbonate impregnated Li₅AlO₄ samples:Effects produced by the use of CO₂ partial pressures and oxygen addition[J]. 能源化学(英文), 2017, 26(5): 919-926.
[3]	Lu Bai, Dawei Shang, Mengdie Li, Zhongde Dai, Liyuan Deng, Xiangping Zhang. CO₂ absorption with ionic liquids at elevated temperatures[J]. 能源化学(英文), 2017, 26(5): 1001-1006.
[4]	Alejandra Cruz-Hernández, J. Arturo Mendoza-Nieto, Heriberto Pfeiffer. NiO-CaO materials as promising catalysts for hydrogen production through carbon dioxide capture and subsequent dry methane reforming[J]. 能源化学(英文), 2017, 26(5): 942-947.
[5]	Pillaiyar Puthiaraj, Wha-Seung Ahn. Facile synthesis of microporous carbonaceous materials derived from a covalent triazine polymer for CO₂ capture[J]. 能源化学(英文), 2017, 26(5): 965-971.
[6]	Hongchao Luo, Hirofumi Kanoh. Fundamentals in CO₂ capture of Na₂CO₃ under a moist condition[J]. 能源化学(英文), 2017, 26(5): 972-983.
[7]	Xuan Wang, Jin Zhou, Wei Xing, Boyu Liu, Jianlin Zhang, Hongtao Lin, Hongyou Cui, Shuping Zhuo. Resorcinol-formaldehyde resin-based porous carbon spheres with high CO₂ capture capacities[J]. 能源化学(英文), 2017, 26(5): 1007-1013.
[8]	Yin Xu, Yingjie Zhou, Jingjing Liu, Luyi Sun. Coassembled ionic liquid/laponite hybrids as effective CO₂ adsorbents[J]. 能源化学(英文), 2017, 26(5): 1026-1029.
[9]	Chao Chen, Siqian Zhang, Kyung Ho Row, Wha-Seung Ahn. Amine-silica composites for CO₂ capture:A short review[J]. 能源化学(英文), 2017, 26(5): 868-880.
[10]	Qingqing Qin, Junya Wang, Tuantuan Zhou, Qianwen Zheng, Liang Huang, Yu Zhang, Peng Lu, Ahmad Umar, Benoît Louis, Qiang Wang. Impact of organic interlayer anions on the CO₂ adsorption performance of Mg-Al layered double hydroxides derived mixed oxides[J]. 能源化学(英文), 2017, 26(3): 346-353.
[11]	E. M. Briz-López, M. J. Ramírez-Moreno, I. C. Romero-Ibarra, C. Gómez-Yáñez, H. Pfeiffer, J. Ortiz-Landeros. First assessment of Li₂O-Bi₂O₃ ceramic oxides for high temperature carbon dioxide capture[J]. 能源化学(英文), 2016, 25(5): 754-760.
[12]	Huaqing Xie, Qingbo Yu, Xin Yao, Wenjun Duan, Zongliang Zuo, Qin Qin. Hydrogen production via steam reforming of bio-oil model compounds over supported nickel catalysts[J]. 能源化学(英文), 2015, 21(3): 299-308.
[13]	Junya Wang, Xueyi Mei, Liang Huang, Qianwen Zheng, Yaqian Qiao, Ketao Zang, Shengcheng Mao, Ruoyan Yang, Zhang Zhang, Yanshan Gao, Zhanhu Guo, Zhanggen Huang, Qiang Wang. Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO₂ adsorbent[J]. 能源化学(英文), 2015, 21(2): 127-137.
[14]	Longfei Luo, Hongwei Cheng, Guangshi Li, Xionggang Lu, Bo Jiang. Oxygen permeability and CO₂-tolerance of Ce_0.8Gd_0.2O_2-δ-LnBaCo₂O_5+δ dual-phase membranes[J]. 能源化学(英文), 2015, 21(1): 15-22.
[15]	Lianjun Wang, Yang Li, Shuguang Li, Pengfei Ji, Chengzhang Jiang. Preparation of composite poly(ether block amide) membrane for CO₂ capture[J]. 能源化学(英文), 2014, 23(6): 717-725.